A rational basis for the axial ligand effect in C-H oxidation by [MnO(porphyrin)(X)]+ (X = H2O, OH-, O 2-) from a DFT study

Inorganic Chemistry

Volumn 47, Issue 21, 2008, Pages 10090-10099

  Balcells, David ^a   Raynaud, Christophe ^a   Crabtree, Robert H ^b   Eisenstein, Odile ^a  

^a UNIVERSITÉ DE MONTPELLIER   (France)

^b YALE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROXIDE; HYDROXIDE ION; LIGAND; MANGANESE DERIVATIVE; MANGANESE OXIDE; METALLOPORPHYRIN; OXIDE; OXYGEN; WATER;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION; THERMODYNAMICS;

HYDROXIDES; LIGANDS; MANGANESE COMPOUNDS; METALLOPORPHYRINS; MODELS, MOLECULAR; OXIDATION-REDUCTION; OXIDES; OXYGEN; THERMODYNAMICS; WATER;

EID: 56649109679     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic8013706     Document Type: Article

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