Role of hot electrons and metal - Oxide interfaces in surface chemistry and catalytic reactions

Chemical Reviews

Volumn 115, Issue 8, 2015, Pages 2781-2817

  Park, Jeong Young ^a,b   Baker, L Robert ^c   Somorjai, Gabor A ^d,e  

^a Institute for Basic Science   (South Korea)

^b Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^c OHIO STATE UNIVERSITY   (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

^e LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; CHARGE TRANSFER; CHEMICAL ACTIVATION; ELECTRONS; ENERGY CONVERSION; ENERGY DISSIPATION; HOT ELECTRONS; METALS;

ACTIVATION PATHWAY; CATALYTIC REACTIONS; CONVERSION PROCESS; ELECTRON EXCITATIONS; ENERGY DISSIPATION MECHANISM; FUNDAMENTAL MECHANISMS; HETEROGENEOUS REACTIONS; METAL OXIDE INTERFACE;

SURFACE REACTIONS;

EID: 84928473980     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/cr400311p     Document Type: Article

References (264)

1. Greber, T. Charge-Transfer Induced Particle Emission in Gas Surface Reactions Surf. Sci. Rep. 1997, 28, 1-64
2. Mantell, D. A.; Ryali, S. B.; Halpern, B. L.; Haller, G. L.; Fenn, J. B. The Exciting Oxidation of Co on Pt Chem. Phys. Lett. 1981, 81, 185-187
3. Haber, F.; Just, G. Ann. Phys. 1909, 30, 411
4. Haber, F.; Just, G. Ann. Phys. 1911, 30, 308
5. Kasemo, B. Photon Emission During Chemisorption of Oxygen on Al and Mg Surfaces Phys. Rev. Lett. 1974, 32, 1114-1117
6. Kasemo, B.; Tornqvist, E.; Norskov, J. K.; Lundqvist, B. I. Photon and Electron-Emission as Indicators of Intermediate States in Surface-Reactions Surf. Sci. 1979, 89, 554-565
7. Kasemo, B.; Wallden, L. Photon and Electron-Emission During Halogen Adsorption on Sodium Surf. Sci. 1975, 53, 393-407
8. Norskov, J. K.; Newns, D. M.; Lundqvist, B. I. Molecular-Orbital Description of Surface Chemi-Luminescence Surf. Sci. 1979, 80, 179-188
9. Majorana, E. Nuovo Cimento 1932, 9, 43-50
10. Gergen, B.; Nienhaus, H.; Weinberg, W. H.; McFarland, E. W. Chemically Induced Electronic Excitations at Metal Surfaces Science 2001, 294, 2521-2523
11. Nienhaus, H. Electronic Excitations by Chemical Reactions on Metal Surfaces Surf. Sci. Rep. 2002, 45, 3-78
12. Tully, J. C. Chemical Dynamics at Metal Surfaces Annu. Rev. Phys. Chem. 2000, 51, 153-178
13. Lee, H.; Nedrygailov, I. I.; Lee, C.; Somorjai, G. A.; Park, J. Y. Chemical Reaction-induced Hot Electron Flows on Pt Colloid Nanoparticles under Hydrogen Oxidation: Impact of Nanoparticle Size Angew. Chem., Int. Ed. 2015, 54, 2340-2344
14. Kim, S. M.; Lee, H.; Park, J. Y. Charge Transport in Metal-Oxide Interfaces: Genesis and Detection of Hot Electron Flow and Its Role in Heterogeneous Catal. Lett. 2015, 145, 299-308
15. Shenvi, N.; Cheng, H. Z.; Tully, J. C. Nonadiabatic Dynamics near Metal Surfaces: Decoupling Quantum Equations of Motion in the Wide-Band Limit Phys. Rev. A 2006, 74, 10
16. Somorjai, G. A.; Park, J. Y. The Impact of Surface Science on the Commercialization of Chemical Processes Catal. Lett. 2007, 115, 87-98
17. Gadzuk, J. W. On the Detection of Chemically-Induced Hot Electrons in Surface Processes: From X-Ray Edges to Schottky Barriers J. Phys. Chem. B 2002, 106, 8265-8270
18. Shenvi, N.; Roy, S.; Parandekar, P.; Tully, J. Vibrational Relaxation of No on Au(111) Via Electron-Hole Pair Generation J. Chem. Phys. 2006, 125, 9
19. Baker, L. R.; Kennedy, G.; Van Spronsen, M.; Hervier, A.; Cai, X.; Chen, S.; Wang, L.-W.; Somorjai, G. A. Furfuraldehyde Hydrogenation on Titanium Oxide-Supported Platinum Nanoparticles Studied by Sum Frequency Generation Vibrational Spectroscopy: Acid-Base Catalysis Explains the Molecular Origin of Strong Metal-Support Interactions J. Am. Chem. Soc. 2012, 134, 14208-14216
20. Park, J. Y.; Somorjai, G. A. The Catalytic Nanodiode: Detecting Continous Electron Flow at Oxide-Metal Interfaces Generated by a Gas-Phase Exothermic Reaction ChemPhysChem 2006, 7, 1409-1413
21. Hervier, A.; Renzas, J. R.; Park, J. Y.; Somorjai, G. A. Hydrogen Oxidation-Driven Hot Electron Flow Detected by Catalytic Nanodiodes Nano Lett. 2009, 9, 3930-3933
22. Baker, L. R.; Hervier, A.; Kennedy, G.; Somorjai, G. A. Solid-State Charge-Based Device for Control of Catalytic Carbon Monoxide Oxidation on Platinum Nanofilms Using External Bias and Light Nano Lett. 2012, 12, 2554-2558
23. Park, J. Y.; Kim, S. M.; Lee, H.; Naik, B. Hot Electron and Surface Plasmon-Driven Catalytic Reaction in Metal-Semiconductor Nanostructures Catal. Lett. 2014, 144, 1996-2004
24. Baker, L. R.; Hervier, A.; Seo, H.; Kennedy, G.; Komvopoulos, K.; Somorjai, G. A. Highly N-Type Titanium Oxide as an Electronically Active Support for Platinum in the Catalytic Oxidation of Carbon Monoxide J. Phys. Chem. C 2011, 115, 16006-16011
25. 2 with Nitrogen and Fluorine and Its Support Effect on Catalytic Activity of CO Oxidation Catal. Lett. 2014, 144, 1411-1417
26. Burns, G. Solid State Physics; Academic Press: Orlando, FL, 1985, p 407.
27. Manson, J. R. Energy Transfer to Phonons in Atom and Molecule Collisions with Surfaces, Handbook of Surface Science; Elsevier: Amsterdam, 2008; Chapter 3, pp 53-94.
