Polymer Interfaces: Synthetic Strategies Enabling Functionality, Adaptivity, and Spatial Control

Macromolecules

Volumn 49, Issue 14, 2016, Pages 5001-5016

  Barner Kowollik, Christopher ^a,b,c   Goldmann, Anja S ^a,b   Schacher, Felix H ^d  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^c QUEENSLAND UNIVERSITY OF TECHNOLOGY   (Australia)

^d FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; SELF ASSEMBLY; SIGNAL ENCODING;

CHEMICAL COMPLEXITY; LIGATION CHEMISTRY; LIGATION REACTIONS; MACROMOLECULAR CHEMISTRY; POLYMER INTERFACES; SINGLE POLYMER CHAINS; STRUCTURED INTERFACES; SYNTHETIC STRATEGIES;

ENCODING (SYMBOLS);

EID: 84979939314     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/acs.macromol.6b00650     Document Type: Review

References (132)

1. Zetterlund, P. B.; Thickett, S. C.; Perrier, S.; Bourgeat-Lami, E.; Lansalot, M. Controlled/Living Radical Polymerization in Dispersed Systems: An Update Chem. Rev. 2015, 115 (18) 9745-9800 10.1021/cr500625k
2. Braunecker, W. A.; Matyjaszewski, K. Controlled/living radical polymerization: Features, developments, and perspectives Prog. Polym. Sci. 2007, 32 (1) 93-146 10.1016/j.progpolymsci.2006.11.002
3. Matyjaszewski, K.; Tsarevsky, N. V. Nanostructured functional materials prepared by atom transfer radical polymerization Nat. Chem. 2009, 1 (4) 276-288 10.1038/nchem.257
4. Anastasaki, A.; Nikolaou, V.; Nurumbetov, G.; Wilson, P.; Kempe, K.; Quinn, J. F.; Davis, T. P.; Whittaker, M. R.; Haddleton, D. M. Cu(0)-Mediated Living Radical Polymerization: A Versatile Tool for Materials Synthesis Chem. Rev. 2016, 116 (3) 835-877 10.1021/acs.chemrev.5b00191
5. Gregory, A.; Stenzel, M. H. Complex polymer architectures via RAFT polymerization: From fundamental process to extending the scope using click chemistry and nature's building blocks Prog. Polym. Sci. 2012, 37 (1) 38-105 10.1016/j.progpolymsci.2011.08.004
6. Moad, G.; Rizzardo, E.; Thang, S. H. Living Radical Polymerization by the RAFT Process-A Third Update Aust. J. Chem. 2012, 65 (8) 985-1076 10.1071/CH12295
7. Wang, H.-S.; Song, M.; Hang, T.-J. Functional Interfaces Constructed by Controlled/Living Radical Polymerization for Analytical Chemistry ACS Appl. Mater. Interfaces 2016, 8 (5) 2881-2898 10.1021/acsami.5b10465
8. Brocas, A.-L.; Mantzaridis, C.; Tunc, D.; Carlotti, S. Polyether synthesis: From activated or metal-free anionic ring-opening polymerization of epoxides to functionalization Prog. Polym. Sci. 2013, 38 (6) 845-873 10.1016/j.progpolymsci.2012.09.007
9. Kempe, K.; Krieg, A.; Becer, C. R.; Schubert, U. S. ″Clicking″ on/with polymers: a rapidly expanding field for the straightforward preparation of novel macromolecular architectures Chem. Soc. Rev. 2012, 41 (1) 176-191 10.1039/C1CS15107J
10. Hilf, S.; Kilbinger, A. F. M. Functional end groups for polymers prepared using ring-opening metathesis polymerization Nat. Chem. 2009, 1 (7) 537-546 10.1038/nchem.347
11. Rudolph, T.; Barthel, M. J.; Kretschmer, F.; Mansfeld, U.; Hoeppener, S.; Hager, M. D.; Schubert, U. S.; Schacher, F. H. Poly(2-vinyl pyridine)-block-poly(ethylene oxide) featuring a furan group at the block junction-synthesis and functionalization Macromol. Rapid Commun. 2014, 35 (9) 916-921 10.1002/marc.201300875
12. Tonhauser, C.; Golriz, A. A.; Moers, C.; Klein, R.; Butt, H.-J.; Frey, H. Stimuli-Responsive Y-Shaped Polymer Brushes Based on Junction-Point-Reactive Block Copolymers Adv. Mater. 2012, 24 (41) 5559-5563 10.1002/adma.201202105
13. Gauthier, M. A.; Gibson, M. I.; Klok, H.-A. Synthesis of Functional Polymers by Post-Polymerization Modification Angew. Chem., Int. Ed. 2009, 48 (1) 48-58 10.1002/anie.200801951
14. Günay, K. A.; Theato, P.; Klok, H.-A. Standing on the shoulders of Hermann Staudinger: Post-polymerization modification from past to present J. Polym. Sci., Part A: Polym. Chem. 2013, 51 (1) 1-28 10.1002/pola.26333
15. Goldmann, A. S.; Glassner, M.; Inglis, A. J.; Barner-Kowollik, C. Post-Functionalization of Polymers via Orthogonal Ligation Chemistry Macromol. Rapid Commun. 2013, 34 (10) 810-849 10.1002/marc.201300017
16. Turgut, H.; Delaittre, G. On the Orthogonality of Two Thiol-Based Modular Ligations Chem. Eur. J. 2016, 22 (4) 1511-1521 10.1002/chem.201503844
17. Rudolph, T.; Espeel, P.; Du Prez, F. E.; Schacher, F. H. Poly(thiolactone) homo- and copolymers from maleimide thiolactone: synthesis and functionalization Polym. Chem. 2015, 6 (23) 4240-4251 10.1039/C5PY00329F
18. Yang, B.; Zhao, Y.; Wei, Y.; Fu, C.; Tao, L. The Ugi reaction in polymer chemistry: syntheses, applications and perspectives Polym. Chem. 2015, 6 (48) 8233-8239 10.1039/C5PY01398D
