Do Heavy Nuclei See Light at the End of the Tunnel?

Angewandte Chemie - International Edition

Volumn 43, Issue 4, 2004, Pages 398-401

  Berger, Robert ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

Carbenes; Density functional calculations; IR spectroscopy; Matrix isolation; Tunneling

Indexed keywords

ELECTRON TUNNELING; LOW TEMPERATURE EFFECTS;

HEAVY NUCLEI; RING EXPANSION;

ORGANIC COMPOUNDS;

(1 METHYLCYCLOBUTYL)FLUOROCARBENE; CARBENOID; UNCLASSIFIED DRUG;

CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; INFRARED SPECTROSCOPY; LOW TEMPERATURE PROCEDURES; PHOTOCHEMISTRY; REVIEW;

EID: 0842285889     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200301675     Document Type: Review

References (61)

1. F. Hund, Z. Phys. 1927, 40, 742-764.
2. P. Zuev, R. Sheridan, T. Albu, D. Truhlar, D. Hrovat, W. Borden, Science 2003, 299, 867-870.
3. F. Hund, Z. Phys. 1927, 43, 805-826.
4. a) M. Quack, Angew. Chem. 1989, 101, 588-604; Angew. Chem. Int. Ed. Engl. 1989, 28, 571-586;
5. a) M. Quack, Angew. Chem. 1989, 101, 588-604; Angew. Chem. Int. Ed. Engl. 1989, 28, 571-586;
6. b) M. Quack, Angew. Chem. 2002, 114, 4812-4825; Angew. Chem. Int. Ed. 2002, 41, 4618-4630.
7. b) M. Quack, Angew. Chem. 2002, 114, 4812-4825; Angew. Chem. Int. Ed. 2002, 41, 4618-4630.
8. a) R. Berger, M. Quack, J. Chem. Phys. 2000, 112, 3148-3158;
9. b) R. Berger, M. Quack, ChemPhysChem 2000, 1, 57-60;
10. c) J. Laerdahl, P. Schwerdtfeger, ChemPhysChem 2000, 1, 60-62;
11. d) R. Berger, M. Quack, G. Tschumper, Helv. Chim. Acta 2000, 83, 1919-1950;
12. e) M. Quack, J. Stohner, Phys. Rev. Lett. 2000, 84, 3807-3810;
13. f) J. Laerdahl, P. Schwerdtfeger, H. Quiney, Phys. Rev. Lett. 2000, 84, 3811-3814;
14. g) R. Berger, M. Quack, J. Stohner, Angew. Chem. 2001, 113, 1716-1719; Angew. Chem. Int. Ed. 2001, 40, 1667-1670;
15. g) R. Berger, M. Quack, J. Stohner, Angew. Chem. 2001, 113, 1716-1719; Angew. Chem. Int. Ed. 2001, 40, 1667-1670;
16. h) R. Berger, M. Gottselig, M. Quack, M. Willeke, Angew. Chem. 2001, 113, 4342-4345; Angew. Chem. Int. Ed. 2001, 40, 4195-4198;
17. h) R. Berger, M. Gottselig, M. Quack, M. Willeke, Angew. Chem. 2001, 113, 4342-4345; Angew. Chem. Int. Ed. 2001, 40, 4195-4198;
18. i) M. Gottselig, D. Luckhaus, M. Quack, J. Stohner, M. Willeke, Helv. Chim. Acta 2001, 84, 1846-1861;
19. j) T. Kitayama, H. Kiyonaga, K. Morihashi, O. Takahashi, O. Kikuchi, J. Mol. Struct. 2002, 589-590, 183-193;
20. k) A. Hennum, T. Helgaker, W. Klopper, Chem. Phys. Lett. 2002, 354, 274-282;
21. l) R. Berger, Phys. Chem. Chem. Phys. 2003, 5, 12-17;
22. m) P. Schwerdtfeger, J. Gierlich, T. Bollwein, Angew. Chem. 2003, 115, 1331-1334; Angew. Chem. Int. Ed. 2003, 42, 1293-1296;
23. m) P. Schwerdtfeger, J. Gierlich, T. Bollwein, Angew. Chem. 2003, 115, 1331-1334; Angew. Chem. Int. Ed. 2003, 42, 1293-1296;
24. n) F. Faglioni, P. Lazzeretti, Phys. Rev. A 2003, 67, 032101;