28. Gumhalter, B. Single-and Multiphonon Atom-Surface Scattering in the Quantum Regime Phys. Rep. 2001, 351, 1-159
29. Chang, H. C.; Ewing, G. E. Infrared Fluorescence from a Monolayer of CO on Nacl(100) Phys. Rev. Lett. 1990, 65, 2125-2128
30. Ewing, G. E. Energy Flow from Excited Molecules on Salt Surfaces Acc. Chem. Res. 1992, 25, 292-299
31. -2 System Phys. Rev. Lett. 1990, 65, 2035-2037
32. Born, M.; Oppenheimer, R. Ann. Phys. 1927, 389, 457-484
33. Schaich, W. L. Brownian-Motion Model of Surface Chemical-Reactions-Derivation in Large Mass Limit J. Chem. Phys. 1974, 60, 1087-1093
34. Schaich, W. L. Model Calculation of Brownian-Motion Parameters at a Metal-Surface Surf. Sci. 1975, 49, 221-235
35. Dagliano, E. G.; Kumar, P.; Schaich, W.; Suhl, H. Brownian-Motion Model of Interactions between Chemical Species and Metallic Electrons-Bootstrap Derivation and Parameter Evaluation Phys. Rev. B 1975, 11, 2122-2143
36. Head-Gordon, M.; Tully, J. C. Vibrational-Relaxation on Metal-Surfaces-Molecular-Orbital Theory and Application to CO/Cu(100) J. Chem. Phys. 1992, 96, 3939-3949
37. Persson, B. N. J.; Persson, M. Vibrational Lifetime for CO Adsorbed on Cu(100) Solid State Commun. 1980, 36, 175-179
38. Persson, B. N. J.; Persson, M. Damping of Vibrations in Molecules Adsorbed on a Metal-Surface Surf. Sci. 1980, 97, 609-624
39. Huang, Y. H.; Rettner, C. T.; Auerbach, D. J.; Wodtke, A. M. Vibrational Promotion of Electron Transfer Science 2000, 290, 111-114
40. White, J. D.; Chen, J.; Matsiev, D.; Auerbach, D. J.; Wodtke, A. M. Vibrationally Promoted Emission of Electrons from Low Work Function Surfaces: Oxygen and Cs Surface Coverage Dependence J. Vac. Sci. Technol. A 2005, 23, 1085-1089
41. White, J. D.; Chen, J.; Matsiev, D.; Auerbach, D. J.; Wodtke, A. M. Conversion of Large-Amplitude Vibration to Electron Excitation at a Metal Surface Nature 2005, 433, 503-505
42. Wodtke, A. M.; Tully, J. C.; Auerbach, D. J. Electronically Non-Adiabatic Interactions of Molecules at Metal Surfaces: Can We Trust the Born-Oppenheimer Approximation for Surface Chemistry? Int. Rev. Phys. Chem. 2004, 23, 513-539
43. Landau, L. D. Phys. Z. Sowjetunion 1932, 2, 46
44. Zener, G. Proc. R. Soc. London A 1932, 137, 696-702
45. Stückelberg, E. C. G. Helv. Phys. Acta 1932, 5, 369-423
46. 2, and Pt/GaN Catalytic Nanodiodes Influencing Hot Electron Flow J. Phys. Chem. C 2007, 111, 15331-15336
47. Groeneveld, R. H. M.; Sprik, R.; Lagendijk, A. Effect of a Nonthermal Electron-Distribution on the Electron-Phonon Energy Relaxation Process in Noble-Metals Phys. Rev. B 1992, 45, 5079-5082
48. Suarez, C.; Bron, W. E.; Juhasz, T. Dynamics and Transport of Electronic Carriers in Thin Gold-Films Phys. Rev. Lett. 1995, 75, 4536-4539
49. Ogawa, S.; Petek, H. Two-Photon Photoemission Spectroscopy at Clean and Oxidized Cu(110) and Cu(100) Surfaces Surf. Sci. 1996, 363, 313-320
50. Hertel, T.; Knoesel, E.; Wolf, M.; Ertl, G. Ultrafast Electron Dynamics at Cu(111): Response of an Electron Gas to Optical Excitation Phys. Rev. Lett. 1996, 76, 535-538
51. Lingle, R. L.; Ge, N. H.; Jordan, R. E.; McNeill, J. D.; Harris, C. B. Femtosecond Studies of Electron Tunneling at Metal-Dielectric Interfaces Chem. Phys. 1996, 205, 191-203
52. Ogawa, S.; Nagano, H.; Petek, H. Hot-Electron Dynamics at Cu(100), Cu(110), and Cu(111) Surfaces: Comparison of Experiment with Fermi-Liquid Theory Phys. Rev. B 1997, 55, 10869-10877
53. Petek, H.; Ogawa, S. Femtosecond Time-Resolved Two-Photon Photoemission Studies of Electron Dynamics in Metals Prog. Surf. Sci. 1997, 56, 239-310
54. Amirav, A.; Cardillo, M. J. Electron-Hole Pair Creation by Atomic Scattering at Surfaces Phys. Rev. Lett. 1986, 57, 2299-2302
55. Amirav, A.; Lambert, W. R.; Cardillo, M. J.; Trevor, P. L.; Luke, P. N.; Haller, E. E. Electron-Hole Pair Creation at a Ge(100) Surface by Ground-State Neutral Xe Atoms J. Appl. Phys. 1986, 59, 2213-2215
56. Huang, Y.; Wodtke, A. M.; Hou, H.; Rettner, C. T.; Auerbach, D. J. Observation of Vibration Excitation and Deexcitation for NO(N=2) Scattering from Au(111): Evidence for Electron-Hole-Pair Mediated Energy Transfer Phys. Rev. Lett. 2000, 84, 2985-2988
57. Hou, H.; Huang, Y.; Gulding, S. J.; Rettner, C. T.; Auerbach, D. J.; Wodtke, A. M. Direct Multiquantum Relaxation of Highly Vibrationally Excited NO in Collisions with O/Cu(111) J. Chem. Phys. 1999, 110, 10660-10663
58. Hou, H.; Rettner, C. T.; Auerbach, D. J.; Huang, Y.; Gulding, S. J.; Wodtke, A. M. The Interaction of Highly Vibrationally Excited Molecules with Surfaces: Vibrational Relaxation and Reaction of NO(V) at Cu(111) and O/Cu(111) Faraday Discuss. 1999, 113, 181-200
59. White, J. D.; Chen, J.; Matsiev, D.; Auerbach, D. J.; Wodtke, A. M. Vibrationally Promoted Electron Emission from Low Work-Function Metal Surfaces J. Chem. Phys. 2006, 124, 064702
60. Holloway, S.; Gadzuk, J. W. Charge-Transfer, Vibrational-Excitation, and Dissociative Adsorption in Molecule Surface Collisions-Classical Trajectory Theory J. Chem. Phys. 1985, 82, 5203-5215
61. Holloway, S.; Gadzuk, J. W. Energy Redistribution and Dissociation in Molecule Surface Collisions Involving Charge-Transfer Surface Hopping Surf. Sci. 1985, 152, 838-850
62. Shenvi, N.; Roy, S.; Tully, J. C. Dynamical Steering and Electronic Excitation in No Scattering from a Gold Surface Science 2009, 326, 829-832
63. Shenvi, N.; Roy, S.; Tully, J. C. Nonadiabatic Dynamics at Metal Surfaces: Independent-Electron Surface Hopping J. Chem. Phys. 2009, 130, 174107
64. Hellberg, L.; Stromquist, J.; Kasemo, B.; Lundqvist, B. I. Electron-Transfer Pathways in Dynamic Processes-Cl-2 on K Phys. Rev. Lett. 1995, 74, 4742-4745
65. Denzler, D. N.; Frischkorn, C.; Hess, C.; Wolf, M.; Ertl, G. Electronic Excitation and Dynamic Proportion of a Surface Reaction Phys. Rev. Lett. 2003, 91, 226102-226101-226102-226104
