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Volumn 43, Issue 17, 2004, Pages 5198-5204

Radical autoxidation and autogenous O2 evolution in manganese-porphyrin catalyzed alkane oxidations with chlorite

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; ALKANE; CHLORINE DERIVATIVE; CHLORITE; CYCLOHEXANE; CYCLOHEXANOL; CYCLOHEXANONE; KETONE; MANGANESE DERIVATIVE; OXIDIZING AGENT; OXYGEN; OXYGEN RADICAL; PORPHYRIN DERIVATIVE; PORPHYRIN MANGANESE; UNCLASSIFIED DRUG;

EID: 4043183941     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049922j     Document Type: Article
Times cited : (121)

References (67)
  • 2
    • 0001146772 scopus 로고    scopus 로고
    • Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego
    • Meunier, B.; Robert, A.; Pratviel, G.; Bernadou, J. In The Porphyrin Handbook; Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego, 2000; Vol. 4, pp 119-187.
    • (2000) The Porphyrin Handbook , vol.4 , pp. 119-187
    • Meunier, B.1    Robert, A.2    Pratviel, G.3    Bernadou, J.4
  • 18
    • 4043179387 scopus 로고    scopus 로고
    • note
    • tBuPy, 4-tert-butylpyridine; (Por), generalized porphyrin dianion.
  • 21
    • 4043102942 scopus 로고    scopus 로고
    • note
    • 11,15,18 presumably by activating the "shunt" oxidant through a trans-axial ligand effect.
  • 33
    • 4043134088 scopus 로고    scopus 로고
    • note
    • - or its decomposition products.
  • 34
    • 1642588627 scopus 로고
    • Nygaard, O. F., Simic, M. G., Eds.; Academic Press: New York
    • Simic, M. G.; Hunter, E. P. L. In Radioprotectors and Anticarcinogens; Nygaard, O. F., Simic, M. G., Eds.; Academic Press: New York, 1983; pp 449-460.
    • (1983) Radioprotectors and Anticarcinogens , pp. 449-460
    • Simic, M.G.1    Hunter, E.P.L.2
  • 51
    • 4043098627 scopus 로고    scopus 로고
    • note
    • a(HOClO) = 1.72, and relevant bond energies; see Supporting Information.
  • 54
    • 4043118625 scopus 로고    scopus 로고
    • note
    • BDE(H-Cl) = 103.15 kcal/mol; BDE(Cy-H) = 95.6 kcal/mol.
  • 55
    • 4043139652 scopus 로고    scopus 로고
    • note
    • 27 [Mn(TDCPP)Cl] is assumed constant at 61 μM.
  • 64
    • 4043155225 scopus 로고    scopus 로고
    • note
    • .; see Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.