Effects of hydrogen bonding on metal ion-promoted intramolecular electron transfer and photoinduced electron transfer in a ferrocene-quinone dyad with a rigid amide spacer

Journal of the American Chemical Society

Volumn 125, Issue 4, 2003, Pages 1007-1013

  Fukuzumi, Shunichi ^a   Okamoto, Ken ^a   Yoshida, Yutaka ^a   Imahori, Hiroshi ^a   Araki, Yasuyuki ^b   Ito, Osamu ^b  

^a OSAKA UNIVERSITY   (Japan)

^b TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; ELECTRON TRANSPORT PROPERTIES; METHANE; PARAMAGNETIC RESONANCE; PROTONS;

AMIDE SPACER; FERROCENE-QUINONE DYAD; INTRAMOLECULAR;

HYDROGEN BONDS;

AMIDE; FERROCENE DERIVATIVE; METAL ION; METHYL GROUP; QUINONE DERIVATIVE; SUPEROXIDE;

ARTICLE; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; HYDROGEN BOND; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION TIME; X RAY DIFFRACTION;

AMIDES; ELECTRONS; FERROUS COMPOUNDS; HYDROGEN BONDING; PHOTOCHEMISTRY; QUINONES;

EID: 0037471636     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026441v     Document Type: Article

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68. .- (Figure 4b).
69. 3+ (bpy = 2,2′-bipyridine).
70. 2+ was employed.
71. .- (Figure 1c), which may also affect the rate of metal ion-promoted electron transfer of Fc-Q and Fc-(Me)Q in addition to the effect of hydrogen bond.