Copper-mediated trifluoromethylation of α-diazo esters with TMSCF3: The important role of water as a promoter

Journal of the American Chemical Society

Volumn 134, Issue 37, 2012, Pages 15257-15260

  Hu, Mingyou ^a   Ni, Chuanfa ^a   Hu, Jinbo ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENES; ITS EFFICIENCIES; ROLE OF WATER; TRIFLUOROMETHYL; TRIFLUOROMETHYLATION;

COPPER; ESTERIFICATION;

ESTERS;

ALKYL SUBSTITUTED 3,3,3 TRIFLUOROPROPANOATE DERIVATIVE; ALPHA DIAZO ESTER; ARYL SUBSTITUTED 3,3,3 TRIFLUOROPROPANOATE DERIVATIVE; BENZYL SUBSTITUTED 3,3,3 TRIFLUOROPROPANOATE DERIVATIVE; COPPER; ESTER DERIVATIVE; PROPIONIC ACID DERIVATIVE; REAGENT; RUPPERT PRAKASH REAGENT; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL STRUCTURE; METHYLATION; TRIFLUOROMETHYLATION;

AZO COMPOUNDS; COPPER; ESTERS; METHYLATION; WATER;

EID: 84866481449     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja307058c     Document Type: Article

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