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60 chromophores. It is a general belief, however, that, in solution, families of conformers simultaneously exist in equilibrium. Therefore, the presence of a heterogeneous mixture of conformers in CBT/ protic cosolvent cannot be ruled out.
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An increase of the solvent polarity, e.g., from CBT to CBT/HFIP, enhances the thermodynamic driving force (AG) for an intramolecular electron transfer by lowering the energy of the respective charge-separated radical pair. Thus, upon addition of a protic cosolvent to CBT, a stronger luminescence quenching would have been expected also in the case of dyad 1, reflecting the faster ET dynamics. The measured luminescence quantum yields in CBT/EtOH, CBT/TFE, and CBT/HFIP are, however, in sharp contrast to this trend, assuming no Marcus inverted behavior.
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