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Volumn 38, Issue 1, 2005, Pages 4-17

ROM polymerization in facilitated synthesis

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER;

EID: 18444399620     PISSN: 00025100     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Review
Times cited : (5)

References (91)
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    • Schrock, R. R. The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis. In Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: New York, 2003; Vol. 1, Chapter 1.3, pp 8-32.
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    • (b) Vedantham, P.; Flynn, D. L.; Hanson, P. R. Design and Utility of ROMP-Generated Oligomeric Scavenging Agents. Presented at the 227th National Meeting of the American Chemical Society, Anaheim, CA, March 28-April 1, 2004; Paper ORGN 340.
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    • Recently, the development of versatile arylsulfonyl chloride resins as both scavenging resins and capture-release agents has been reported: (a) Rueter, J. K.; Nortey, S. O.; Baxter, E. W.; Leo, G. C.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 975. (b) Baxter, E. W.; Rueter, J. K.; Nortey, S. O.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 979. (c) Takahashi, T.; Ebata, S.; Doi, T. Tetrahedron Lett. 1998, 39, 1369. (d) For a review on polymer-supported arylsulfonyl chloride resins, see Huang, W.; He, B. Chin. J. Reactive Polymers (Engl.) 1992, 1, 61.
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    • 0032567901 scopus 로고    scopus 로고
    • Recently, the development of versatile arylsulfonyl chloride resins as both scavenging resins and capture-release agents has been reported: (a) Rueter, J. K.; Nortey, S. O.; Baxter, E. W.; Leo, G. C.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 975. (b) Baxter, E. W.; Rueter, J. K.; Nortey, S. O.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 979. (c) Takahashi, T.; Ebata, S.; Doi, T. Tetrahedron Lett. 1998, 39, 1369. (d) For a review on polymer-supported arylsulfonyl chloride resins, see Huang, W.; He, B. Chin. J. Reactive Polymers (Engl.) 1992, 1, 61.
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    • Baxter, E.W.1    Rueter, J.K.2    Nortey, S.O.3    Reitz, A.B.4
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    • 0032510298 scopus 로고    scopus 로고
    • Recently, the development of versatile arylsulfonyl chloride resins as both scavenging resins and capture-release agents has been reported: (a) Rueter, J. K.; Nortey, S. O.; Baxter, E. W.; Leo, G. C.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 975. (b) Baxter, E. W.; Rueter, J. K.; Nortey, S. O.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 979. (c) Takahashi, T.; Ebata, S.; Doi, T. Tetrahedron Lett. 1998, 39, 1369. (d) For a review on polymer-supported arylsulfonyl chloride resins, see Huang, W.; He, B. Chin. J. Reactive Polymers (Engl.) 1992, 1, 61.
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    • Takahashi, T.1    Ebata, S.2    Doi, T.3
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    • Recently, the development of versatile arylsulfonyl chloride resins as both scavenging resins and capture-release agents has been reported: (a) Rueter, J. K.; Nortey, S. O.; Baxter, E. W.; Leo, G. C.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 975. (b) Baxter, E. W.; Rueter, J. K.; Nortey, S. O.; Reitz, A. B. Tetrahedron Lett. 1998, 39, 979. (c) Takahashi, T.; Ebata, S.; Doi, T. Tetrahedron Lett. 1998, 39, 1369. (d) For a review on polymer-supported arylsulfonyl chloride resins, see Huang, W.; He, B. Chin. J. Reactive Polymers (Engl.) 1992, 1, 61.
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    • note
    • n stands for n-mer OACC (oligomeric alkyl cyclohexyl carbodiimide), where n = 50, 100, 150. These are prepared by ROM polymerization of monomer carbodiimide 32 using second-generation (2G) Grubbs' catalyst (cat-B).
  • 54
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    • note
    • A wet chemical method confirmed the actual loading as 2.5 mmol/g, which represented 77% of the theoretical load (see reference 26).
  • 55
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    • note
    • The length of the polymer is calculated using the following equation: length = 100 ÷ (mol % catalyst). These oligomers are generated as a Gaussian distribution, with the most heavily populated region corresponding to the length calculated from this equation.
  • 65
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    • U.S. Patent US 5,603,985, 18 Feb 1997
    • Kent, M. S.; Saunders, R. U.S. Patent US 5,603,985, 18 Feb 1997; Chem. Abstr. 1997, 126, 225990t.
    • (1997) Chem. Abstr. , vol.126
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