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note
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Examples of the many possible applications of geometric metallocyclic polygons and polyhedra are discussed in ref. [1a].
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The structural motif of a truncated tetrahedron is described in: a) S. Leininger, J. Fan, M. Schmitz, P. J. Stang, Proc. Natl. Acad. Sci. USA 2000, 97, 1380-1384. The formal distinction between a truncated tetrahedron and a hexanuclear adamantanoid is illustrated on p. 857 in ref. [1a] these two motif types differ only in the directing angle of the ligands (109.5° in an adamantanoid but 120° in a truncated tetrahedron). A "super-adamantanoid" involving a ligand which is theoretically capable of forming a strict adamantanoid has been reported in:
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D. W. Johnson, J. Xu, R. W. Saalfrank, K. N. Raymond, Angew. Chem. 1999, 111, 3058-3061;
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note
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An example of an octahedron in which all of the faces are occupied by ligands has not yet been reported.
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J. Manna, C. J. Kuehl, J. A. Whitford, P. J. Stang, D. C. Muddiman, C. D. Hofstadler, R. D. Smith, J. Am. Chem. Soc. 1997, 119, 11611-11619.
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