A structural model of the type 1 copper protein active site: N2S(thiolate)s(thioether) ligation in a Cu(II) complex [23]

Journal of the American Chemical Society

Volumn 122, Issue 26, 2000, Pages 6331-6332

  Holland, Patrick L ^a   Tolman, William B ^a  

^a University of Minnesota ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; COPPER COMPLEX; PROTEIN; SULFIDE;

CHEMICAL INTERACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; GEOMETRY; LETTER; SYNTHESIS;

EID: 0034608976     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja001328v     Document Type: Letter

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5. Representative literature: (a) Palmer, A. E.; Randall, D. W.; Xu, F.; Solomon. E. I. J. Am. Chem. Soc. 1999, 121, 7138. (b) Buning, C.; Canters, G. W.; Comba, P.; Dennison, C.; Jeuken, L.; Melter, M.; Sanders-Loehr, J. J. Am. Chem. Soc. 2000, 122, 204. (c) Pierloot, K.; De Kerpel, J. O. A.; Ryde, U.; Olsson, M. H. M.; Roos, B. O. J. Am. Chem. Soc. 1998, 120, 13156. (d) LaCroix, L. B.; Randall, D. W.; Nersissian, A. M.; Hoitink, C. W. G.; Canters, G. W.; Valentine, J. S.; Solomon, E. I. J. Am. Chem. Soc. 1998, 120, 9621.
6. Representative literature: (a) Palmer, A. E.; Randall, D. W.; Xu, F.; Solomon. E. I. J. Am. Chem. Soc. 1999, 121, 7138. (b) Buning, C.; Canters, G. W.; Comba, P.; Dennison, C.; Jeuken, L.; Melter, M.; Sanders-Loehr, J. J. Am. Chem. Soc. 2000, 122, 204. (c) Pierloot, K.; De Kerpel, J. O. A.; Ryde, U.; Olsson, M. H. M.; Roos, B. O. J. Am. Chem. Soc. 1998, 120, 13156. (d) LaCroix, L. B.; Randall, D. W.; Nersissian, A. M.; Hoitink, C. W. G.; Canters, G. W.; Valentine, J. S.; Solomon, E. I. J. Am. Chem. Soc. 1998, 120, 9621.
7. Representative literature: (a) Palmer, A. E.; Randall, D. W.; Xu, F.; Solomon. E. I. J. Am. Chem. Soc. 1999, 121, 7138. (b) Buning, C.; Canters, G. W.; Comba, P.; Dennison, C.; Jeuken, L.; Melter, M.; Sanders-Loehr, J. J. Am. Chem. Soc. 2000, 122, 204. (c) Pierloot, K.; De Kerpel, J. O. A.; Ryde, U.; Olsson, M. H. M.; Roos, B. O. J. Am. Chem. Soc. 1998, 120, 13156. (d) LaCroix, L. B.; Randall, D. W.; Nersissian, A. M.; Hoitink, C. W. G.; Canters, G. W.; Valentine, J. S.; Solomon, E. I. J. Am. Chem. Soc. 1998, 120, 9621.
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13. Synthetic type 1 copper protein design efforts: Hellinga, H. W. J. Am. Chem. Soc. 1998, 120, 10055 and references therein.
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17. For synthetic procedures and complete characterization data, see the Supporting Information.
18. 1/2 = -0.18 V vs NHE.
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23. -1. Bowen, L. L.; Holland, P. L.; Tolman, W. B. Unpublished results.
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25. -1 is due to copper-sulfur stretching: Randall, D. W.; DeBeer, S.; Holland, P. L.; Hedman, B.; Hodgson, K. O.; Tolman, W. B.; Solomon, E. I. Submitted for publication.