Pd-catalyzed C=C double-bond formation by coupling of N-tosylhydrazones with benzyl halides

Organic Letters

Volumn 11, Issue 20, 2009, Pages 4732-4735

  Xiao, Qing ^b   Ma, Jian ^b   Yang, Yang ^b   Zhang, Yan ^b   Wang, Jianbo ^a  

^a PEKING UNIVERSITY   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CARBON; HYDRAZONE DERIVATIVE; NITROGEN; PALLADIUM;

ARTICLE; CATALYSIS; CHEMISTRY; HALOGENATION;

BENZENE; CARBON; CATALYSIS; HALOGENATION; HYDRAZONES; NITROGEN; PALLADIUM;

EID: 70349915905     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol901876w     Document Type: Article

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42. 3 (14 mg, 0.06 mmol) in PhMe (5 mL) was added benzyl bromide (la, 51 mg, 0.3 mmol) and l-(diphenylmethylene)-2-tosylhydrazone (2a, 105 mg, 0.3 mmol). The mixture was then stirred at 80 °C for 3 h. The reaction was monitored through. TLC. Solvent was removed in vacuo to leave a residue which was purified by column chromatography to afford pure 3a as a white solid (72 mg, 94%).
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