Aromatic hydroxylation in a copper bis(imine) complex mediated by a μ-η2:η2 peroxo dicopper core: A mechanistic scenario

Chemistry - A European Journal

Volumn 14, Issue 31, 2008, Pages 9714-9729

  Sander, Ole ^a   Henß, Anja ^b   Näther, Christian ^a   Würtele, Christian ^b   Holthausen, Max C ^c   Schindler, Siegfried ^b   Tuczek, Felix ^a  

^a UNIVERSITY OF KIEL   (Germany)

^b JUSTUS LIEBIG UNIVERSITY   (Germany)

^c GOETHE UNIVERSITY   (Germany)

Author keywords

Copper; Hydroxylation; N ligands; O O activation; Reaction mechanisms

Indexed keywords

ABSORPTION; ACETONITRILE; ACTIVATION ENERGY; BINDING ENERGY; CHEMICAL REACTIONS; COPPER; COPPER COMPOUNDS; HYDROXYLATION; LIGANDS; METHANOL; MOLECULAR SPECTROSCOPY; NITROGEN COMPOUNDS; OXYGENATION; REACTION KINETICS; STRUCTURAL ANALYSIS;

A STABLES; ARENE RING; AROMATIC HYDROXYLATIONS; DICOPPER; ELECTROPHILIC ATTACKS; EXPERIMENTAL OBSERVATIONS; HYDROXYLATION REACTIONS; KINETIC ANALYSES; KINETIC ISOTOPE EFFECTS; LIMITING STEPS; MECHANISTIC STUDIES; N LIGANDS; O-O ACTIVATION; OPTICAL ABSORPTIONS; ORBITAL INTERACTIONS; RATELIMITING STEPS; REACTION MECHANISMS; STARTING MATERIALS; STERICALLY CONGESTED; TRANSITION STATES;

RATE CONSTANTS;

COPPER; IMINE; OXYGEN;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; HYDROXYLATION; INFRARED SPECTROPHOTOMETRY; KINETICS; RAMAN SPECTROMETRY; SPECTROPHOTOMETRY; X RAY CRYSTALLOGRAPHY;

COPPER; CRYSTALLOGRAPHY, X-RAY; HYDROXYLATION; IMINES; KINETICS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXYGEN; SPECTROPHOTOMETRY; SPECTROPHOTOMETRY, INFRARED; SPECTRUM ANALYSIS, RAMAN;

EID: 55049084721     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800799     Document Type: Article

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