66. Trenhaile, B. R.; Antonov, V. N.; Xu, G. J.; Nakayama, K. S.; Weaver, J. H. Electron-Stimulated Desorption from an Unexpected Source: Internal Hot Electrons for Br-Si(100)-(2 × 1) Surf. Sci. 2005, 583, L135-L141
67. Prietsch, M.; Ludeke, R. Ballistic-Electron-Emission Microscopy and Spectroscopy of Gap(110)-Metal Interfaces Phys. Rev. Lett. 1991, 66, 2511-2514
68. Schowalter, L. J.; Lee, E. Y. Role of Elastic-Scattering in Ballistic-Electron-Emission Microscopy of Au/Si(001) and Au/Si(111) Interfaces Phys. Rev. B 1991, 43, 9308-9311
69. Rubin, M. E.; MedeirosRibeiro, G.; Oshea, J. J.; Chin, M. A.; Lee, E. Y.; Petroff, P. M.; Narayanamurti, V. Imaging and Spectroscopy Elf Single InAs Self-Assembled Quantum Dots Using Ballistic Electron Emission Microscopy Phys. Rev. Lett. 1996, 77, 5268-5271
70. Sirringhaus, H.; Lee, E. Y.; Vonkanel, H. Hot-Carrier Scattering at Interfacial Dislocations Observed by Ballistic-Electron-Emission Microscopy Phys. Rev. Lett. 1994, 73, 577-580
71. Kovacs, D. A.; Peters, T.; Haake, C.; Schleberger, M.; Wucher, A.; Golczewski, A.; Aumayr, F.; Diesing, D. Potential Electron Emission Induced by Multiply Charged Ions in Thin Film Tunnel Junctions Phys. Rev.B 2008, 77, 245432
72. Diesing, D.; Winkes, H.; Otto, A. Time Resolved Investigation of the Hydrogen Evolution Reaction on Ag(111), Ag(100), Smooth Polycrystalline, and Activated Polycrystalline Silver Surfaces Phys. Status Solidi A 1997, 159, 243-254
73. Diesing, D.; Merschdorf, M.; Thon, A.; Pfeiffer, W. Identification of Multiphoton Induced Photocurrents in Metal-Insulator-Metal Junctions Appl. Phys. B: Lasers Opt. 2004, 78, 443-446
74. Thon, A.; Merschdorf, M.; Pfeiffer, W.; Klamroth, T.; Saalfrank, P.; Diesing, D. Photon-Assisted Tunneling Versus Tunneling of Excited Electrons in Metal-Insulator-Metal Junctions Appl. Phys. A: Mater. Sci. Process 2004, 78, 189-199
75. Kovacs, D. A.; Babkina, T.; Gans, T.; Czarnetzki, U.; Diesing, D. Electronic Excitation in Metals through Hyperthermal Atoms J. Phys. D: Appl. Phys. 2006, 39, 5224-5229
76. Kovacs, D. A.; Winter, J.; Meyer, S.; Wucher, A.; Diesing, D. Photo and Particle Induced Transport of Excited Carriers in Thin Film Tunnel Junctions Phys. Rev. B 2007, 76, 235408
77. Mildner, B.; Hasselbrink, E.; Diesing, D. Electronic Excitations Induced by Surface Reactions of H and D on Gold Chem. Phys. Lett. 2006, 432, 133-138
78. Marpe, M.; Heuser, C.; Diesing, D.; Wucher, A. Internal Electron Emission in Metal-Insulator-Metal Thin Film Tunnel Devices Bombarded with KeV Argon and Gold-Cluster Projectiles Nucl. Instrum. Methods Phys. Res., Sect. B 2011, 269, 972-976
79. Peters, T.; Haake, C.; Diesing, D.; Kovacs, D. A.; Golczewski, A.; Kowarik, G.; Aumayr, F.; Wucher, A.; Schleberger, M. Hot Electrons Induced by Slow Multiply Charged Ions New J. Phys. 2008, 10, 073019
80. Schindler, B.; Diesing, D.; Hasselbrink, E. Electronic Excitations Induced by Hydrogen Surface Chemical Reactions on Gold J. Chem. Phys. 2011, 134, 034705
81. Stella, K.; Kovacs, D. A.; Diesing, D.; Brezna, W.; Smoliner, J. Charge Transport through Thin Amorphous Titanium and Tantalum Oxide Layers J. Electrochem. Soc. 2011, 158, P65-P74
82. Thissen, P.; Schindler, B.; Diesing, D.; Hasselbrink, E. Optical Response of Metal-Insulator-Metal Heterostructures and Their Application for the Detection of Chemicurrents New J. Phys. 2010, 12, 113014
83. Sharpe, R. G.; Dixonwarren, S.; Durston, P. J.; Palmer, R. E. The Electronic Catalyst-Dissociation of Chlorinated Hydrocarbons by Metal-Insulator-Metal Electron Emitters Chem. Phys. Lett. 1995, 234, 354-358
84. Wadayama, T.; Kojim, A.; Hatta, A. Bias-Voltage-Induced Decomposition of 2-Methyl-1,4-Naphthoquinone on Ag/Alox/Al Tunnel Junction Appl. Phys. A: Mater. Sci. Process 2004, 79, 1891-1894
85. Wadayama, T.; Yokawa, M. Hot-Electron Assisted Reaction of P-Nitrobenzoic Acid Adsorbed on Metal-Insulator-Metal Tunnel Junction's Electrode Surface Chem. Phys. Lett. 2006, 428, 348-351
86. Nienhaus, H.; Bergh, H. S.; Gergen, B.; Majumdar, A.; Weinberg, W. H.; McFarland, E. W. Electron-Hole Pair Creation at Ag and Cu Surfaces by Adsorption of Atomic Hydrogen and Deuterium Phys. Rev. Lett. 1999, 82, 446-449
87. Nienhaus, H.; Bergh, H. S.; Gergen, B.; Majumdar, A.; Weinberg, W. H.; McFarland, E. W. Direct Detection of Electron-Hole Pairs Generated by Chemical Reactions on Metal Surfaces Surf. Sci. 2000, 445, 335-342
88. Rankin, R. B.; Greeley, J. Trends in Selective Hydrogen Peroxide Production on Transition Metal Surfaces from First Principles ACS Catal. 2012, 2, 2664-2672
89. Trail, J. R.; Graham, M. C.; Bird, D. M.; Persson, M.; Holloway, S. Energy Loss of Atoms at Metal Surfaces Due to Electron-Hole Pair Excitations: First-Principles Theory of "Chemicurrents" Phys. Rev. Lett. 2002, 88, 166802
90. 2 on Polycristalline Ag Surf. Sci. 2001, 488, 123-132
91. Hagemann, U.; Krix, D.; Nienhaus, H. Electronic Excitations Generated by the Deposition of Mg on Mg Films Phys. Rev. Lett. 2010, 104, 028301
92. Hagemann, U.; Timmer, M.; Krix, D.; Kratzer, P.; Nienhaus, H. Electronic Excitations in Magnesium Epitaxy: Experiment and Theory Phys. Rev. B 2010, 82, 155420
93. Mizielinski, M. S.; Bird, D. M.; Persson, M.; Holloway, S. Electronic Nonadiabatic Effects in the Adsorption of Hydrogen Atoms on Metals J. Chem. Phys. 2005, 122, 084710
94. Bonn, M.; Funk, S.; Hess, C.; Denzler, D. N.; Stampfl, C.; Scheffler, M.; Wolf, M.; Ertl, G. Phonon- Versus Electron-Mediated Desorption and Oxidation of CO on Ru(0001) Science 1999, 285, 1042-1045
95. Somorjai, G. A.; Li, Y. Introduction to Surface Chemistry and Catalysis, 2nd ed.; Johns Wiley & Sons, Inc.: Hoboken, NJ, 2010.