19. Theato, P. Multi-Component and Sequential Reactions in Polymer Synthesis; Springer: Switzerland, 2015.
20. Hartmann, L. Polymers for Control Freaks: Sequence-Defined Poly(amidoamine)s and Their Biomedical Applications Macromol. Chem. Phys. 2011, 212 (1) 8-13 10.1002/macp.201000479
21. ten Brummelhuis, N. Controlling monomer-sequence using supramolecular templates Polym. Chem. 2015, 6 (5) 654-667 10.1039/C4PY01522C
22. Anastasaki, A.; Nikolaou, V.; Pappas, G. S.; Zhang, Q.; Wan, C.; Wilson, P.; Davis, T. P.; Whittaker, M. R.; Haddleton, D. M. Photoinduced sequence-control via one pot living radical polymerization of acrylates Chemical Science 2014, 5 (9) 3536-3542 10.1039/C4SC01374C
23. Gody, G.; Maschmeyer, T.; Zetterlund, P. B.; Perrier, S. Rapid and quantitative one-pot synthesis of sequence-controlled polymers by radical polymerization Nat. Commun. 2013, 4 (2505) 1-9 10.1038/ncomms3505
24. Lutz, J.-F.; Ouchi, M.; Liu, D. R.; Sawamoto, M. Sequence-Controlled Polymers Science 2013, 341 (6146) 1238149 10.1126/science.1238149
25. Solleder, S. C.; Zengel, D.; Wetzel, K. S.; Meier, M. A. R. A Scalable and High-Yield Strategy for the Synthesis of Sequence-Defined Macromolecules Angew. Chem., Int. Ed. 2016, 55 (3) 1204-1207 10.1002/anie.201509398
26. Zydziak, N.; Feist, F.; Huber, B.; Mueller, J. O.; Barner-Kowollik, C. Photo-induced sequence defined macromolecules via hetero bifunctional synthons Chem. Commun. 2015, 51 (10) 1799-1802 10.1039/C4CC08756A
27. Alsubaie, F.; Anastasaki, A.; Wilson, P.; Haddleton, D. M. Sequence-controlled multi-block copolymerization of acrylamides via aqueous SET-LRP at 0 °C Polym. Chem. 2015, 6 (3) 406-417 10.1039/C4PY01066C
28. Lutz, J.-F. Writing on Polymer Chains Acc. Chem. Res. 2013, 46 (11) 2696-2705 10.1021/ar400097a
29. Simula, A.; Nikolaou, V.; Anastasaki, A.; Alsubaie, F.; Nurumbetov, G.; Wilson, P.; Kempe, K.; Haddleton, D. M. Synthesis of well-defined [α],[ω]-telechelic multiblock copolymers in aqueous medium: in situ generation of [α],[ω]-diols Polym. Chem. 2015, 6 (12) 2226-2233 10.1039/C4PY01802H
30. Zetterlund, P. B.; Gody, G.; Perrier, S. Sequence-Controlled Multiblock Copolymers via RAFT Polymerization: Modeling and Simulations Macromol. Theory Simul. 2014, 23 (5) 331-339 10.1002/mats.201300165
31. Altintas, O.; Barner-Kowollik, C. Single-Chain Folding of Synthetic Polymers: A Critical Update Macromol. Rapid Commun. 2016, 37 (1) 29-46 10.1002/marc.201500547
32. Gonzalez-Burgos, M.; Latorre-Sanchez, A.; Pomposo, J. A. Advances in single chain technology Chem. Soc. Rev. 2015, 44 (17) 6122-6142 10.1039/C5CS00209E
33. Hanlon, A. M.; Lyon, C. K.; Berda, E. B. What Is Next in Single-Chain Nanoparticles? Macromolecules 2016, 49 (1) 2-14 10.1021/acs.macromol.5b01456
34. Latorre-Sánchez, A.; Pomposo, J. A. Recent bioinspired applications of single-chain nanoparticles Polym. Int. 2016, 10.1002/pi.5078
35. Mavila, S.; Eivgi, O.; Berkovich, I.; Lemcoff, N. G. Intramolecular Crosslinking Methodologies for the Synthesis of Polymer Nanoparticles Chem. Rev. 2016, 116 (3) 878-961 10.1021/acs.chemrev.5b00290
36. Willenbacher, J.; Altintas, O.; Trouillet, V.; Knöfel, N.; Monteiro, M. J.; Roesky, P. W.; Barner-Kowollik, C. Pd-complex driven formation of single-chain nanoparticles Polym. Chem. 2015, 6 (24) 4358-4365 10.1039/C5PY00389J
37. Hosono, N.; Kushner, A. M.; Chung, J.; Palmans, A. R. A.; Guan, Z.; Meijer, E. W. Forced Unfolding of Single-Chain Polymeric Nanoparticles J. Am. Chem. Soc. 2015, 137 (21) 6880-6888 10.1021/jacs.5b02967
