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The enones 4a and 4b were prepared from the corresponding amides with vinylmagnesium bromide given in the following paper: Nahm, S.; Weinreb, S. M. Tetrahedron Lett. 1981, 22, 3815.
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Although we have used many hydrogenation conditions for 5a, the cis,trans,cis-fused ring was always obtained exclusively
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Although we have used many hydrogenation conditions for 5a, the cis,trans,cis-fused ring was always obtained exclusively.
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