Sub-10 nm features obtained from directed self-assembly of semicrystalline polycarbosilane-based block copolymer thin films

Advanced Materials

Volumn 27, Issue 2, 2015, Pages 261-265

  Aissou, Karim ^a   Mumtaz, Muhammad ^a   Fleury, Guillaume ^a   Portale, Giuseppe ^b   Navarro, Christophe ^c   Cloutet, Eric ^a   Brochon, Cyril ^a   Ross, Caroline A ^d   Hadziioannou, Georges ^a  

^a UNIVERSITÉ DE BORDEAUX   (France)

^b EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^c ARKEMA   (France)

^d Massachusetts Institute of Technology   (United States)

Author keywords

Anionic polymerization; Block copolymer; Crystallization; Directed self assembly; Long range order

Indexed keywords

ACRYLIC MONOMERS; ANIONIC POLYMERIZATION; BLOCK COPOLYMERS; COPOLYMERS; CRYSTALLIZATION; ESTERS; MICROPHASE SEPARATION; POLYSILANES;

BLOCK COPOLYMER THIN FILMS; DIRECTED SELF-ASSEMBLY; DOMAIN ORIENTATION; HIGHLY ORDERED ARRAYS; LONG RANGE ORDERS; LOW MOLECULAR WEIGHT; SEMICRYSTALLINES; THERMAL ANNEALING PROCESS;

SELF ASSEMBLY;

EID: 84920721245     PISSN: 09359648     EISSN: 15214095     Source Type: Journal    
DOI: 10.1002/adma.201404077     Document Type: Article

References (29)

1. R. Ruiz, H. Kang, F. A. Detcheverry, E. Dobisz, D. S. Kercher, T. R. Albrecht, J. J. de Pablo, P. F. Nealey, Science 2008, 321, 936.
2. S.-M. Park, X. Liang, B. D. Harteneck, T. E Pick, N. Hiroshiba, Y. Wu, B. A. Helms, D. L. Olynick, ACS Nano 2011, 5, 8523.
3. M. Steinhart, Adv. Polym. Sci. 2008, 220, 123.
4. C. A. Ross, J. Y. Cheng, MRS Bull. 2008, 33, 838.
5. T. Thurn-Albrecht, J. Schotter, G. A. Kästle, N. Emley, T. Shibauchi, L. Krusin-Elbaum, K. Guarini, C. T. Black, M. T. Tuominen, T. P. Russell, Science 2000, 290, 2126.
6. S. O. Kim, H. H. Solak, M. P. Stoykovich, N. J. Ferrier, J. J. de Pablo, P. F. Nealey, Nature 2003, 424, 411.
7. M. P. Stoykovich, M. Müller, S. O. Kim, H. H. Solak, E. W. Edwards, J. J. de Pablo, P. F. Nealey, Science 2005, 308, 1442.
8. P. Andrew, W. T. S. Huck, Soft Matter 2007, 220, 230.
9. R. A. Segalman, H. Yokoyama, E. J. Kramer, Adv. Mater. 2001, 13, 1152.
10. J. Y. Cheng, A. M. Mayes, C. A. Ross, Nat. Mater. 2004, 3, 823.
11. S. Park, D. H. Lee, J. Xu, B. Kim, S. W. Hong, U. Jeong, T. Xu, T. P. Russell, Science 2009, 323, 1030.
12. K. Aissou, J. Shaver, G. Fleury, G. Pécastaings, C. Brochon, C. Navarro, S. Grauby, J.-M. Rampnoux, S. Dilhaire, G. Hadziioannou, Adv. Mater. 2013, 25, 213.
13. Y. S. Jung, C. A. Ross, Nano Lett. 2007, 7, 2046.
14. J. Y. Cheng, F. L. Zhang, H. I. Smith, G. J. Vancso, C. A. Ross, Adv. Mater. 2006, 18, 597.
15. a) K. Aissou, H. K. Choi, A. Nunns, I. Manners, C. A. Ross, Nano Lett. 2013, 13, 835;
16. b) K. Aissou, A. Nunns, I. Manners, C. A. Ross, Small 2013, 9, 4077.
17. Y. S. Jung, W. Jung, C. A. Ross, Nano Lett. 2008, 8, 2975.
18. M. D. Rodwogin, C. S. Spanjers, C. Leighton, M. A. Hillmyer, ACS Nano 2010, 4, 725.
19. Q. D. Nghiem, D.-P. Kim, Chem. Mater. 2008, 20, 3735.
20. a) K. Matsumoto, H. Yamaoka, Macromolecules 1995, 28, 7029;
21. b) K. Matsumoto, H. Shimazu, M. Deguchi, H. Yamaoka, J. Polym. Sci., Part A: Polym. Chem. 1997, 35, 3207;
22. c) Q. D. Nghiem, D. P. Kim, S. O. Kim, J. Nanosci. Nanotechnol. 2008, 8, 5527.
23. J. Li, B. Kuttich, M. Gallei, J. Elbert, M. Rehahn, B. Stühn, Polymer 2013, 54, 5703.
24. A. N. Semenov, Sov. Phys. JETP 1985, 61, 733.
25. P. Mansky, Y. Liu, E. Huang, T. P. Russell, C. Hawker, Science 1997, 275, 1458.
26. S. H. Kim, M. J. Misner, T. P. Russell, Adv. Mater. 2004, 16, 2119.
27. A. Knoll, A. Horvat, K. Lyakhova, Phys. Rev. Lett. 2002, 89, 035501.
28. Y. X. Liu, E. Q. Chen, Coord. Chem. Rev. 2010, 254, 1011.
29. L. Li, D. Lambreva, W. H. de Jeu, J. Macromol. Sci., Part B: Phys. 2005, 43, 59.