Is the bis(μ-oxo)dicopper core capable of hydroxylating an arene?

Angewandte Chemie - International Edition

Volumn 38, Issue 8, 1999, Pages 1139-1142

  Holland, Patrick L ^a   Rodgers, Kenton R ^b   Tolman, William B ^a  

^a University of Minnesota   (United States)

^b NORTH DAKOTA STATE UNIVERSITY   (United States)

Author keywords

Copper; Hydroxylations; Monooxygenases; Oxidases; Tyrosinase

Indexed keywords

COPPER DERIVATIVE; MONOPHENOL MONOOXYGENASE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

ARTICLE; DECOMPOSITION; HYDROXYLATION; RAMAN SPECTROMETRY; REACTION ANALYSIS;

EID: 0033583463     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1139::AID-ANIE1139>3.0.CO;2-0     Document Type: Article

References (42)

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31. 2 = 0.0742, and GOF = 1.039 for 3038 independent reflections with I > 2σ(I), 278 parameters, and 45 restraints. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-105 596. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
32. The extinction coefficient (in THF solution) was determined with 3c, because its stability was greater than that of 3a. Intense pyridine-to-metal charge-transfer bands obscured the presumed bis(μ-oxo)dicopper band at about 300 nm.
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