gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors

Journal of the American Chemical Society

Volumn 137, Issue 45, 2015, Pages 14496-14501

  Hu, Mingyou ^a   Ni, Chuanfa ^a   Li, Lingchun ^a   Han, Yongxin ^b   Hu, Jinbo ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b MERCK RESEARCH LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHEMICAL REACTIONS; ORGANIC COMPOUNDS; TRANSITION METALS;

CARBENES; CROSS-COUPLINGS; DIAZO COMPOUNDS; DIFLUOROCARBENE; NUCLEOPHILIC ADDITIONS; OLEFINATION; ORGANIC SYNTHESIS;

BROMINE COMPOUNDS;

ACETIC ACID DERIVATIVE; AZIRINE DERIVATIVE; CARBENE; DIARYLDIAZOMETHANE DERIVATIVE; DIAZIRINE DERIVATIVE; DIAZOACETATE DERIVATIVE; DIAZOMETHANE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CROSS COUPLING REACTION; CYCLOADDITION; CYCLOPROPANATION; DIFLUOROOLEFINATION; ELECTROPHILICITY; FLUORINATION; HIGH TEMPERATURE; LOW TEMPERATURE; NUCLEOPHILICITY; OLEFINATION; REACTION TIME;

EID: 84947762378     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b09888     Document Type: Article

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