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Volumn 119, Issue 27, 1997, Pages 6269-6273

Detection and characterization of an oxomanganese(V) porphyrin complex by rapid-mixing stopped-flow spectrophotometry

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; BENZOIC ACID DERIVATIVE; CARBAMAZEPINE; DEUTERIUM OXIDE; EPOXIDE; MANGANESE OXIDE; NITRITE; OXIDIZING AGENT; OXYGEN; PORPHYRIN DERIVATIVE;

EID: 0030804770     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962605u     Document Type: Article
Times cited : (407)

References (49)
  • 6
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    • Montanari, F., Casella, L., Eds.; Kluwer: Dordrecht, The Netherlands
    • (b) Mlodnika, T.; James, B. R. In Metalloporphyrin Catalyzed Oxidations; Montanari, F., Casella, L., Eds.; Kluwer: Dordrecht, The Netherlands, 1994; p 121.
    • (1994) Metalloporphyrin Catalyzed Oxidations , pp. 121
    • Mlodnika, T.1    James, B.R.2
  • 7
    • 3543009735 scopus 로고
    • King, T. E., Mason, H. S., Morrison, M., Eds.; Liss: New York
    • (a) Mann, T. In Oxidases and Related Redox Systems; King, T. E., Mason, H. S., Morrison, M., Eds.; Liss: New York, 1988; pp 29-49.
    • (1988) Oxidases and Related Redox Systems , pp. 29-49
    • Mann, T.1
  • 42
    • 16944365856 scopus 로고    scopus 로고
    • note
    • -1; R = 0.9999). On the basis of these rate constants, the full kinetic profiles were nicely simulated globally using HopKINSIM simulation program.
  • 43
    • 16944367053 scopus 로고    scopus 로고
    • note
    • Into a reaction mixture of 50 μM Mn(III)TMPyP and 520 μM carbamazepine (CBZ) in 50 mM pH 7.4 phosphate buffer, 300 μM of m-CPBA was added in six aliquots of 50 μM each at 2 min intervals. Quantitative analyses of the reaction products were performed by HPLC. (Detailed reaction conditions and analyses are available in Experimental Section.) Under these conditons, the conversion (based on oxidant consumed) of the olefin was 35% and the yield of epoxide was 93%. In the presence of 600 μM of nitrite ion, less than 3% of the epoxide was found.
  • 44
    • 16944366659 scopus 로고    scopus 로고
    • note
    • 18O (95%). (Detailed reaction conditions and experimental data are available in the Experimental Section.)
  • 48
    • 0029654151 scopus 로고
    • For a discussion of the oxygenation of toluene by permanganate, see: Gardner, K.,A.; Mayer, J. M. Science 1995, 269, 1849-1851.
    • (1995) Science , vol.269 , pp. 1849-1851
    • Gardner, K.A.1    Mayer, J.M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.