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Volumn 24, Issue 13, 2005, Pages 3321-3334

Intramolecular C-H activation reactions derived from a terminal titanium neopentylidene functionality. redox-controlled 1,2-addition and α-hydrogen abstraction reactions

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTION REACTIONS; COUPLING CONSTANTS; INTRAMOLECULAR REACTIONS; TITANIUM NEOPNETYLIDENE;

EID: 23144466909     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049318g     Document Type: Article
Times cited : (60)

References (108)
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    • (d) De With, J.; Horton, A. D. Angew. Chem., Int. Ed. Engl. 1993, 32, 903-905. A terminal imido complex of cobalt was recently isolated and found to undergo intramolecular C-H activation:
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    • De With, J.1    Horton, A.D.2
  • 52
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    • (2002) Coord. Chem. Rev. , pp. 233-234
    • Piers, W.E.1    Emslie, D.J.H.2
  • 57
    • 85168647471 scopus 로고    scopus 로고
    • (c) Fekl, U.; Goldberg, K. I. Adv. Inorg. Chem. 2003, 54, 259-320. C-H activation reactions have been reported for analogous β-diketiminate Ir-hydride complexes:
    • (2003) Adv. Inorg. Chem. , vol.54 , pp. 259-320
    • Fekl, U.1    Goldberg, K.I.2
  • 62
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    • Double C-H activation of two 1° carbons has been documented recently for electron-deficient Rh(III) systems: (a) Dorta, R.; Stevens, E. D.; Nolan, S. P. J. Am. Chem. Soc. 2004, 126, 5054-5055.
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 5054-5055
    • Dorta, R.1    Stevens, E.D.2    Nolan, S.P.3
  • 85
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    • 23144442066 scopus 로고    scopus 로고
    • note
    • 2 and filtered to remove AgCl, and the filtrate was dried under reduced pressure to afford pure product.
  • 91
    • 0001348064 scopus 로고    scopus 로고
    • Similar spectroscopic features have been suggested for 1-aza-1,3-diene ligands containing α-hydrogens which are bonded to titanium: Scholz, J.; Kahlert, S. Gorls, H. Organometallics 1998, 17, 2876-2884.
    • (1998) Organometallics , vol.17 , pp. 2876-2884
    • Scholz, J.1    Kahlert, S.2    Gorls, H.3
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    • note
    • 6e was used as the alkylating reagent.
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    • Experimental Organometallic Chemistry; Wayda, A. L., Darensbourg, M. Y., Eds.; American Chemical Society; Washington, DC
    • For a general description of the equipment and techniques used in carrying out this chemistry, see: Burger, B. J.; Bercaw, J. E. In Experimental Organometallic Chemistry; Wayda, A. L., Darensbourg, M. Y., Eds.; ACS Symposium Series 357; American Chemical Society; Washington, DC, 1987; pp 79-98.
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    • Bruker Analytical X-ray Systems, Madison, WI
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.