38. Altintas, O.; Krolla-Sidenstein, P.; Gliemann, H.; Barner-Kowollik, C. Single-Chain Folding of Diblock Copolymers Driven by Orthogonal H-Donor and Acceptor Units Macromolecules 2014, 47 (17) 5877-5888 10.1021/ma501186k
39. Terashima, T.; Mes, T.; De Greef, T. F. A.; Gillissen, M. A. J.; Besenius, P.; Palmans, A. R. A.; Meijer, E. W. Single-Chain Folding of Polymers for Catalytic Systems in Water J. Am. Chem. Soc. 2011, 133 (13) 4742-4745 10.1021/ja2004494
40. Inglis, A. J.; Barner-Kowollik, C. Ultra Rapid Approaches to Mild Macromolecular Conjugation Macromol. Rapid Commun. 2010, 31 (14) 1247-1266 10.1002/marc.200900924
41. Bates, F. S.; Fredrickson, G. H. Block Copolymers-Designer Soft Materials Phys. Today 1999, 52 (2) 32-38 10.1063/1.882522
42. Schacher, F. H.; Rupar, P. A.; Manners, I. Functional block copolymers: nanostructured materials with emerging applications Angew. Chem., Int. Ed. 2012, 51 (32) 7898-7921 10.1002/anie.201200310
43. Luo, M.; Epps, T. H. Directed Block Copolymer Thin Film Self-Assembly: Emerging Trends in Nanopattern Fabrication Macromolecules 2013, 46 (19) 7567-7579 10.1021/ma401112y
44. Widin, J. M.; Schmitt, A. K.; Schmitt, A. L.; Im, K.; Mahanthappa, M. K. Unexpected Consequences of Block Polydispersity on the Self-Assembly of ABA Triblock Copolymers J. Am. Chem. Soc. 2012, 134 (8) 3834-3844 10.1021/ja210548e
45. Sinturel, C.; Bates, F. S.; Hillmyer, M. A. High ξ-Low N Block Polymers: How Far Can We Go? ACS Macro Lett. 2015, 4 (9) 1044-1050 10.1021/acsmacrolett.5b00472
46. Chang, J.-B.; Son, J. G.; Hannon, A. F.; Alexander-Katz, A.; Ross, C. A.; Berggren, K. K. Aligned Sub-10-nm Block Copolymer Patterns Templated by Post Arrays ACS Nano 2012, 6 (3) 2071-2077 10.1021/nn203767s
47. Rodwogin, M. D.; Spanjers, C. S.; Leighton, C.; Hillmyer, M. A. Polylactide-Poly(dimethylsiloxane)-Polylactide Triblock Copolymers as Multifunctional Materials for Nanolithographic Applications ACS Nano 2010, 4 (2) 725-732 10.1021/nn901190a
48. Cushen, J. D.; Otsuka, I.; Bates, C. M.; Halila, S.; Fort, S.; Rochas, C.; Easley, J. A.; Rausch, E. L.; Thio, A.; Borsali, R.; Willson, C. G.; Ellison, C. J. Oligosaccharide/Silicon-Containing Block Copolymers with 5 nm Features for Lithographic Applications ACS Nano 2012, 6 (4) 3424-3433 10.1021/nn300459r
49. Aissou, K.; Mumtaz, M.; Fleury, G.; Portale, G.; Navarro, C.; Cloutet, E.; Brochon, C.; Ross, C. A.; Hadziioannou, G. Sub-10 nm Features Obtained from Directed Self-Assembly of Semicrystalline Polycarbosilane-Based Block Copolymer Thin Films Adv. Mater. 2015, 27 (2) 261-265 10.1002/adma.201404077
50. Park, S.; Lee, D. H.; Xu, J.; Kim, B.; Hong, S. W.; Jeong, U.; Xu, T.; Russell, T. P. Macroscopic 10-Terabit-per-Square-Inch Arrays from Block Copolymers with Lateral Order Science 2009, 323 (5917) 1030-1033 10.1126/science.1168108
51. Rudolph, T.; Schacher, F. H. Selective crosslinking or addressing of individual domains within block copolymer nanostructures Eur. Polym. J. 2016, 80 (7) 317-331 10.1016/j.eurpolymj.2016.03.018
52. Stuart, M. A. C.; Huck, W. T. S.; Genzer, J.; Muller, M.; Ober, C.; Stamm, M.; Sukhorukov, G. B.; Szleifer, I.; Tsukruk, V. V.; Urban, M.; Winnik, F.; Zauscher, S.; Luzinov, I.; Minko, S. Emerging applications of stimuli-responsive polymer materials Nat. Mater. 2010, 9 (2) 101-113 10.1038/nmat2614