25. o) G. Laubender, R. Berger, ChemPhysChem 2003, 4, 395-399;
26. p) A. Soncini, F. Faglioni, P. Lazzeretti, Phys. Rev. A 2003, 68, 033402.
27. G. Gamov, Z. Phys. 1928, 51, 204-212.
28. R. Gurney, E. Condon, Phys. Rev. 1929, 33, 127-140.
29. a) H. Eyring, J. Chem. Phys. 1935, 3, 107;
30. b) M. Evans, M. Polanyi, Trans. Faraday Soc. 1935, 31, 857.
31. a) K. Laidler, M. King, J. Phys. Chem. 1983, 87, 2657-2664;
32. b) W. Miller, Faraday Discuss. 1998, 110, 1-21;
33. c) G. Petersson, Theor. Chem. Acc. 2000, 103, 190-195;
34. d) B. Garrett, Theor. Chem. Acc. 2000, 103, 200-204 and references therein.
35. E. Wigner, Z. Phys. Chem. Abt. B 1932, 19, 203-216.
36. E. Wigner, Trans. Faraday Soc. 1938, 34, 29-41.
37. J. Troe in Tunneling, Vol. 19 (Eds.: J. Jortner, B. Pullman), Reidel, Dordrecht, 1986, pp. 149-164.
38. For a recent review on condensed-phase proton- and hydrogen-transfer reactions see: M. Basilevsky, M. Verner, Russ. Chem. Rev. 2003, 72, 1-33.
39. Z. Smedarchina, W. Siebrand, A. Fernandez-Ramoz, Q. Cui, J. Am. Chem. Soc. 2003, 125, 243-251.
40. B. Carpenter, J. Am. Chem. Soc. 1983, 105, 1700-1701 and references therein.
41. A. Orendt, B. Arnold, J. Radziszewski, J. Facelli, K. Malsch, H. Strub, D. Grant, J. Michl, J. Am. Chem. Soc. 1988, 110, 2648-2650.
42. B. Arnold, J. Radziszewski, A. Campion, S. Perry, J. Michl, J. Am. Chem. Soc. 1991, 113, 692-694.
43. G. Maier, R. Wolf, H. Kalinowski, Angew. Chem. 1992, 104, 764-766; Angew. Chem. Int. Ed. Engl. 1992, 31, 738-740.
44. G. Maier, R. Wolf, H. Kalinowski, Angew. Chem. 1992, 104, 764-766; Angew. Chem. Int. Ed. Engl. 1992, 31, 738-740.
45. P. Carsky, J. Michl, Theor. Chim. Acta 1992, 84, 125-133.
46. A. Hallou, L. Schriver-Mazzuoli, A. Schriver, P. Chaquin, Chem. Phys. 1998, 237, 251-264.
47. G. Maier, H. Reisenauer, M. de Marco, Chem. Eur. J. 2000, 6, 800-808.
48. H. Frei, G. Pimentel, J. Phys. Chem. 1981, 85, 3355-3360.
49. M. Sponsler, R. Jain, F. Coms, D. Dougherty, J. Am. Chem. Soc. 1989, 111, 2240-2252.
50. W. Sander, G. Bucher, F. Reichel, D. Cremer, J. Am. Chem. Soc. 1991, 113, 5311-5322.
51. S. Buchwalter, G. Closs, J. Am. Chem. Soc. 1979, 101, 4688-4694.
52. W. Siebrand, T. Wildman, Acc. Chem. Res. 1986, 19, 238-243.
53. D. Truhlar, B. Garrett, Annu. Rev. Phys. Chem. 1984, 35, 159-189.
54. Y. Liu, G. Lynch, T. Truong, D. Lu, D. Truhlar, B. Garrett, J. Am. Chem. Soc. 1993, 115, 2408-2415 and references therein.
55. a) B. Fehrensen, D. Luckhaus, M. Quack, Z. Phys. Chem. 1999, 209, 1-19;
56. b) D. Luckhaus, J. Chem. Phys. 2000, 113, 1329-1347;
57. c) S. Carter, N. Handy, J. Chem. Phys. 2000, 113, 987-993;
58. d) R. Chen, G. Ma, H. Guo, Chem. Phys. Lett. 2000, 320, 567-574;
59. e) V. Benderskii, I. Irgibaeva, E. Vetoshkin, H. Trommsdorff, Chem. Phys. 2000, 262, 369-391;
60. f) J. Koput, S. Carter, N. Handy, J. Chem. Phys. 2001, 115, 8345-8350;
61. g) Y. Guo, D. Thompson, J. Phys. Chem. A 2002, 106, 8374-8377.