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Volumn 42, Issue 29, 2003, Pages 3430-3434

Intramolecular C-H activation in alkaline-earth metal complexes

Author keywords

Alkaline earth metals; C H activation; Calcium; Carbanions; Cyclometalation

Indexed keywords

ALKALINE EARTH METAL COMPOUNDS; CHEMICAL ACTIVATION; COMPLEXATION; DECOMPOSITION; HYDROGEN BONDS; X RAY CRYSTALLOGRAPHY;

EID: 0042029675     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351055     Document Type: Article
Times cited : (86)

References (58)
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    • note
    • - ion and the dipp-nacnac ligand and could not be isolated.
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    • note
    • - group. This is typical for H-C-C-C-H substructures with a W geometry.
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    • note
    • An increase in temperature shifts the equilibrium to 5, the side with the least solvation and highest entropy. A decrease in the concentration shifts the equilibrium to the least aggregated species, that is, monomer 8.
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    • note
    • 3OD is slowly deuterated in the Me groups.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.