Terminal vanadium-neopentylidyne complexes and intramolecular cross-metathesis reactions to generate azametalacyclohexatrienes

Journal of the American Chemical Society

Volumn 126, Issue 34, 2004, Pages 10506-10507

  Basuli, Falguni ^a   Bailey, Brad C ^a   Brown, Douglas ^a   Tomaszewski, John ^a   Huffman, John C ^a   Baik, Mu Hyun ^a   Mindiola, Daniel J ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; AZAMETALLACYCLOHEXATRIENE DERIVATIVE; HETEROCYCLIC COMPOUND; NEOPENTYLIDENE DERIVATIVE; UNCLASSIFIED DRUG; VANADIUM DERIVATIVE;

ADDITION REACTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CROSS METATHESIS; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; GEOMETRY; MAGNETISM; MOLECULAR STABILITY; OXIDATION; PARAMETER; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; ROOM TEMPERATURE; STRUCTURE ANALYSIS; SYNTHESIS; TECHNIQUE; THERMODYNAMICS; X RAY DIFFRACTION;

EID: 4344703547     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0472376     Document Type: Article

References (17)

1. (a) Schrock, R. R. Chem. Rev. 2002, 102, 145-179.
2. (b) Schrock, R. R. Acc. Chem. Res. 1986, 19, 342-348.
3. (c) Murdzek, J. S.; Schrock, R. R. In Carbyne Complexes; VCH: New York, 1988.
4. (d) Mayr, A.; Hoffmeister, H. Adv. Organomet. Chem. 1991, 32, 227-324.
5. (e) Engel, P. F.; Pfeffer, M. Chem. Rev. 1995, 95, 2281-2909.
6. (a) Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S. M.; Pedersen, S. F. Organometallics 1982, 1, 1645-1651.
7. (b) Listemann, M.; Schrock, R. R. Organometallics 1985, 4, 74-83 and references therein.
8. (c) Schrock, R. R.; Listermann, M. L.; Sturgeoff, L. G. J. Am. Chem. Soc. 1982, 104, 4291-4293.
9. (a) Chisholm, M. H.; Eichhorn, B. W.; Folting, K.; Huffman, J. C. Organometallics 1989, 8, 49-66.
10. (b) Akiyama, M.; Chisholm, M. H.; Cotton, F. A.; Extine, M. W.; Haitko, D. A.; Little, D.; Fanwick, P. E. Inorg. Chem. 1979, 18, 2266-2270.
11. Protasiewicz, J. D.; Lippard, S. J. J. Am. Chem. Soc. 1991, 113, 6564-6570.
12. (a) Basuli, F.; Bailey, B. C.; Tomaszewski, J.; Huffman, J. C.; Mindiola, D. J. J. Am. Chem. Soc. 2003, 125, 6052-6053.
13. (b) Basuli, F.; Kilgore, U. J.; Hu, X.; Meyer, K.; Pink, M.; Huffman, J. C.; Mindiola, D. J. Angew. Chem., Int. Ed. 2004, 43, 3156-3159.
14. See Supporting Information for complete experimental, crystallographic, and DFT calculation details.
15. 13C nucleus: Claridge, T. D. W. High-Resolution NMR techniques in Organic Chemistry; Pergamon: Amsterdam, 1999; pp 40-44.
16. For an example of a planar metalapyridine system of group 5, see: Weller, K. J.; Filippov, I.; Briggs, P. M.; Wigley, D. E. Organometallics 1998, 17, 322-329 and references therein.
17. Fellmann, J. D.; Tuner, H. W.; Schrock, R. R. J. Am. Chem. Soc. 1980, 102, 6608-6609.