53. Stewart-Sloan, C. R.; Olsen, B. D. Protonation-Induced Microphase Separation in Thin Films of a Polyelectrolyte-Hydrophilic Diblock Copolymer ACS Macro Lett. 2014, 3 (5) 410-414 10.1021/mz400650q
54. Hörenz, C.; Rudolph, T.; Barthel, M. J.; Günther, U.; Schacher, F. H. Amphiphilic polyether-based block copolymers as crosslinkable ligands for Au-nanoparticles Polym. Chem. 2015, 6 (31) 5633-5642 10.1039/C4PY01434K
55. Barthel, M. J.; Rudolph, T.; Teichler, A.; Paulus, R. M.; Vitz, J.; Hoeppener, S.; Hager, M. D.; Schacher, F. H.; Schubert, U. S. Self-Healing Materials via Reversible Crosslinking of Poly(ethylene oxide)-Block-Poly(furfuryl glycidyl ether) (PEO-b-PFGE) Block Copolymer Films Adv. Funct. Mater. 2013, 23 (39) 4921-4932 10.1002/adfm.201300469
56. Aissou, K.; Mumtaz, M.; Fleury, G.; Portale, G.; Navarro, C.; Cloutet, E.; Brochon, C.; Ross, C. A.; Hadziioannou, G. Sub-10 nm Features Obtained from Directed Self-Assembly of Semicrystalline Polycarbosilane-Based Block Copolymer Thin Films Adv. Mater. 2015, 27 (2) 261-265 10.1002/adma.201404077
57. Li, Z.; Kesselman, E.; Talmon, Y.; Hillmyer, M. A.; Lodge, T. P. Multicompartment Micelles from ABC Miktoarm Stars in Water Science 2004, 306 (5693) 98-101 10.1126/science.1103350
58. Kubowicz, S.; Baussard, J.-F.; Lutz, J.-F.; Thünemann, A. F.; von Berlepsch, H.; Laschewsky, A. Multicompartment Micelles Formed by Self-Assembly of Linear ABC Triblock Copolymers in Aqueous Medium Angew. Chem., Int. Ed. 2005, 44 (33) 5262-5265 10.1002/anie.200500584
59. Gröschel, A. H.; Müller, A. H. E. Self-assembly concepts for multicompartment nanostructures Nanoscale 2015, 7 (28) 11841-11876 10.1039/C5NR02448J
60. Rinkenauer, A. C.; Schallon, A.; Günther, U.; Wagner, M.; Betthausen, E.; Schubert, U. S.; Schacher, F. H. A Paradigm Change: Efficient Transfection of Human Leukemia Cells by Stimuli-Responsive Multicompartment Micelles ACS Nano 2013, 7 (11) 9621-9631 10.1021/nn402072d
61. Staff, R. H.; Gallei, M.; Mazurowski, M.; Rehahn, M.; Berger, R.; Landfester, K.; Crespy, D. Patchy Nanocapsules of Poly(vinylferrocene)-Based Block Copolymers for Redox-Responsive Release ACS Nano 2012, 6 (10) 9042-9049 10.1021/nn3031589
62. Hayward, R. C.; Pochan, D. J. Tailored Assemblies of Block Copolymers in Solution: It Is All about the Process Macromolecules 2010, 43 (8) 3577-3584 10.1021/ma9026806
63. Xia, Y.; Whitesides, G. M. Soft Lithography Annu. Rev. Mater. Sci. 1998, 28 (1) 153-184 10.1146/annurev.matsci.28.1.153
64. Qin, D.; Xia, Y.; Whitesides, G. M. Soft lithography for micro- and nanoscale patterning Nat. Protoc. 2010, 5 (3) 491-502 10.1038/nprot.2009.234
65. Perl, A.; Reinhoudt, D. N.; Huskens, J. Microcontact Printing: Limitations and Achievements Adv. Mater. 2009, 21 (22) 2257-2268 10.1002/adma.200801864
66. Coyer, S. R.; García, A. J.; Delamarche, E. Facile Preparation of Complex Protein Architectures with Sub-100-nm Resolution on Surfaces Angew. Chem., Int. Ed. 2007, 46 (36) 6837-6840 10.1002/anie.200700989
67. Feng, C. L.; Embrechts, A.; Bredebusch, I.; Schnekenburger, J.; Domschke, W.; Vancso, G. J.; Schönherr, H. Reactive Microcontact Printing on Block Copolymer Films: Exploiting Chemistry in Microcontacts for Sub-micrometer Patterning of Biomolecules Adv. Mater. 2007, 19 (2) 286-290 10.1002/adma.200601047
68. Zdyrko, B.; Luzinov, I. Polymer Brushes by the "Grafting to" Method Macromol. Rapid Commun. 2011, 32 (12) 859-869 10.1002/marc.201100162
69. Goldmann, A. S.; Barner, L.; Kaupp, M.; Vogt, A. P.; Barner-Kowollik, C. Orthogonal ligation to spherical polymeric microparticles: Modular approaches for surface tailoring Prog. Polym. Sci. 2012, 37 (7) 975-984 10.1016/j.progpolymsci.2011.11.008
