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note
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Abbreviations used: tmc 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane; N4Py N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl) methylamine; Bn-tpen N-benzyl-N,N′,N′-tris(2-pyridylme-thyl)ethane- 1,2-diamine.
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0002347508
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(Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, New York, chap. 55
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For some examples of the electrochemical studies of high-valent iron(IV)-oxo porphyrins, see: a) K. M. Kadish, E. V. Caemelbecke, G. Royal in The Porphyrin Handbook, Vol. 8 (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, New York, 2000, chap. 55, pp. 1-111;
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IV=O], of heme-containing peroxidases have been reported: a) M. T. Green, J. H. Dawson, H. B. Gray, Science 2004, 304, 1653-1656;
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note
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We only observed the reduction of the iron(IV)-oxo complexes and did not identify the products and reaction pathways during the electrochemical reduction. Detailed electrochemical studies of mononuclear nonheme iron(IV)-oxo species are underway and will be presented elsewhere.
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