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Volumn 10, Issue 2, 2004, Pages 474-483

Effects of Metal Ions on Photoinduced Electron Transfer in Zinc Porphyrin-Naphthalenediimide Linked Systems

Author keywords

Electron transfer; Marcus theory; Metal ions; Porphyrinoids; Zinc

Indexed keywords

FLUORESCENCE; FREE RADICALS; LIGHT ABSORPTION; OXIDATION; PHOTOCHEMICAL REACTIONS; POSITIVE IONS; ZINC;

EID: 0842303778     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305239     Document Type: Article
Times cited : (57)

References (108)
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    • The radical cation of Zn(TPP) (zinc 5,10,15,20-tetraphenyl-21H,23 H-porphinate) has the characteristic broad absorption in 500-700 nm together with an intense band at 406 nm; see: J. Fajer, D. C. Borg, A. Forman, D. Dolphin, R. H. Felton, J. Am. Chem. Soc. 1970, 92, 3451-3459.
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    • note
    • The bleaching of the porphyrin Q band is observed at 560 nm in Figure 2 a.
  • 92
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    • note
    • +, which has no absorption band in the visible region; see ref. [32].
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    • CR value is hence highly sensitive to the spacer length of an electron donor-acceptor dyad.
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  • 97
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    • note
    • ISC = 0.09).
  • 98
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    • note
    • 3+ complex.
  • 99
    • 0842316830 scopus 로고    scopus 로고
    • note
    • The CS process of 2 may proceed in a stepwise manner. However, the absence of any intermediate in the fast spectroscopy indicates that the secondary charge-shift reaction would be much faster than the primary CS process (ref. [27]). The faster CS rate of 2 than of 1 (Table 1) may be attributed to this primary CS process.
  • 100


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