Spectroscopic evidence for a high-spin Br-Fe(IV)-OxO intermediate in the α-ketoglutarate-dependent halogenase CytC3 from Streptomyces

Journal of the American Chemical Society

Volumn 129, Issue 44, 2007, Pages 13408-13409

  Fujimori, Danica Galonić ^a   Barr, Eric W ^b   Matthews, Megan L ^b   Koch, Gretchen M ^b   Yonce, J Ryan ^c   Walsh, Christopher T ^a   Bollinger Jr , J Martin ^b   Krebs, Carsten ^b   Riggs Gelasco, Pamela J ^c  

^a HARVARD MEDICAL SCHOOL   (United States)

^b PENNSYLVANIA STATE UNIVERSITY   (United States)

^c School of Business   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2 OXOGLUTARIC ACID; BACTERIAL ENZYME; BROMINE; HALOGENASE; IRON; OXYGEN; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; ENZYME ANALYSIS; ENZYME MECHANISM; MOLECULAR INTERACTION; MOSSBAUER SPECTROSCOPY; NONHUMAN; REACTION ANALYSIS; SPECTROSCOPY; STREPTOMYCES;

BROMINE; CATALYSIS; CYTOCHROME C GROUP; FERRIC COMPOUNDS; HALOGENATION; KETOGLUTARIC ACIDS; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; OXIDOREDUCTASES; SPECTRUM ANALYSIS; STEREOISOMERISM; STREPTOMYCES; X-RAYS;

EID: 35948990530     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja076454e     Document Type: Article

References (25)

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