70. Olivier, A.; Meyer, F.; Raquez, J.-M.; Damman, P.; Dubois, P. Surface-initiated controlled polymerization as a convenient method for designing functional polymer brushes: From self-assembled monolayers to patterned surfaces Prog. Polym. Sci. 2012, 37 (1) 157-181 10.1016/j.progpolymsci.2011.06.002
71. Rodriguez-Emmenegger, C.; Preuss, C. M.; Yameen, B.; Pop-Georgievski, O.; Bachmann, M.; Mueller, J. O.; Bruns, M.; Goldmann, A. S.; Bastmeyer, M.; Barner-Kowollik, C. Controlled Cell Adhesion on Poly(dopamine) Interfaces Photopatterned with Non-Fouling Brushes Adv. Mater. 2013, 25 (42) 6123-6127 10.1002/adma.201302492
72. Tischer, T.; Rodriguez-Emmenegger, C.; Trouillet, V.; Welle, A.; Schueler, V.; Mueller, J. O.; Goldmann, A. S.; Brynda, E.; Barner-Kowollik, C. Photo-Patterning of Non-Fouling Polymers and Biomolecules on Paper Adv. Mater. 2014, 26 (24) 4087-4092 10.1002/adma.201401006
73. Delaittre, G.; Goldmann, A. S.; Mueller, J. O.; Barner-Kowollik, C. Efficient Photochemical Approaches for Spatially Resolved Surface Functionalization Angew. Chem., Int. Ed. 2015, 54 (39) 11388-11403 10.1002/anie.201504920
74. Jaggy, M.; Zhang, P.; Greiner, A. M.; Autenrieth, T. J.; Nedashkivska, V.; Efremov, A. N.; Blattner, C.; Bastmeyer, M.; Levkin, P. A. Hierarchical Micro-Nano Surface Topography Promotes Long-Term Maintenance of Undifferentiated Mouse Embryonic Stem Cells Nano Lett. 2015, 15 (10) 7146-7154 10.1021/acs.nanolett.5b03359
75. Tasdelen, M. A.; Yagci, Y. Light-Induced Click Reactions Angew. Chem., Int. Ed. 2013, 52 (23) 5930-5938 10.1002/anie.201208741
76. Roling, O.; De Bruycker, K.; Vonhören, B.; Stricker, L.; Körsgen, M.; Arlinghaus, H. F.; Ravoo, B. J.; Du Prez, F. E. Rewritable Polymer Brush Micropatterns Grafted by Triazolinedione Click Chemistry Angew. Chem., Int. Ed. 2015, 54 (44) 13126-13129 10.1002/anie.201506361
77. von Freymann, G.; Ledermann, A.; Thiel, M.; Staude, I.; Essig, S.; Busch, K.; Wegener, M. Three-Dimensional Nanostructures for Photonics Adv. Funct. Mater. 2010, 20 (7) 1038-1052 10.1002/adfm.200901838
78. Hell, S. W. Microscopy and its focal switch Nat. Methods 2009, 6 (1) 24-32 10.1038/nmeth.1291
79. Cavalcanti-Adam, E. A.; Volberg, T.; Micoulet, A.; Kessler, H.; Geiger, B.; Spatz, J. P. Cell Spreading and Focal Adhesion Dynamics Are Regulated by Spacing of Integrin Ligands Biophys. J. 2007, 92 (8) 2964-2974 10.1529/biophysj.106.089730
80. Klein, F.; Striebel, T.; Fischer, J.; Jiang, Z.; Franz, C. M.; von Freymann, G.; Wegener, M.; Bastmeyer, M. Elastic Fully Three-dimensional Microstructure Scaffolds for Cell Force Measurements Adv. Mater. 2010, 22 (8) 868-871 10.1002/adma.200902515
81. Geiger, B.; Spatz, J. P.; Bershadsky, A. D. Environmental sensing through focal adhesions Nat. Rev. Mol. Cell Biol. 2009, 10 (1) 21-33 10.1038/nrm2593
82. Kilian, K. A.; Bugarija, B.; Lahn, B. T.; Mrksich, M. Geometric cues for directing the differentiation of mesenchymal stem cells Proc. Natl. Acad. Sci. U. S. A. 2010, 107 (11) 4872-4877 10.1073/pnas.0903269107
83. Huang, J.; Gräter, S. V.; Corbellini, F.; Rinck, S.; Bock, E.; Kemkemer, R.; Kessler, H.; Ding, J.; Spatz, J. P. Impact of Order and Disorder in RGD Nanopatterns on Cell Adhesion Nano Lett. 2009, 9 (3) 1111-1116 10.1021/nl803548b
84. El-Ali, J.; Sorger, P. K.; Jensen, K. F. Cells on chips Nature 2006, 442 (7101) 403-411 10.1038/nature05063
