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33746286213
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note
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The assignment of Matoba et al. is only correct for the deoxy and metI forms, which are not relevant for catalysis.
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31
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33746286497
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note
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2, the differences in bond lengths are less distinct, but the Cu-N(His63) bond length is still the longest (2.20 vs. 2.19 and 2.14 Å). In the oxy form that is generated in the presence of dithiotreitol, the CuA-N(His63) bond is again much longer than the other ones (2.37 vs. 2.15 and 2.08 Å).
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32
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0032511358
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