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Volumn 55, Issue 43, 1999, Pages 12431-12477

Recent advances in electrophilic fluorination

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; FLUORINATION; PRIORITY JOURNAL; REACTION ANALYSIS; REVIEW; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033595850     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(99)00748-6     Document Type: Review
Times cited : (253)

References (200)
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    • For discussions concerning the mechanistic aspects of electrophilic fluorination see refs. 7-11
    • For discussions concerning the mechanistic aspects of electrophilic fluorination see refs. 7-11.
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    • This review does not cover patents and other publications that do not appear in the general scientific literature
    • This review does not cover patents and other publications that do not appear in the general scientific literature.
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    • 4 or Selectfluor (compound 1) as a fluorinating agent and its applications to the synthesis of organofluorine compounds
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    • This review covers the literature, from July, 1996 to June 1997, on the preparation of organic halides, including selected examples on the preparation of organofluorines by electrophilic fluorination
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    • This review discusses a variety of methods, including electrophilic fluorination, for synthesizing α-fluoroaldehydes and α-fluoroketones
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    • For an extensive list of electrophilic N-F fluorinating agents that have appeared prior to 1995 see ref 10
    • For an extensive list of electrophilic N-F fluorinating agents that have appeared prior to 1995 see ref 10.
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    • Available from Aldrich, APCI, Janchim and FLCHEM
    • Available from Aldrich, APCI, Janchim and FLCHEM.
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    • Available from Aldrich, FLCHEM, PCR
    • Available from Aldrich, FLCHEM, PCR.
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    • Available from Aldrich, FLCHEM, PCR
    • Available from Aldrich, FLCHEM, PCR.
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    • Available from FLCHEM
    • Available from FLCHEM.
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    • NFTh is produced and commercialized by AlliedSignal, Buffalo, USA
    • NFTh is produced and commercialized by AlliedSignal, Buffalo, USA.
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    • For references on the fluorination of these substrates with other electrophilic fluorinating agents see ref. 113 and references therein
    • For references on the fluorination of these substrates with other electrophilic fluorinating agents see ref. 113 and references therein.
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    • For earlier references on the electrophilic fluorination of purines and pyrimidines see refs. 9 and 10
    • For earlier references on the electrophilic fluorination of purines and pyrimidines see refs. 9 and 10.
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    • See reference 37 for a similar reaction
    • See reference 37 for a similar reaction.
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    • Direct formation of α-fluorosulfones from sulfoxides by reaction with elemental fluorine has recently been reported. However, whether this reaction can be considered an "electrophilic" fluorination of sulfoxides is questionable. See: (a) Toyota, A.; Nishimura, A.; Kaneko, C. Tetrahedron Lett. 1998, 39, 4687,
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    • For electrophilic fluorination of α-sulfonyl phosphonate esters see also section 5
    • For electrophilic fluorination of α-sulfonyl phosphonate esters see also section 5.
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    • For references on earlier work in this area of chemistry see references 11a and 11b
    • For references on earlier work in this area of chemistry see references 11a and 11b.
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    • note
    • 2NF and N-fluoroquinuclidinium triflate as fluorinating agents. See reference 10.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.