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The procedure used was adapted from one kindly provided to us by R. F. Jordan, University of Chicago.
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note
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2 corresponds to the major (85%) component of the disordered structure. The value for the minor component is 51.75(17)°. For details, see the Experimental Section and the Supporting Information (CIF file).
-
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54
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fPr2)Cu(MeCN)], Δ = |(∠N1-Cu1-N1S) - (∠N5-Cu1-N1S)| = |128.19(11)° - 133.75(10)°| = 5.6°.
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In the cathodic region each complex exhibited an irreversible reduction.
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