Intramolecular C-H activation by inferred terminal cobalt imido intermediates

Journal of the American Chemical Society

Volumn 125, Issue 15, 2003, Pages 4440-4441

  Thyagarajan, Sunita ^a   Shay, Daniel T ^a   Incarvito, Christopher D ^a   Rheingold, Arnold L ^a   Theopold, Klaus H ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; COBALT; HYDROGEN; IMIDE;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0037448905     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028267g     Document Type: Article

References (28)

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12. 3 as minor byproduct.
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22. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.
23. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.
24. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.
25. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.
26. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.
27. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.
28. For intermolecular C-H activations by early metal imido complexes, see: (a) Walsh, P. J. Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. R. G. J. Am. Chem. Soc. 1988, 110, 8731. (c) Schaller, C. P.; Wolczanski, P. T. Inorg. Chem. 1993, 32, 131. (d) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179. (e) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591. (f) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696. (g) Schafer, D. F.; Wolczanski, P. T. J. Am. Chem. Soc. 1998, 120, 4881.