96. Preparation of Solid Catalysts; Ertl, G.; Knozinger, H.; Weitkamp, J., Eds.; Wiley-VCH: Weinheim, Germany, 1999.
97. Schwab, G. M. Metal Electrons and Catalysis Trans. Faraday Soc. 1946, 42, 689-697
98. Schwab, G. M.; Noller, H.; Steinback, F.; Venugopalan, M. Oxidaation of Carbon Monoxide and Methyl Alcohol Photosensitized in the Gas Phase by Zinc Oxide Nature 1962, 193, 774
99. Schwab, G. M.; Steinback, F.; Noller, H.; Venugopalan, M. Z. Naturforsch. 1964, 19a, 445
100. Schwab, G. M.; Koller, K. Combined Action of Metal and Semiconductor Catalysts J. Am. Chem. Soc. 1968, 90, 3078-3080
101. Hume-Rothery, W.; Mabbott, G. W.; Channel Evans, K. M. The Freezing Points, Melting Points, and Solid Solubility Limits of the Alloys of Silver, and Copper with the Elements of the B Sub-Groups Philos. Trans. R. Soc. London, A 1934, 233, 1-97
102. Hume-Rothery, W.; Lewin, G. F.; Reynolds, P. W. The Lattice Spacings of Certain Primary Solid Solutions in Silver and Copper Proc. R. Soc. A 1936, 157, 167-183
103. Mott, N. F.; Jones, H. The Theory of the Properties of Metals and Alloys; Dover Publishing: 1958.
104. Dalla Betta, R. A.; Boudart, M. Proc. Int. Congr. Catal., 5th 1973, 2, 1329
105. Gallezot, P.; Datka, J.; Massardier, J.; Primet, M.; Imelik, B. Proc. Int. Congr. Catal., 6th 1976, A11
106. ;2 J. Am. Chem. Soc. 1978, 100, 170-175
107. Tauster, S. J.; Fung, S. C.; Baker, R. T. K.; Horsley, J. A. Strong-Interactions in Supported-Metal Catalysts Science 1981, 211, 1121-1125
108. Baker, R. T. K.; Prestridge, E. B.; Garten, R. L. Electron Microscopy of Supported Metal Particles: I. Behavior of Pt on Titanium Oxide, Aluminum Oxide, Silicon Oxide, and Carbon J. Catal. 1979, 56, 390-406
109. Horsley, J. A. A Molecular Orbital Study of Strong Metal-Support Interaction between Platinum and Titanium Dioxide J. Am. Chem. Soc. 1979, 101, 2870-2874
110. 2 J. Catal. 1994, 149, 142-148
111. Bernal, S.; Calvino, J. J.; Cauqui, M. A.; Gatica, J. M.; López Cartes, C.; Pérez Omil, J. A.; Pintado, J. M. Some Contributions of Electron Microscopy to the Characterisation of the Strong Metal-Support Interaction Effect Catal. Today 2003, 77, 385-406
112. Simoens, A. J.; Baker, R. T. K.; Dwyer, D. J.; Lund, C. R. F.; Madon, R. J. A Study of the Nickel-Titanium Oxide Interaction J. Catal. 1984, 86, 359-372
113. Haerudin, H.; Bertel, S.; Kramer, R. Surface Stoichiometry of 'Titanium Suboxide' Part I Volumetric and Ftir Study J. Chem. Soc., Faraday Trans. 1998, 94, 1481-1487
114. Jochum, W.; Eder, D.; Kaltenhauser, G.; Kramer, R. Impedance Measurements in Catalysis: Charge Transfer in Titania Supported Noble Metal Catalysts Top. Catal. 2007, 46, 49-55
115. 2 Synthesis Reactions J. Catal. 1979, 56, 236-248
116. Vannice, M. A. Titania-Supported Metals as CO Hydrogenation Catalysts J. Catal. 1982, 74, 199-202
117. 2 and CO on Nickel Surfaces: Consequences for Understanding Methanation over Titania-Supported Nickel Catalysts J. Catal. 1985, 96, 597-612
118. 2 Reaction in the Absence of Strong Metal-Support Interactions (SMSI) J. Catal. 1984, 86, 384-391
119. 2 Hydrogenation Reactivity J. Catal. 1993, 139, 602-610
120. Boffa, A.; Lin, C.; Bell, A. T.; Somorjai, G. A. Promotion of CO and CO2 Hydrogenation over Rh by Metal Oxides: The Influence of Oxide Lewis Acidity and Reducibility J. Catal. 1994, 149, 149-158
121. Ichikawa, M.; Fukushima, T. Infrared Studies of Metal Additive Effects on Carbon Monoxide Chemisorption Modes on Silicon Dioxide-Supported Rhodium-Manganese, -Titanium and Iron Catalysts J. Phys. Chem. 1985, 89, 1564-1567
122. Sachtler, W. M. H.; Shriver, D. F.; Hollenberg, W. B.; Lang, A. F. Promoter Action in Fischer-Tropsch Catalysis J. Catal. 1985, 92, 429-431