85. Harrison, R. G. The reaction of embryonic cells to solid structures J. Exp. Zool. 1914, 17 (4) 521-544 10.1002/jez.1400170403
86. Gillette, B. M.; Jensen, J. A.; Tang, B.; Yang, G. J.; Bazargan-Lari, A.; Zhong, M.; Sia, S. K. In situ collagen assembly for integrating microfabricated three-dimensional cell-seeded matrices Nat. Mater. 2008, 7 (8) 636-640 10.1038/nmat2203
87. Greiner, A. M.; Richter, B.; Bastmeyer, M. Micro-Engineered 3D Scaffolds for Cell Culture Studies Macromol. Biosci. 2012, 12 (10) 1301-1314 10.1002/mabi.201200132
88. Adzima, B. J.; Kloxin, C. J.; DeForest, C. A.; Anseth, K. S.; Bowman, C. N. 3D Photofixation Lithography in Diels-Alder Networks Macromol. Rapid Commun. 2012, 33 (24) 2092-2096 10.1002/marc.201200599
89. Berg, G. J.; Gong, T.; Fenoli, C. R.; Bowman, C. N. A Dual-Cure, Solid-State Photoresist Combining a Thermoreversible Diels-Alder Network and a Chain Growth Acrylate Network Macromolecules 2014, 47 (10) 3473-3482 10.1021/ma500244r
90. Cicha, K.; Koch, T.; Torgersen, J.; Li, Z.; Liska, R.; Stampfl, J. Young's modulus measurement of two-photon polymerized micro-cantilevers by using nanoindentation equipment J. Appl. Phys. 2012, 112 (9) 094906 10.1063/1.4764330
91. Li, Z.; Stankevicius, E.; Ajami, A.; Raciukaitis, G.; Husinsky, W.; Ovsianikov, A.; Stampfl, J.; Liska, R. 3D alkyne-azide cycloaddition: spatiotemporally controlled by combination of aryl azide photochemistry and two-photon grafting Chem. Commun. 2013, 49 (69) 7635-7637 10.1039/c3cc43533d
92. Petrochenko, P. E.; Torgersen, J.; Gruber, P.; Hicks, L. A.; Zheng, J.; Kumar, G.; Narayan, R. J.; Goering, P. L.; Liska, R.; Stampfl, J.; Ovsianikov, A. Laser 3D Printing with Sub-Microscale Resolution of Porous Elastomeric Scaffolds for Supporting Human Bone Stem Cells Adv. Healthcare Mater. 2015, 4 (5) 739-747 10.1002/adhm.201400442
93. Quick, A. S.; de los Santos Pereira, A.; Bruns, M.; Bückmann, T.; Rodriguez-Emmenegger, C.; Wegener, M.; Barner-Kowollik, C. Rapid Thiol-Yne-Mediated Fabrication and Dual Postfunctionalization of Micro-Resolved 3D Mesostructures Adv. Funct. Mater. 2015, 25 (24) 3735-3744 10.1002/adfm.201500683
94. Quick, A. S.; Fischer, J.; Richter, B.; Pauloehrl, T.; Trouillet, V.; Wegener, M.; Barner-Kowollik, C. Preparation of Reactive Three-Dimensional Microstructures via Direct Laser Writing and Thiol-ene Chemistry Macromol. Rapid Commun. 2013, 34 (4) 335-340 10.1002/marc.201200796
95. Quick, A. S.; Rothfuss, H.; Welle, A.; Richter, B.; Fischer, J.; Wegener, M.; Barner-Kowollik, C. Fabrication and Spatially Resolved Functionalization of 3D Microstructures via Multiphoton-Induced Diels-Alder Chemistry Adv. Funct. Mater. 2014, 24 (23) 3571-3580 10.1002/adfm.201304030
96. Claus, T. K.; Richter, B.; Hahn, V.; Welle, A.; Kayser, S.; Wegener, M.; Bastmeyer, M.; Delaittre, G.; Barner-Kowollik, C. Simultaneous Dual Encoding of Three-Dimensional Structures by Light-Induced Modular Ligation Angew. Chem., Int. Ed. 2016, 55 (11) 3817-3822 10.1002/anie.201509937
97. Pauloehrl, T.; Welle, A.; Oehlenschlaeger, K. K.; Barner-Kowollik, C. Spatially controlled surface immobilization of nucleophiles via trapping of photo-generated thioaldehydes Chem. Sci. 2013, 4 (9) 3503-3507 10.1039/c3sc50815c
98. Gruendling, T.; Oehlenschlaeger, K. K.; Frick, E.; Glassner, M.; Schmid, C.; Barner-Kowollik, C. Rapid UV Light-Triggered Macromolecular Click Conjugations via the Use of o-Quinodimethanes Macromol. Rapid Commun. 2011, 32 (11) 807-812 10.1002/marc.201100159
