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33746365547
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note
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In cases where the P:O ratio differs significantly from 1:1, the equilibrium presumably occurs, but is difficult to detect due to the predominance of one isomer and the broadness of the UV-vis features.
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12
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33645874211
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Hatcher, L. Q.; Vance, M. A.; Sarjeant, A. A. N.; Solomon, E. I.; Karlin, K. D. Inorg. Chem. 2006, 45, 3004-3013.
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13
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33746330027
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note
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- was successful only in acetone at -87 °C with slow addition of up to 1.0 equiv of anion per dimer. The acetate anion behaves similarly, but its P species is too unstable to allow a complete titration.
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14
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33746379388
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note
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2 (cf. Supporting Information).
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15
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33746346271
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note
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2 species.
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16
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33746353195
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note
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Scatterers differing by Z ± 1 are not distinguishable in an EXAFS analysis. For these data, the resolution of such scatterers is ∼0.12 Å.
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17
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0033575068
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Stack, T.D.P.5
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18
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33746331189
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note
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2 parameters were constrained to have equal values during refinement.
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19
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33746351173
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note
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DFT optimizations were performed in vacuo with a B3LYP function, a 6-3IG* basis set, and a broken-symmetry wave function for the singlet ground state.
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20
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0035851636
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