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Volumn 37, Issue 26, 1998, Pages 6597-6605

Modeling Tyrosinase Monooxygenase Activity. Spectroscopic and Magnetic Investigations of products Due to Reactions between Copper(I) Complexes of Xylyl-Based Dinucleating Ligands and Dioxygen: Aromatic Ring Hydroxylation and Irreversible Oxidation Products

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EID: 0001545218     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9713689     Document Type: Article
Times cited : (80)

References (78)
  • 43
    • 0040012902 scopus 로고
    • Kubas, G. Inorg. Synth. 1979, 19, 90; 1990, 28, 68.
    • (1990) Inorg. Synth. , vol.28 , pp. 68
  • 52
    • 1842645781 scopus 로고    scopus 로고
    • Reactions between isolated dicopper(I) complexes and dioxygen give rise to only phenoxo-/hydroxo-bridged product
    • Reactions between isolated dicopper(I) complexes and dioxygen give rise to only phenoxo-/hydroxo-bridged product.
  • 65
    • 85088542499 scopus 로고    scopus 로고
    • note
    • 2O.
  • 66
    • 1842797032 scopus 로고    scopus 로고
    • note
    • 2 resulting in the formation of chlorocopper(II) compounds.
  • 78
    • 1842797033 scopus 로고    scopus 로고
    • The reaction resembles a simple electrophilic aromatic substitution and might be expected to proceed via a cationic intermediate akin to a "σ complex" that would be preferentially stabilized in polar solvent. We are grateful to one of the reviewers for suggesting this
    • The reaction resembles a simple electrophilic aromatic substitution and might be expected to proceed via a cationic intermediate akin to a "σ complex" that would be preferentially stabilized in polar solvent. We are grateful to one of the reviewers for suggesting this.


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