99. Hohmann, J. K.; Renner, M.; Waller, E. H.; von Freymann, G. Three-Dimensional μ-Printing: An Enabling Technology Adv. Opt. Mater. 2015, 3 (11) 1488-1507 10.1002/adom.201500328
100. Klein, F.; Richter, B.; Striebel, T.; Franz, C. M.; Freymann, G. v.; Wegener, M.; Bastmeyer, M. Two-Component Polymer Scaffolds for Controlled Three-Dimensional Cell Culture Adv. Mater. 2011, 23 (11) 1341-1345 10.1002/adma.201004060
101. Miserez, A.; Schneberk, T.; Sun, C.; Zok, F. W.; Waite, J. H. The Transition from Stiff to Compliant Materials in Squid Beaks Science 2008, 319 (5871) 1816-1819 10.1126/science.1154117
102. Waite, J. H.; Lichtenegger, H. C.; Stucky, G. D.; Hansma, P. Exploring Molecular and Mechanical Gradients in Structural Bioscaffolds Biochemistry 2004, 43 (24) 7653-7662 10.1021/bi049380h
103. Claussen, K. U.; Scheibel, T.; Schmidt, H.-W.; Giesa, R. Polymer Gradient Materials: Can Nature Teach Us New Tricks? Macromol. Mater. Eng. 2012, 297 (10) 938-957 10.1002/mame.201200032
104. Ionov, L. Hydrogel-based actuators: possibilities and limitations Mater. Today 2014, 17 (10) 494-503 10.1016/j.mattod.2014.07.002
105. Libanori, R.; Erb, R. M.; Reiser, A.; Le Ferrand, H.; Süess, M. J.; Spolenak, R.; Studart, A. R. Stretchable heterogeneous composites with extreme mechanical gradients Nat. Commun. 2012, 3, 1265 10.1038/ncomms2281
106. Claussen, K. U.; Giesa, R.; Schmidt, H.-W. Longitudinal polymer gradient materials based on crosslinked polymers Polymer 2014, 55 (1) 29-38 10.1016/j.polymer.2013.11.018
107. Claussen, K. U.; Lintz, E. S.; Giesa, R.; Schmidt, H.-W.; Scheibel, T. Protein Gradient Films of Fibroin and Gelatine Macromol. Biosci. 2013, 13 (10) 1396-1403 10.1002/mabi.201300221
108. Diederich, V. E. G.; Studer, P.; Kern, A.; Lattuada, M.; Storti, G.; Sharma, R. I.; Snedeker, J. G.; Morbidelli, M. Bioactive polyacrylamide hydrogels with gradients in mechanical stiffness Biotechnol. Bioeng. 2013, 110 (5) 1508-1519 10.1002/bit.24810
109. Singh, P.; Deckert, V. Local protonation control using plasmonic activation Chem. Commun. 2014, 50 (76) 11204-11207 10.1039/C4CC04642K
110. Tallarida, N.; Rios, L.; Apkarian, V. A.; Lee, J. Isomerization of One Molecule Observed through Tip-Enhanced Raman Spectroscopy Nano Lett. 2015, 15 (10) 6386-6394 10.1021/acs.nanolett.5b01543
111. Kurouski, D.; Mattei, M.; Van Duyne, R. P. Probing Redox Reactions at the Nanoscale with Electrochemical Tip-Enhanced Raman Spectroscopy Nano Lett. 2015, 15 (12) 7956-7962 10.1021/acs.nanolett.5b04177
112. Arnold, R. M.; Patton, D. L.; Popik, V. V.; Locklin, J. A Dynamic Duo: Pairing Click Chemistry and Postpolymerization Modification To Design Complex Surfaces Acc. Chem. Res. 2014, 47 (10) 2999-3008 10.1021/ar500191m
113. Hiltebrandt, K.; Pauloehrl, T.; Blinco, J. P.; Linkert, K.; Börner, H. G.; Barner-Kowollik, C. λ-Orthogonal Pericyclic Macromolecular Photoligation Angew. Chem., Int. Ed. 2015, 54 (9) 2838-2843 10.1002/anie.201410789
114. Espeel, P.; Du Prez, F. E. Click-Inspired Chemistry in Macromolecular Science: Matching Recent Progress and User Expectations Macromolecules 2015, 48 (1) 2-14 10.1021/ma501386v
115. Barner-Kowollik, C.; Du Prez, F. E.; Espeel, P.; Hawker, C. J.; Junkers, T.; Schlaad, H.; Van Camp, W. Clicking" Polymers or Just Efficient Linking: What Is the Difference? Angew. Chem., Int. Ed. 2011, 50 (1) 60-62 10.1002/anie.201003707
