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Volumn 41, Issue 24, 2002, Pages 6307-6321

Copper chemistry of β-diketiminate ligands: Monomer/dimer equilibria and a new class of bis(μ-oxo)dicopper compounds

Author keywords

[No Author keywords available]

Indexed keywords

BETA DIKETIMINATE; COPPER; COPPER COMPLEX; DIMER; ISOTOPE; LIGAND; MONOMER; ORGANOMETALLIC COMPOUND; UNCLASSIFIED DRUG;

EID: 0037010964     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020369k     Document Type: Article
Times cited : (137)

References (76)
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    • University of Chicago
    • The procedure used was adapted from one kindly provided to us by R. F. Jordan, University of Chicago.
    • Jordan, R.F.1
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    • note
    • 2 corresponds to the major (85%) component of the disordered structure. The value for the minor component is 51.75(17)°. For details, see the Experimental Section and the Supporting Information (CIF file).
  • 59
    • 0011835599 scopus 로고    scopus 로고
    • note
    • fPr2)Cu(MeCN)], Δ = |(∠N1-Cu1-N1S) - (∠N5-Cu1-N1S)| = |128.19(11)° - 133.75(10)°| = 5.6°.
  • 60
    • 6844239208 scopus 로고    scopus 로고
    • 6 as electrolyte, according to Table 1 in the following: Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877-910.
    • (1996) Chem. Rev. , vol.96 , pp. 877-910
    • Connelly, N.G.1    Geiger, W.E.2
  • 61
    • 0011840470 scopus 로고    scopus 로고
    • note
    • In the cathodic region each complex exhibited an irreversible reduction.
  • 63
    • 0011835601 scopus 로고    scopus 로고
    • note
    • An axial signal from a monocopper(II) species was observed for the warmed solutions, but values for spin quantitation were only between 1 and 7% (versus an external standard).
  • 68
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    • note
    • Related steric arguments have been presented to rationalize differences in polymerization reactivity of β-diketiminate complexes of Zn(II); see ref 14.
  • 71
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    • Bruker Analytical X-ray Systems: Madison, WI
    • SAINT V6.01; Bruker Analytical X-ray Systems: Madison, WI, 1999.
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    • Blessing, R.1
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.