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note
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-1; R = 0.9999). On the basis of these rate constants, the full kinetic profiles were nicely simulated globally using HopKINSIM simulation program.
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43
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note
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Into a reaction mixture of 50 μM Mn(III)TMPyP and 520 μM carbamazepine (CBZ) in 50 mM pH 7.4 phosphate buffer, 300 μM of m-CPBA was added in six aliquots of 50 μM each at 2 min intervals. Quantitative analyses of the reaction products were performed by HPLC. (Detailed reaction conditions and analyses are available in Experimental Section.) Under these conditons, the conversion (based on oxidant consumed) of the olefin was 35% and the yield of epoxide was 93%. In the presence of 600 μM of nitrite ion, less than 3% of the epoxide was found.
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44
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note
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18O (95%). (Detailed reaction conditions and experimental data are available in the Experimental Section.)
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