Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-MnV-oxo species and apparent disproportionation equilibrium constants for porphyrin-MnIV-oxo species

Journal of the American Chemical Society

Volumn 127, Issue 18, 2005, Pages 6573-6582

  Zhang, Rui ^a   Horner, John H ^a   Newcomb, Martin ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; AMINES; BENZENE; CATALYSIS; COMPLEXATION; LASER APPLICATIONS; MANGANESE; ORGANIC SOLVENTS; OXIDATION; PORPHYRINS; RATE CONSTANTS; REACTION KINETICS;

CHLORATE COMPLEXES; EQUILIBRIUM CONSTANTS; LASER FLASH PHOTOLYSIS (LFP); TRIPHENYLAMINE;

PHOTOLYSIS;

5,10,15,20 TETRAKIS(4 METHYLPYRIDINIUM)PORPHYRIN; 5,10,15,20 TETRAKIS(PENTAFLUOROPHENYL)PORPHYRIN; 5,10,15,20 TETRAPHENYLPORPHYRIN; ACETONITRILE; AMINE; ETHYLBENZENE; MANGANESE; OXYGEN; PORPHYRIN DERIVATIVE; TRIPHENYLAMINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; OXIDATION; PHOTOLYSIS;

KINETICS; MANGANESE; METALLOPORPHYRINS; OXIDATION-REDUCTION; PHOSPHINES; PHOTOLYSIS; PORPHYRINS; SPECTROMETRY, FLUORESCENCE; STRUCTURE-ACTIVITY RELATIONSHIP;

EID: 18644380815     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja045042s     Document Type: Article

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