123. 2-Supported RhFe and PdFe Bimetallic Clusters Catal. Today 1989, 6, 55-62
124. Olah, G. A.; Molnar, A. Hydrocarbon Chemistry, 2 nd ed.; John Wiley & Sons, Inc.: Hoboken, NJ, 2003.
125. Yao, Y.-F. Y. The Oxidation of CO and Hydrocarbons over Noble Metal Catalysts J. Catal. 1984, 87, 152-162
126. Over, H.; Muhler, M. Catalytic CO Oxidation over Ruthenium - Bridging the Pressure Gap Prog. Surf. Sci. 2003, 72, 3-17
127. Schwank, J. Catalytic Gold Gold Bull. 1983, 16, 103-110
128. Hammer, B.; Norskov, J. K. Why Gold Is the Noblest of All the Metals Nature 1995, 376, 238-240
129. Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. Gold Catalysts Prepared by Coprecipitation for Low-Temperature Oxidation of Hydrogen and of Carbon Monoxide J. Catal. 1989, 115, 301-309
130. Valden, M.; Lai, X.; Goodman, D. W. Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties Science 1998, 281, 1647-1650
131. Haruta, M. Size- and Support-Dependency in the Catalysis of Gold Catal. Today 1997, 36, 153-166
132. 2 catalysts in the Presence of Oxygen and Hydrogen J. Catal. 1998, 178, 566-575
133. 2(110) Catal. Lett. 1999, 63, 143-151
134. Chusuei, C. C.; Lai, X.; Luo, K.; Goodman, D. W. Modeling Heterogeneous Catalysts: Metal Clusters on Planar Oxide Supports Top. Catal. 2001, 14, 71-83
135. 2 J. Am. Chem. Soc. 2004, 126, 1892-1899
136. Goodman, D. Catalytically Active Au on Titania:" yet Another Example of a Strong Metal Support Interaction (SMSI)? Catal. Lett. 2005, 99, 1-4
137. 2 (110) Phys. Rev. Lett. 2003, 90, 026101
138. 2 Catalysts by Suspension Spray Reaction Method and Their Catalytic Property for CO Oxidation Appl. Catal., A 2003, 246, 87-95
139. 2 (110) Phys. Rev. B 2000, 61, 14066-14071
140. 2 (110) Surfaces J. Chem. Phys. 2003, 118, 6536-6551
141. Grunwaldt, J.-D.; Baiker, A. Gold/Titania Interfaces and Their Role in Carbon Monoxide Oxidation J. Phys. Chem. B 1999, 103, 1002-1012
142. Schubert, M. M.; Hackenberg, S.; van Veen, A. C.; Muhler, M.; Plzak, V.; Behm, R. J. CO Oxidation over Supported Gold Catalysts-"Inert" and "Active" Support Materials and Their Role for the Oxygen Supply During Reaction J. Catal. 2001, 197, 113-122
143. Molina, L. M.; Hammer, B. Active Role of Oxide Support During CO Oxidation at Au/Mgo Phys. Rev. Lett. 2003, 90, 206102
144. Bondzie, V.; Parker, S.; Campbell, C. The Kinetics of CO Oxidation by Adsorbed Oxygen on Well-Defined Gold Particles on Tio2(110) Catal. Lett. 1999, 63, 143-151
145. Mills, G.; Gordon, M. S.; Metiu, H. Oxygen Adsorption on Au Clusters and a Rough Au(111) Surface: The Role of Surface Flatness, Electron Confinement, Excess Electrons, and Band Gap J. Chem. Phys. 2003, 118, 4198-4205
146. Lemire, C.; Meyer, R.; Shaikhutdinov, S.; Freund, H.-J. Do Quantum Size Effects Control CO Adsorption on Gold Nanoparticles? Angew. Chem., Int. Ed. 2004, 43, 118-121
147. Lopez, N.; Janssens, T. V. W.; Clausen, B. S.; Xu, Y.; Mavrikakis, M.; Bligaard, T.; Nørskov, J. K. On the Origin of the Catalytic Activity of Gold Nanoparticles for Low-Temperature Co Oxidation J. Catal. 2004, 223, 232-235
148. 2 Prepared by Deposition-Precipitation with Naoh And urea J. Catal. 2004, 222, 357-367
149. 2 for CO Oxidation Catal. Lett. 1997, 44, 83-87
150. Sanchez, A.; Abbet, S.; Heiz, U.; Schneider, W. D.; Häkkinen, H.; Barnett, R. N.; Landman, U. When Gold Is Not Noble: Nanoscale Gold Catalysts J. Phys. Chem. A 1999, 103, 9573-9578
151. Guzman, J.; Gates, B. C. Simultaneous Presence of Cationic and Reduced Gold in Functioning Mgo-Supported Co Oxidation Catalysts: Evidence from X-Ray Absorption Spectroscopy J. Phys. Chem. B 2002, 106, 7659-7665
152. Fu, Q.; Saltsburg, H.; Flytzani-Stephanopoulos, M. Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts Science 2003, 301, 935-938
153. 2 J. Catal. 1982, 76, 225-230
154. Sexton, B. A.; Hughes, A. E.; Foger, K. XPS Investigation of Strong Metal Support Interactions of Group Iiia-Va Oxides J. Catal. 1982, 77, 85-93
155. Chien, S.-H.; Shelimov, B. N.; Resasco, D. E.; Lee, E. H.; Haller, G. L. Characterization of the Interaction between Rhodium and Titanium Oxide by XPS J. Catal. 1982, 77, 301-303
156. Bahl, M. K.; Tsai, S. C.; Chung, Y. W. Auger and Photoemission Investigations of the Platinum-Srtio-{3}(100) Interface: Relaxation and Chemical-Shift Effects Phys. Rev. B 1980, 21, 1344-1348
157. Kao, C. C.; Tsai, S. C.; Bahl, M. K.; Chung, Y. W.; Lo, W. J. Electronic Properties, Structure and Temperature-Dependent Composition of Nickel Deposited on Rutile Titanium Dioxide (110) Surfaces Surf. Sci. 1980, 95, 1-14
158. Hughes, M. D.; Xu, Y.-J.; Jenkins, P.; McMorn, P.; Landon, P.; Enache, D. I.; Carley, A. F.; Attard, G. A.; Hutchings, G. J.; King, F.; Stitt, E. H.; Johnston, P.; Griffin, K.; Kiely, C. J. Tunable Gold Catalysts for Selective Hydrocarbon Oxidation under Mild Conditions Nature 2005, 437, 1132-1135
159. 2 Catalysts Science 2006, 311, 362-365
160. 2+ Science 2008, 321, 1072-1075
161. Jiao, F.; Frei, H. Nanostructured Cobalt and Manganese Oxide Clusters as Efficient Water Oxidation Catalysts Energy Environ. Sci. 2010, 3, 1018-1027
162. Somorjai, G. A.; Park, J. Y. Frontiers of Surface Science Phys. Today 2007, 60, 48
163. An, K.; Musselwhite, N.; Kennedy, G.; Pushkarev, V. V.; Robert Baker, L.; Somorjai, G. A. Preparation of Mesoporous Oxides and Their Support Effects on Pt Nanoparticle Catalysts in Catalytic Hydrogenation of Furfural J. Colloid Interface Sci. 2013, 392, 122-128
164. Kennedy, G.; Baker, L. R.; Somorjai, G. A. Selective Amplification of Ci=O Bond Hydrogenation on Platinum with TiO2 as a Support. Catalytic Reaction and Sum-Frequency Generation Vibrational Spectroscopy Studies of Crotonaldehyde Hydrogenation Angew. Chem. Int. Ed. 2014, 53, 3405-3408
165. Pushkarev, V.; Zhu, Z.; An, K.; Hervier, A.; Somorjai, G. Monodisperse Metal Nanoparticle Catalysts: Synthesis, Characterizations, and Molecular Studies under Reaction Conditions Top. Catal. 2012, 55, 1257-1275
166. Seo, H.; Baker, L. R.; Hervier, A.; Kim, J.; Whitten, J. L.; Somorjai, G. A. Generation of Highly N-Type Titanium Oxide Using Plasma Fluorine Insertion Nano Lett. 2010, 11, 751-756
167. Shi, F.; Baker, L. R.; Hervier, A.; Somorjai, G. A.; Komvopoulos, K. Tuning the Electronic Structure of Titanium Oxide Support to Enhance the Electrochemical Acticity of Platinum Nanoparticles Nano Lett. 2013, 13, 4469-4474
168. Sheldon, R. A.; Kochi, J. K. Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic Methodology Including Biochemical Processes; Academic Press: New York, 1981.
