Manganese oxyl radical intermediates and O - O bond formation in photosynthetic oxygen evolution and a proposed role for the calcium cofactor in photosystem II

Journal of the American Chemical Society

Volumn 121, Issue 1, 1999, Pages 117-127

  Siegbahn, Per E M ^a   Crabtree, Robert H ^b  

^a STOCKHOLM UNIVERSITY   (Sweden)

^b YALE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CALCIUM; CHLORIDE; MANGANESE; RADICAL;

ARTICLE; CHELATION; COMPLEX FORMATION; ISOMERISM; NONHUMAN; OXIDATION REDUCTION REACTION; PHOTOSYNTHESIS; PHOTOSYSTEM II; PLANT; QUANTUM CHEMISTRY;

EID: 0033550515     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982290d     Document Type: Article

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51. 3, the oxyl is probably sufficiently low in energy so that state mixing can give the oxygen a significant radical character even in the ground state.