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Volumn 45, Issue 24, 2006, Pages 3992-3995

Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

Author keywords

Coordination modes; Enzyme models; Iron; N ligands; Oxygen

Indexed keywords

COMPLEXATION; ELECTROCHEMISTRY; MASS SPECTROMETRY; MATHEMATICAL MODELS; OXYGEN; SPECTROPHOTOMETRY;

EID: 33746287535     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200504422     Document Type: Article
Times cited : (58)

References (45)
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    • note
    • Abbreviations used: tmc 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane; N4Py N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl) methylamine; Bn-tpen N-benzyl-N,N′,N′-tris(2-pyridylme-thyl)ethane- 1,2-diamine.
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    • (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, New York, chap. 55
    • For some examples of the electrochemical studies of high-valent iron(IV)-oxo porphyrins, see: a) K. M. Kadish, E. V. Caemelbecke, G. Royal in The Porphyrin Handbook, Vol. 8 (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, New York, 2000, chap. 55, pp. 1-111;
    • (2000) The Porphyrin Handbook , vol.8 , pp. 1-111
    • Kadish, K.M.1    Caemelbecke, E.V.2    Royal, G.3
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    • IV=O], of heme-containing peroxidases have been reported: a) M. T. Green, J. H. Dawson, H. B. Gray, Science 2004, 304, 1653-1656;
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    • note
    • We only observed the reduction of the iron(IV)-oxo complexes and did not identify the products and reaction pathways during the electrochemical reduction. Detailed electrochemical studies of mononuclear nonheme iron(IV)-oxo species are underway and will be presented elsewhere.


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