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Volumn 126, Issue 5, 2004, Pages 1526-1536

Encapsulation of Transition Metal Catalysts by Ligand-Template Directed Assembly

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CATALYSTS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ULTRAVIOLET SPECTROSCOPY;

EID: 1042298084     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0386795     Document Type: Article
Times cited : (179)

References (187)
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  • 3
    • 0001805503 scopus 로고
    • (b) Cram, D. J. Nature 1992, 356, 29.
    • (1992) Nature , vol.356 , pp. 29
    • Cram, D.J.1
  • 22
  • 100
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    • and references therein
    • For reviews on cyclodextrins, see: (a) Takahashi, K. Chem. Rev. 1998, 98, 2013 and references therein.
    • (1998) Chem. Rev. , vol.98 , pp. 2013
    • Takahashi, K.1
  • 125
    • 0042880466 scopus 로고
    • (d) Hunter, C. A.; Sarson, L. D. Angew. Chem., Int. Ed. Engl. 1994, 33, 2316. Chi, X.; Guerin, A. J.; Haycock, R. A.; Hunter, C. A.; Sarson, L. D. J. Chem. Soc., Chem. Commun. 1995, 2567.
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 2316
    • Hunter, C.A.1    Sarson, L.D.2
  • 147
    • 1042280407 scopus 로고    scopus 로고
    • note
    • -1).
  • 149
    • 1042280412 scopus 로고    scopus 로고
    • note
    • 3 calculations were performed using the Spartan sofware on a silicon graphics Unix workstation.
  • 162
    • 1042268956 scopus 로고    scopus 로고
    • note
    • Dichloromethane was chosen as a solvent, because toluene interferes with the signals of the carbonyl in the IR spectrum.
  • 164
    • 1042280413 scopus 로고    scopus 로고
    • note
    • The various porphyrin/4 and porphyrin/5 ratios in the rhodium-catalyzed hydroformylation were tested using rapid parallel screening in a high-throughput autoclave without incubation (volume per vessel 0.5 mL). Because of the different experimental setup, small quantitative differences in activity and selectivity were observed as compared to Table 1.
  • 178
    • 1042268955 scopus 로고    scopus 로고
    • note
    • Although the exchange processes are slow on the NMR time scale, the assemblies are formed and exchanged within the NMR experiment (within minutes), indicating that the assembly formation is fast as compared to the catalysis.
  • 180
    • 0007783002 scopus 로고
    • (to Union Carbide) EP 213.639, 1987
    • For phosphite-based rhodium catalysts that give high selectivity for branched aldehyde, see: (a) Billig, E.; Abatjoglou, A. G.; Bryant, D. R. (to Union Carbide) EP 213.639, 1987 [Chem. Abstr. 1987, 107, 7392r].
    • (1987) Chem. Abstr. , vol.107
    • Billig, E.1    Abatjoglou, A.G.2    Bryant, D.R.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.