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Volumn 128, Issue 29, 2006, Pages 9268-9269

Reversible O-O bond cleavage in copper-dioxygen isomers: Impact of anion basicity

Author keywords

[No Author keywords available]

Indexed keywords

ANION; COPPER COMPLEX; METAL COMPLEX; OXYGEN;

EID: 33746333886     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja061132g     Document Type: Article
Times cited : (60)

References (24)
  • 11
    • 33746365547 scopus 로고    scopus 로고
    • note
    • In cases where the P:O ratio differs significantly from 1:1, the equilibrium presumably occurs, but is difficult to detect due to the predominance of one isomer and the broadness of the UV-vis features.
  • 13
    • 33746330027 scopus 로고    scopus 로고
    • note
    • - was successful only in acetone at -87 °C with slow addition of up to 1.0 equiv of anion per dimer. The acetate anion behaves similarly, but its P species is too unstable to allow a complete titration.
  • 14
    • 33746379388 scopus 로고    scopus 로고
    • note
    • 2 (cf. Supporting Information).
  • 15
    • 33746346271 scopus 로고    scopus 로고
    • note
    • 2 species.
  • 16
    • 33746353195 scopus 로고    scopus 로고
    • note
    • Scatterers differing by Z ± 1 are not distinguishable in an EXAFS analysis. For these data, the resolution of such scatterers is ∼0.12 Å.
  • 18
    • 33746331189 scopus 로고    scopus 로고
    • note
    • 2 parameters were constrained to have equal values during refinement.
  • 19
    • 33746351173 scopus 로고    scopus 로고
    • note
    • DFT optimizations were performed in vacuo with a B3LYP function, a 6-3IG* basis set, and a broken-symmetry wave function for the singlet ground state.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.