Azo-compound-mediated cyanoalkylation of alkenes by copper catalysis: General access to cyano-substituted oxindoles

Synthesis (Germany)

Volumn 47, Issue 11, 2015, Pages 1567-1580

  Tang, Shi ^a   Zhou, Dong ^a   Li, Zhi Hao ^a,b   Fu, Mei Jun ^a   Jie, Li ^a   Sheng, Rui Long ^b   Li, Shu Hua ^a  

^a JISHOU UNIVERSITY   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

alkenes; azo compounds; copper catalysis; cyanoalkylation; radical

Indexed keywords

CATALYSIS; CYANIDES; CYCLIZATION; HYDROCARBONS; OLEFINS;

ACTIVATED ALKENES; AZO COMPOUND; COPPER CATALYSIS; CYANOALKYLATION; FUNCTIONALIZATIONS; RADICAL; RADICAL ADDITION; RADICAL SOURCE;

COPPER;

1 [(1,3 DIMETHYL 2 OXOINDOLIN 3 YL)METHYL]CYCLOHEXANECARBONITRILE; 1 [(1,3,5 TRIMETHYL 2 OXOINDOLIN 3 YL)METHYL]CYCLOHEXANECARBONITRILE; 1 [(5 FLUORO 1,3 DIMETHYL 2 OXOINDOLIN 3 YL)METHYL]CYCLOHEXANECARBONITRILE; 2,2 DIMETHYL 3 (1 METHYL 2 OXO 2,4,5,6 TETRAHYDRO 1H PYRROLO[3,2,1 IJ]QUINOLIN 1 YL)PROPANENITRILE; 2,2 DIMETHYL 3 (1 METHYL 2 OXO 3 PHENYLINDOLIN 3 YL)PROPANENITRILE; 2,2 DIMETHYL 3 (1,3,4 TRIMETHYL 2 OXOINDOLIN 3 YL)PROPANENITRILE; 2,2 DIMETHYL 3 (1,3,6 TRIMETHYL 2 OXOINDOLIN 3 YL)PROPANENITRILE; 2,2 DIMETHYL 3 (1,3,7 TRIMETHYL 2 OXOINDOLIN 3 YL)PROPANENITRILE; 2,2' AZOBISISOBUTYRONITRILE; 3 (1 BENZYL 3 METHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (1 ETHYL 5 METHOXY 3 METHYL 2 OXOINDOLIN 3 YL) 2,2 DIETHYLPROPANENITRILE; 3 (1,3 DIMETHYL 2 OXO 5 (TRIFLUOROMETHYL)INDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (1,3 DIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (1,3 DIMETHYL 2 OXOINDOLIN 3 YL)PROPANENITRILE; 3 (4 CHLORO 1,3,7 TRIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (4,5 DICHLORO 1,3 DIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (5 CHLORO 1,3 DIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (5 FLUORO 1,3 DIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (5,6 DICHLORO 1,3 DIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; 3 (7 METHOXY 1,3 DIMETHYL 2 OXOINDOLIN 3 YL) 2,2 DIMETHYLPROPANENITRILE; ACETONITRILE; ALKENE DERIVATIVE; AZO COMPOUND; COPPER; DIISOPROPYL AZODICARBOXYLIC ACID; ETHYL 3 [(1 CYANOCYCLOHEXYL)METHYL] 1,3 DIMETHYL 2 OXOINDOLINE 5 CARBOXYLIC ACID; INDOLE DERIVATIVE; OXINDOLE DERIVATIVE; UNCLASSIFIED DRUG; UNINDEXED DRUG; [3 (2 CYANO 2 METHYLPROPYL) 1 METHYL 2 OXOINDOLIN 3 YL]METHYL ACETIC ACID;

ALKYLARYLATION; ALKYLATION; ARTICLE; CARBON HYDROGEN BOND; CATALYSIS; CATALYST; CHEMICAL BOND; CYANOALKYLATION; CYANOMETHYLATION; CYANOPROPYLATION; CYCLIZATION; REACTION OPTIMIZATION; SUBSTITUTION REACTION; SYNTHESIS;

EID: 84930047767     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0034-1379902     Document Type: Article

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