116. Mueller, J. O.; Schmidt, F. G.; Blinco, J. P.; Barner-Kowollik, C. Visible-Light-Induced Click Chemistry Angew. Chem., Int. Ed. 2015, 54 (35) 10284-10288 10.1002/anie.201504716
117. Lederhose, P.; Wuest, K. N. R.; Barner-Kowollik, C.; Blinco, J. P. Catalyst free visible light induced cycloaddition as an avenue for polymer ligation Chem. Commun. 2016, 52, 5928-5931 10.1039/C6CC00942E
118. van Dijken, D. J.; Kovaříček, P.; Ihrig, S. P.; Hecht, S. Acylhydrazones as Widely Tunable Photoswitches J. Am. Chem. Soc. 2015, 137 (47) 14982-14991 10.1021/jacs.5b09519
119. Zhang, W.; Huang, M.; Su, H.; Zhang, S.; Yue, K.; Dong, X.-H.; Li, X.; Liu, H.; Zhang, S.; Wesdemiotis, C.; Lotz, B.; Zhang, W.-B.; Li, Y.; Cheng, S. Z. D. Toward Controlled Hierarchical Heterogeneities in Giant Molecules with Precisely Arranged Nano Building Blocks ACS Cent. Sci. 2016, 2 (1) 48-54 10.1021/acscentsci.5b00385
120. Korevaar, P. A.; Newcomb, C. J.; Meijer, E. W.; Stupp, S. I. Pathway Selection in Peptide Amphiphile Assembly J. Am. Chem. Soc. 2014, 136 (24) 8540-8543 10.1021/ja503882s
121. Fischer, J.; Wegener, M. Three-dimensional direct laser writing inspired by stimulated-emission-depletion microscopy Opt. Mater. Express 2011, 1 (4) 614-624 10.1364/OME.1.000614
122. Cao, Y.; Gan, Z.; Jia, B.; Evans, R. A.; Gu, M. High-photosensitive resin for super-resolution direct-laser-writing based on photoinhibited polymerization Opt. Express 2011, 19 (20) 19486-19494 10.1364/OE.19.019486
123. Wollhofen, R.; Katzmann, J.; Hrelescu, C.; Jacak, J.; Klar, T. A. 120 nm resolution and 55 nm structure size in STED-lithography Opt. Express 2013, 21 (9) 10831-10840 10.1364/OE.21.010831
124. Buchegger, B.; Kreutzer, J.; Plochberger, B.; Wollhofen, R.; Sivun, D.; Jacak, J.; Schütz, G. J.; Schubert, U.; Klar, T. A. Stimulated Emission Depletion Lithography with Mercapto-Functional Polymers ACS Nano 2016, 10 (2) 1954-1959 10.1021/acsnano.5b05863
125. Li, L.; Gattass, R. R.; Gershgoren, E.; Hwang, H.; Fourkas, J. T. Achieving λ/20 Resolution by One-Color Initiation and Deactivation of Polymerization Science 2009, 324, 910-913 10.1126/science.1168996
126. Scott, T. F.; Kowalski, B. A.; Sullivan, A. C.; Bowman, C. N.; McLeod, R. R. Two-Color Single-Photon Photoinitiation and Photoinhibition for Subdiffraction Photolithography Science 2009, 324 (5929) 913-917 10.1126/science.1167610
127. Valeur, B.; Berberan-Santos, M. N. Excitation Energy Transfer. In Molecular Fluorescence; Wiley-VCH Verlag GmbH & Co. KGaA: 2012; pp 213-261.
128. Mann, S. Systems of Creation: The Emergence of Life from Nonliving Matter Acc. Chem. Res. 2012, 45 (12) 2131-2141 10.1021/ar200281t
129. Dora Tang, T. Y.; Rohaida Che Hak, C.; Thompson, A. J.; Kuimova, M. K.; Williams, D. S.; Perriman, A. W.; Mann, S. Fatty acid membrane assembly on coacervate microdroplets as a step towards a hybrid protocell model Nat. Chem. 2014, 6 (6) 527-533 10.1038/nchem.1921
130. Boekhoven, J.; Hendriksen, W. E.; Koper, G. J. M.; Eelkema, R.; van Esch, J. H. Transient assembly of active materials fueled by a chemical reaction Science 2015, 349 (6252) 1075-1079 10.1126/science.aac6103
131. Heuser, T.; Steppert, A.-K.; Molano Lopez, C.; Zhu, B.; Walther, A. Generic Concept to Program the Time Domain of Self-Assemblies with a Self-Regulation Mechanism Nano Lett. 2015, 15 (4) 2213-2219 10.1021/nl5039506
132. Heinen, L.; Walther, A. Celebrating Soft Matter's 10th Anniversary: Approaches to program the time domain of self-assemblies Soft Matter 2015, 11 (40) 7857-7866 10.1039/C5SM01660F