169. 2-Supported Au-Pd Catalysts J. Catal. 2005, 236, 69-79
170. Lambert, R. M.; Cropley, R. L.; Husain, A.; Tikhov, M. S. Halogen-Induced Selectivity in Heterogeneous Epoxidation Is an Electronic Effect-Fluorine, Chlorine, Bromine and Iodine in the Ag-Catalysed Selective Oxidation of Ethene Chem. Commun. 2003, 1184-1185
171. Haller, G. L.; Resasco, D. E. Metal Support Interaction-Group-Viii Metals and Reducible Oxides Adv. Catal. 1989, 36, 173-235
172. Tauster, S. J. Strong Metal-Support Interactions Acc. Chem. Res. 1987, 20, 389-394
173. Goodman, D. W. "Catalytically Active Au on Titania": Yet Another Example of a Strong Metal Support Interaction (Smsi)? Catal. Lett. 2005, 99, 1-4
174. Schwab, G. M. Boundary-Layer Catalysis Angew. Chem. Int. Ed. 1967, 6, 375-&
175. Schwab, G. M.; Siegert, R. Inverse Mischkatalysatoren.I. Kohlenmonoxid-Oxydation an Nickeloxid Auf Silber Z. Phys. Chem.-Frankfurt 1966, 50, 191
176. Hayek, K.; Fuchs, M.; Klotzer, B.; Reichl, W.; Rupprechter, G. Studies of Metal-Support Interactions with "Real" and "Inverted" Model Systems: Reactions of CO and Small Hydrocarbons with Hydrogen on Noble Metals in Contact with Oxides Top. Catal. 2000, 13, 55-66
177. Penner, S.; Wang, D.; Podloucky, R.; Schlogl, R.; Hayek, K. Rh and Pt Nanoparticles Supported by CeO2: Metal-Support Interaction Upon High-Temperature Reduction Observed by Electron Microscopy Phys. Chem. Chem. Phys. 2004, 6, 5244-5249
178. Penner, S.; Wang, D.; Su, D. S.; Rupprechter, G.; Podloucky, R.; Schlogl, R.; Hayek, K. Platinum Nanocrystals Supported by Silica, Alumina and Ceria: Metal-Support Interaction Due to High-Temperature Reduction in Hydrogen Surf. Sci. 2003, 532, 276-280
179. Park, J. Y.; Somorjai, G. A. Energy Conversion from Catalyic Reaction to Hot Electron Current with Metal-Semiconductor Schottky Nanodiodes J. Vac. Sci. Technol. B 2006, 24, 1967-1971
180. Somorjai, G. A.; Frei, H.; Park, J. Y. Advancing the Frontiers in Nanocatalysis, Biointerfaces, and Renewable Energy Conversion by Innovations of Surface Techniques J. Am. Chem. Soc. 2009, 131, 16589-16605
181. Lee, Y. K.; Jung, C. H.; Park, J.; Seo, H.; Somorjai, G. A.; Park, J. Y. Surface Plasmon-Driven Hot Electron Flow Probed with Metal-Semiconductor Nanodiodes Nano Lett. 2011, 11, 4251-4255
182. Ali, M.; Cimalla, V.; Lebedev, V.; Romanus, H.; Tilak, V.; Merfeld, D.; Sandvik, P.; Ambacher, O. Pt/GaN Schottky Diodes for Hydrogen Gas Sensors Sens. Actuators, B 2006, 113, 797-804
183. Wang, L.; Nathan, M. I.; Lim, T. H.; Khan, M. A.; Chen, Q. High Barrier Height Gan Schottky Diodes: Pt/Gan and Pd/Gan Appl. Phys. Lett. 1996, 68, 1267-1269
184. 2/Ti Schottky Diodes J. Appl. Phys. 2005, 98, 104501
185. Ji, X. Z.; Zuppero, A.; Gidwani, J. M.; Somorjai, G. A. Electron Flow Generated by Gas Phase Exothermic Catalytic Reactions Using a Platinum-Gallium Nitride Nanodiode J. Am. Chem. Soc. 2005, 127, 5792-5793
186. Park, J. Y.; Renzas, J. R.; Contreras, A. M.; Somorjai, G. A. The Genesis and Importance of Oxide-Metal Interface Controlled Heterogeneous Catalysis; the Catalytic Nanodiode Top. Catal. 2007, 46, 217-222
187. Somorjai, G. A.; Bratlie, K. M.; Montano, M. O.; Park, J. Y. Dynamics of Surface Catalyzed Reactions; the Roles of Surface Defects, Surface Diffusion, and Hot Electrons J. Phys. Chem. B 2006, 110, 20014-20022
188. Glass, S.; Nienhaus, H. Continuous Monitoring of Mg Oxidation by Internal Exoemission Phys. Rev. Lett. 2004, 93, 168302
189. Nienhaus, H.; Krix, D.; Glass, S. Varying the Schottky Barrier of Thin Film Mg/H: P-Si(111) Contacts: Properties and Applications J. Vac. Sci. Technol. A 2007, 25, 950-954
190. 2O on Pt: Oh Desorption at High Temperature J. Phys. Chem. 1992, 96, 5922-5931
191. Michaelides, A.; Hu, P. Catalytic Water Formation on Platinum: A First-Principles Study J. Am. Chem. Soc. 2001, 123, 4235-4242
192. Smith, J. N.; Palmer, R. L. Molecular-Beam Study of Oxidation of Deuterium on a (111) Platinum Surface J. Chem. Phys. 1972, 56, 13
193. Volkening, S.; Bedurftig, K.; Jacobi, K.; Wintterlin, J.; Ertl, G. Dual-Path Mechanism for Catalytic Oxidation of Hydrogen on Platinum Surfaces Phys. Rev. Lett. 1999, 83, 2672-2675
194. Verheij, L. K.; Hugenschmidt, M. B.; Colln, L.; Poelsema, B.; Comsa, G. The Deuterium-Oxygen Reaction on Pt(111)-Influence of Atomic Steps Chem. Phys. Lett. 1990, 166, 523-530
195. Anton, A. B.; Cadogan, D. C. The Mechanism and Kinetics of Water Formation on Pt(111) Surf. Sci. 1990, 239, L548-L560
196. Fisher, G. B.; Sexton, B. A. Identification of an Adsorbed Hydroxyl Species on the Pt(111) Surface Phys. Rev. Lett. 1980, 44, 683-686
