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Volumn 44, Issue 15, 2005, Pages 2255-2258

Axial coordination of carboxylate activates the non-heme FeIV=O unit

Author keywords

Bioinorganic chemistry; Carboxylate ligands; High valent compounds; Iron; Oxo ligands

Indexed keywords

ENZYMES; IRON; OXYGEN;

EID: 17644419347     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200462631     Document Type: Article
Times cited : (92)

References (25)
  • 10
    • 17644380427 scopus 로고    scopus 로고
    • note
    • Abbreviations used: Bn-TPEN = N-benzyl-N,N′,N′-tris(2- pyridylmethyl)-1,2-diaminoethane, N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2- pyridyl)methylamine, OTf = trifluoromethylsulfonate (or triflate) anion, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (or tetra(N-methyl) cyclam), TPA = N,N,N-tris(2-pyridylmethyl)amine.
  • 11
    • 17644419449 scopus 로고    scopus 로고
    • University of Minnesota, unpublished results
    • E. J. Klinker, L. Que, Jr., University of Minnesota, unpublished results.
    • Klinker, E.J.1    Que Jr., L.2
  • 16
    • 17644381402 scopus 로고    scopus 로고
    • note
    • [25] The lack of more detailed structural information on this interesting complex however makes it difficult to draw firm conclusions about its properties.
  • 20
    • 0030763479 scopus 로고    scopus 로고
    • Gross and co-workers have also reported that coordination of an axial carboxylate to an oxoiron(IV) porphyrin cation radical complexes similarly enhances its reactivity:Z. Gross, S. Nimri, C. M. Barzilay, L. Simkhovich, J. Biol. Inorg. Chem. 1997, 2, 492.
    • (1997) J. Biol. Inorg. Chem. , vol.2 , pp. 492
    • Gross, Z.1    Nimri, S.2    Barzilay, C.M.3    Simkhovich, L.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.