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2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene.
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1H NMR spectra of crude 5a-h in the Supporting Information.
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0043043535
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Barrett has previously shown that 3 can be used to construct a ROMPgel acylating agent, see ref 9c.
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58
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0043043533
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When the polymerization was performed at ambient temperature, a reaction time of 3 h was required for complete consumption of monomer.
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When 1 was employed, the polymerization required refluxing for multiple hours, while 2 only required 45 min at reflux.
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63
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0026931032
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1H NMR assignments were made according to the reported shifts of poly(7-oxabicyclo[2.2.1]hept-2-ene) derivatives. See: Benedicto, A. D.; Novak, B. M.; Grubbs, R. H. Macromolecules 1992, 25, 5893-5900.
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