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0038286748
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note
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For details on how the interpretations of the chemistry vary with the nature of the reactive species, see ref 10 and the illustrations therein.
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19
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0002421651
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For the three other reported examples of intermolecular C-H activations by alkylidene complexes, see: (a) Coles, M. P.; Gibson, V. C.; Clegg, W.; Elsegood, M. R. J.; Porrelli, P. A. J. Chem. Soc., Chem. Commun. 1996, 1963-1964.
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22
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0037949378
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note
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Note that the ortho aryl product is also observed as a trace product (∼1% overall) in the activation of toluene by σ-A.
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-
-
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23
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0038625657
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note
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A small amount of decomposition (<5%) is also observed. The signals for the decomposition products increase upon prolonged reaction times and are also observed when pure complex 3 is thermolyzed independently (vide infra). Several related aryl products have been shown to be moderately thermally unstable in other instances (vide infra).
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24
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0001142318
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Debad, J. D.; Legzdins, P.; Batchelor, R. J.; Einstein, F. W. B. Organometallics 1993, 12, 2094-2102.
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Dryden, N. H.; Legzdins; Trotter, J.; Yee, V. C. Organometallics 1991, 10, 2857-2870.
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Legzdins, P.; Jones, R. H.; Phillips, E. C.; Yee, V. C.; Trotter, J.; Einstein, F. W. B. Organometallics 1991, 10, 986-1002.
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Trotter, J.5
Einstein, F.W.B.6
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Bau, R. Mason, S. A.; Patrick, B. O.; Adams, C. S.; Sharp, W. B.; Legzdins, P. Organometallics 2001, 20, 4492-4501.
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