Effects of thioether substituents on the O2 reactivity of β-diketiminate-Cu(I) complexes: Probing the role of the methionine ligand in copper monooxygenases

Journal of the American Chemical Society

Volumn 128, Issue 10, 2006, Pages 3445-3458

  Aboelella, Nermeen W ^a   Gherman, Benjamin F ^a   Hill, Lyndal M R ^a   York, John T ^a   Holm, Nicole ^a   Young Jr , Victor G ^a   Cramer, Christopher J ^a   Tolman, William B ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; NITROGEN COMPOUNDS; NUCLEAR MAGNETIC RESONANCE; OXIDATION; PROTEINS;

HISTIDINE IMIDAZOLES; MONOOXYGENASES; THIOETHER GROUP;

ETHERS;

COPPER COMPLEX; LIGAND; METAL COMPLEX; METHIONINE; OXYGEN; SULFIDE; UNSPECIFIC MONOOXYGENASE;

ABSORPTION SPECTROSCOPY; ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ENERGY; ENZYME ACTIVITY; GEOMETRY; KINETICS; OXYGENATION; PROTON NUCLEAR MAGNETIC RESONANCE; RAMAN SPECTROMETRY; THERMODYNAMICS; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

COPPER; CRYSTALLOGRAPHY, X-RAY; DOPAMINE BETA-HYDROXYLASE; HISTIDINE; IMIDAZOLES; LIGANDS; METHIONINE; MIXED FUNCTION OXYGENASES; MODELS, MOLECULAR; MULTIENZYME COMPLEXES; NUCLEAR MAGNETIC RESONANCE, BIOMOLECULAR; OXYGEN; SPECTROPHOTOMETRY, ULTRAVIOLET; SPECTRUM ANALYSIS, RAMAN; SULFIDES; THERMODYNAMICS;

EID: 33644952526     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057745v     Document Type: Article

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