A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced α-hydrogen abstraction

Journal of the American Chemical Society

Volumn 125, Issue 20, 2003, Pages 6052-6053

  Basuli, Falguni ^a   Bailey, Brad C ^a   Tomaszewski, John ^a   Huffman, John C ^a   Mindiola, Daniel J ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; TITANIUM DERIVATIVE;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CYCLIC POTENTIOMETRY; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PROTON TRANSPORT; REACTION ANALYSIS; RING CLOSING METATHESIS; STEREOCHEMISTRY; SYNTHESIS; X RAY DIFFRACTION;

EID: 0038627642     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja034786n     Document Type: Article

References (35)

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28. For some illustrative "Wittig-type" titanium-based reactions, see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2001. (b) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399. (c) Tebbe, F. N.; Parshall, G. W.; Parshall, G. W.; Reddy, G. S. J. Am. Chem. Soc. 1978, 100, 3611. (d) Kauffmann, T.; Ennen, B.; Sander, J.; Wieschollek, R. Angew. Chem., Int. Ed. Engl. 1983, 22, 244. (e) Grubbs, R. H.; Cannizzo, L. F. J. Org. Chem. 1985, 50, 2316. (f) Wilcox, C. S.; Long, G. W.; Suh, H. Tetrahedron Lett. 1984, 25, 395. (g) Petasis, N. A.; Bzowej, E. I. J. Am. Chem. Soc. 1990, 112, 6392.
29. For some illustrative "Wittig-type" titanium-based reactions, see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2001. (b) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399. (c) Tebbe, F. N.; Parshall, G. W.; Parshall, G. W.; Reddy, G. S. J. Am. Chem. Soc. 1978, 100, 3611. (d) Kauffmann, T.; Ennen, B.; Sander, J.; Wieschollek, R. Angew. Chem., Int. Ed. Engl. 1983, 22, 244. (e) Grubbs, R. H.; Cannizzo, L. F. J. Org. Chem. 1985, 50, 2316. (f) Wilcox, C. S.; Long, G. W.; Suh, H. Tetrahedron Lett. 1984, 25, 395. (g) Petasis, N. A.; Bzowej, E. I. J. Am. Chem. Soc. 1990, 112, 6392.
30. For some illustrative "Wittig-type" titanium-based reactions, see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2001. (b) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399. (c) Tebbe, F. N.; Parshall, G. W.; Parshall, G. W.; Reddy, G. S. J. Am. Chem. Soc. 1978, 100, 3611. (d) Kauffmann, T.; Ennen, B.; Sander, J.; Wieschollek, R. Angew. Chem., Int. Ed. Engl. 1983, 22, 244. (e) Grubbs, R. H.; Cannizzo, L. F. J. Org. Chem. 1985, 50, 2316. (f) Wilcox, C. S.; Long, G. W.; Suh, H. Tetrahedron Lett. 1984, 25, 395. (g) Petasis, N. A.; Bzowej, E. I. J. Am. Chem. Soc. 1990, 112, 6392.
31. For some illustrative "Wittig-type" titanium-based reactions, see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2001. (b) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399. (c) Tebbe, F. N.; Parshall, G. W.; Parshall, G. W.; Reddy, G. S. J. Am. Chem. Soc. 1978, 100, 3611. (d) Kauffmann, T.; Ennen, B.; Sander, J.; Wieschollek, R. Angew. Chem., Int. Ed. Engl. 1983, 22, 244. (e) Grubbs, R. H.; Cannizzo, L. F. J. Org. Chem. 1985, 50, 2316. (f) Wilcox, C. S.; Long, G. W.; Suh, H. Tetrahedron Lett. 1984, 25, 395. (g) Petasis, N. A.; Bzowej, E. I. J. Am. Chem. Soc. 1990, 112, 6392.
32. For some illustrative "Wittig-type" titanium-based reactions, see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2001. (b) Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399. (c) Tebbe, F. N.; Parshall, G. W.; Parshall, G. W.; Reddy, G. S. J. Am. Chem. Soc. 1978, 100, 3611. (d) Kauffmann, T.; Ennen, B.; Sander, J.; Wieschollek, R. Angew. Chem., Int. Ed. Engl. 1983, 22, 244. (e) Grubbs, R. H.; Cannizzo, L. F. J. Org. Chem. 1985, 50, 2316. (f) Wilcox, C. S.; Long, G. W.; Suh, H. Tetrahedron Lett. 1984, 25, 395. (g) Petasis, N. A.; Bzowej, E. I. J. Am. Chem. Soc. 1990, 112, 6392.
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35. One-electron oxidation followed by hydrogen atom abstraction to generate a putative tungsten-alkylidene has been reported. Jernakoff, P.; Cooper, N. J. Organometallics 1986, 5, 747.