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Volumn 125, Issue 50, 2003, Pages 15286-15287

β-Diiminate Platinum Complexes for Alkane Dehydrogenation

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; ALKENE DERIVATIVE; BETA DIIMINATE PLATINUM DERIVATIVE; HYDROCARBON; IMINE; LIGAND; PLATINUM COMPLEX; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

EID: 0346848866     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037781z     Document Type: Article
Times cited : (102)

References (22)
  • 1
    • 0037198618 scopus 로고    scopus 로고
    • Recent general reviews on C-H bond activation and functionalization: (a) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
    • (2002) Nature , vol.417 , pp. 507
    • Labinger, J.A.1    Bercaw, J.E.2
  • 3
    • 85168647471 scopus 로고    scopus 로고
    • Recent reviews on C-H bond activation and functionalization emphasizing platinum catalysts: (a) Fekl, U.; Goldberg, K. I. Adv. Inorg. Chem. 2003, 54, 259.
    • (2003) Adv. Inorg. Chem. , vol.54 , pp. 259
    • Fekl, U.1    Goldberg, K.I.2
  • 16
    • 0037430623 scopus 로고    scopus 로고
    • "Three-coordinate" intermediates (2, 4, and 7) could be stabilized by agostic C-H bond interactions with the open site. A nickel analogue of 7: Wiencko, H. L.; Kogut, E.; Warren, T. H. Inorg. Chim. Acta 2003, 345, 199.
    • (2003) Inorg. Chim. Acta , vol.345 , pp. 199
    • Wiencko, H.L.1    Kogut, E.2    Warren, T.H.3
  • 17
    • 0347398805 scopus 로고    scopus 로고
    • note
    • See Supporting Information.
  • 18
    • 0347398802 scopus 로고    scopus 로고
    • note
    • Complex 1b has an advantage over 1c in that the tert-butyl groups in the para-positions of 1b impart an increased solubility in alkane solvents.
  • 20
    • 0346137791 scopus 로고    scopus 로고
    • note
    • 2) = 1.01.
  • 21
    • 0347398806 scopus 로고    scopus 로고
    • note
    • 1H NMR) liberates all-protio neohexane, supporting that cyclometalation occurs as an intermediate step.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.