197. Roland, U.; Braunschweig, T.; Roessner, F. On the Nature of Spilt-over Hydrogen J. Mol. Catal. A 1997, 127, 61-84
198. 2 over Supported Platinum Catalysts J. Catal. 1978, 53, 56-67
199. Hellsing, B.; Kasemo, B.; Zhdanov, V. P. Kinetics of the Hydrogen Oxygen Reaction on Platinum J. Catal. 1991, 132, 210-228
200. Kwong, D. W. J.; Deleon, N.; Haller, G. L. Desorption of Carbon-Dioxide Molecules from a Pt(111) Surface-a Stochastic Classical Trajectory Approach Chem. Phys. Lett. 1988, 144, 533-540
201. Renzas, J. R.; Somorjai, G. A. Rh Thin-Film Nanocatalysts as Chemical Sensors-the Flot Electron Effect J. Phys. Chem. C 2010, 114, 17660-17664
202. 2 Schottky Diodes During Catalytic CO Oxidation Nano Lett. 2008, 8, 2388-2392
203. Park, J. Y.; Aliaga, C.; Renzas, J. R.; Lee, H.; Somorjai, G. A. The Role of Organic Capping Layers of Platinum Nanoparticles in Catalytic Activity of CO Oxidation Catal. Lett. 2009, 129, 1-6
204. Creighton, J. R.; Coltrin, M. E. Origin of Reaction-Induced Current in Pt/GaN Catalytic Nanodiodes J. Phys. Chem. C 2011, 116, 1139-1144
205. Karpov, E. G.; Nedrygailov, I. I. Solid-State Electric Generator Based on Chemically Induced Internal Electron Emission in Metal-Semiconductor Heterojunction Nanostructures Appl. Phys. Lett. 2009, 94, 214101-214103
206. Karpov, E. G.; Nedrygailov, I. Nonadiabatic Chemical-to-Electrical Energy Conversion in Heterojunction Nanostructures Phys. Rev. B 2010, 81, 205443
207. Dasari, S. K.; Hashemian, M. A.; Mohan, J.; Karpov, E. G. A Nonthermal Chemicurrent Effect of Hydrogen Adsorption on Pt/Sic Planar Nanostructures at Normal Ambient Conditions Chem. Phys. Lett. 2012, 553, 47-50
208. Nedrygailov, I. I.; Karpov, E. G.; Hasselbrink, E.; Diesing, D. On the Significance of Thermoelectric and Thermionic Emission Currents Induced by Chemical Reactions Catalyzed on Nanofilm Metal - Semiconductor Heterostructures J. Vac. Sci. Technol. A 2013, 31, 021101-021105
209. Hashemian, M. A.; Dasari, S. K.; Karpov, E. G. Separation of Hot Electron Current Component Induced by Hydrogen Oxidation on Resistively Heated Pt/N-GaP Schottky Nanostructures J. Vac. Sci. Technol. A 2013, 31, 020603-020605
210. Renzas, J. R.; Somorjai, G. A. Rh Thin-Film Nanocatalysts as Chemical Sensors-the Hot Electron Effect J. Phys. Chem. C 2010, 114, 17660-17664
211. Maximoff, S. N.; Head-Gordon, M. P. Chemistry of Fast Electrons Proc. Natl. Acad. Sci. U.S.A. 2009, 106, 11460-11465
212. 2, and Pt/GaN Catalytic Nanodiodes from Oxidation of Carbon Monoxide J. Phys. Chem. B 2005, 109, 22530-22535
213. Park, J. Y.; Somorjai, G. A. Concepts, Instruments, and Model Systems that Enabled the Rapid Evolution of Surface Science Surf. Sci. 2009, 603, 1293-1300
214. Shen, T. C.; Wang, C.; Abeln, G. C.; Tucker, J. R.; Lyding, J. W.; Avouris, P.; Walkup, R. E. Atomic-Scale Desorption through Electronic and Vibrational-Excitation Mechanisms Science 1995, 268, 1590-1592
215. 2O on Pd(111) Surf. Sci. 2006, 600, 542-546
216. Choi, B. Y.; Kahng, S. J.; Kim, S.; Kim, H.; Kim, H. W.; Song, Y. J.; Ihm, J.; Kuk, Y. Conformational Molecular Switch of the Azobenzene Molecule: A Scanning Tunneling Microscopy Study Phys. Rev. Lett. 2006, 96, 156106
217. Henzl, J.; Mehlhorn, M.; Gawronski, H.; Rieder, K. H.; Morgenstern, K. Reversible Cis-Trans Isomerization of a Single Azobenzene Molecule Angew. Chem., Int. Ed. 2006, 45, 603-606
218. Gadzuk, J. W. Resonance-Assisted Hot Electron Femtochemistry at Surfaces Phys. Rev. Lett. 1996, 76, 4234-4237
219. Anisimov, S. I.; Kapeliov, Bl; Perelman, T. L. Electron-Emission from Surface of Metals Induced by Ultrashort Laser Pulses Zhurnal Eksperimentalnoi I Teoreticheskoi Fiziki 1974, 66, 776-781
220. Zhang, Y.; Kolmakov, A.; Chretien, S.; Metiu, H.; Moskovits, M. Control of Catalytic Reactions at the Surface of a Metal Oxide Nanowire by Manipulating Electron Density inside It Nano Lett. 2004, 4, 403-407
221. 2(110) Surface During Electronic Excitation J. Am. Chem. Soc. 2010, 132, 12804-12807
222. Sharpe, R. G.; Dixon-Warren, S. J.; Durston, P. J.; Palmer, R. E. The Electronic Catalyst: Dissociation of Chlorinated Hydrocarbons by Metal-Insulator-Metal Electron Emitters Chem. Phys. Lett. 1995, 234, 354-358
223. Wadayama, T.; Kojim, A.; Hatta, A. Bias-Voltage-Induced Decomposition of 2-Methyl-1,4-Naphthoquinone on Ag/AlOx/Al Tunnel Junction Appl. Phys. A: Mater. Sci. Process 2004, 79, 1891-1894
224. Wadayama, T.; Yokawa, M. Hot-Electron Assisted Reaction of P-Nitrobenzoic Acid Adsorbed on Metal-Insulator-Metal Tunnel Junction's Electrode Surface Chem. Phys. Lett. 2006, 428, 348-351
225. Diesing, D.; Janssen, H.; Otto, A. Surface Reactions with Hot Electrons and Hot Holes in Metals Surf. Sci. 1995, 331-333 (Part A) 289-293
226. Diesing, D.; Kritzler, G.; Stermann, M.; Nolting, D.; Otto, A. Metal/Insulator/Metal Junctions for Electrochemical Surface Science J. Solid State Electrochem. 2003, 7, 389-415
227. Thomsen, L. B.; Nielsen, G.; Vendelbo, S. B.; Johansson, M.; Hansen, O.; Chorkendorff, I. Ultralarge Area MOS Tunnel Devices for Electron Emission Phys. Rev. B 2007, 76, 155315
228. Ray, M. P.; Lake, R. E.; Thomsen, L. B.; Nielson, G.; Hansen, O.; Chorkendorff, I.; Sosolik, C. E. Towards Hot Electron Mediated Charge Exchange in Hyperthermal Energy Ion-Surface Interactions J. Phys.: Condens. Matter 2010, 22, 084010
229. 2 Catalytic Diode J. Am. Chem. Soc. 2011, 133, 16459-16467
230. Berlowitz, P. J.; Peden, C. H. F.; Goodman, D. W. Kinetics of Carbon Monoxide Oxidation on Single-Crystal Palladium, Platinum, and Iridium J. Phys. Chem. 1988, 92, 5213-5221
231. Su, X.; Cremer, P. S.; Shen, Y. R.; Somorjai, G. A. High-Pressure CO Oxidation on Pt(111) Monitored with Infrared-Visible Sum Frequency Generation J. Am. Chem. Soc. 1997, 119, 3994-4000
232. Saunders, A. E.; Popov, I.; Banin, U. Synthesis of Hybrid CdS-Au Colloidal Nanostructures J. Phys. Chem. B 2006, 110, 25421-25429
233. Mokari, T.; Sztrum, C. G.; Salant, A.; Rabani, E.; Banin, U. Formation of Asymmetric One-Sided Metal-Tipped Semiconductor Nanocrystal Dots and Rods Nat. Mater. 2005, 4, 855-863
234. Mokari, T.; Rothenberg, E.; Popov, I.; Costi, R.; Banin, U. Selective Growth of Metal Tips onto Semiconductor Quantum Rods and Tetrapods Science 2004, 304, 1787-1790
235. Milliron, D. J.; Hughes, S. M.; Cui, Y.; Manna, L.; Li, J. B.; Wang, L. W.; Alivisatos, A. P. Colloidal Nanocrystal Heterostructures with Linear and Branched Topology Nature 2004, 430, 190-195
236. Kuo, H. S.; Hwang, I. S.; Fu, T. Y.; Wu, J. Y.; Chang, C. C.; Tsong, T. T. Preparation and Characterization of Single-Atom Tips Nano Lett. 2004, 4, 2379-2382
237. Kim, S. M.; Lee, S. J.; Kim, S. H.; Kwon, S.; Yee, K. J.; Song, H.; Somorjai, G. A.; Park, J. Y. Hot Carrier-Driven Catalytic Reactions on Pt-CdSe-Pt Nanodumbbells and Pt/GaN under Light Irradiation Nano Lett. 2013, 13, 1352-1358
238. Schafer, S.; Wyrzgol, S. A.; Caterino, R.; Jentys, A.; Schoell, S. J.; Havecker, M.; Knop-Gericke, A.; Lercher, J. A.; Sharp, I. D.; Stutzmann, M. Platinum Nanoparticles on Gallium Nitride Surfaces: Effect of Semiconductor Doping on Nanoparticle Reactivity J. Am. Chem. Soc. 2012, 134, 12528-12535
239. 2 Nanocatalysts Prepared with Arc Plasma Deposition under Co Oxidation Appl. Catal., A 2013, 454, 53-58
240. 2 Substrate on Catalytic Activity of Co Oxidation J. Phys. Chem. C 2012, 116, 24054-24059
241. McFarland, E. W.; Tang, J. A Photovoltaic Device Structure Based on Internal Electron Emission Nature 2003, 421, 616-618
242. Knight, M. W.; Sobhani, H.; Nordlander, P.; Halas, N. J. Photodetection with Active Optical Antennas Science 2011, 332, 702-704
243. Lee, Y. K.; Park, J.; Park, J. Y. The Effect of Dye Molecules and Surface Plasmons in Photon-Induced Hot Electron Flows Detected on Au/Tio2 Nanodiodes J. Phys. Chem. C 2012, 116, 18591-18596
244. Lee, Y. K.; Lee, J.; Lee, H.; Lee, J. Y.; Park, J. Y. Probing Polarization Modes of Ag Nanowires with Hot Electron Detection on Au/Tio2 Nanodiodes Appl. Phys. Lett. 2013, 102, 123112
245. Jencks, W. P. When Is an Intermediate Not an Intermediate? Enforced Mechanisms of General Acid-Base, Catalyzed, Carbocation, Carbanion, and Ligand Exchange Reaction Acc. Chem. Res. 1980, 13, 161-169
246. Greeley, J.; Norskov, J. K.; Mavrikakis, M. Electronic Structure and Catalysis on Metal Surfaces Annu. Rev. Phys. Chem. 2002, 53, 319-348
247. Yamaguchi, T. Recent Progress in Solid Superacid Appl. Catal. 1990, 61, 1-25
248. Takahashi, O.; Hattori, H. Tracer Study of Conversion of Alkanes Catalyzed by Solid Super Acid J. Catal. 1981, 68, 144-151
249. Schmerling, L.; Vesely, J. A. Alkylation of Aromatic Hydrocarbons with Saturated Hydrocarbons J. Org. Chem. 1973, 38, 312-315
250. 2 Appl. Catal., A 1994, 107, 229-238
251. Kovacic, P.; Kyriakis, A. Polymerization of Benzene to P-Polyphenyl by Aluminum Chloride-Cupric Chloride J. Am. Chem. Soc. 1963, 85, 454-458
252. Li, W.; Shen, Z.; Zhang, Y. Activity and Mechanism of Rare Earth Solid Superacid for Initiating Ring-Opening Polymerization of Chloromethyl Thiirane Eur. Polym. J. 2001, 37, 1185-1190
253. Volkova, G. G.; Plyasova, L. M.; Shkuratova, L. N.; Budneva, A. A.; Paukshtis, E. A.; Timofeeva, M. N.; Likholobov, V. A. In Studies in Surface Science Catalysis; Xinhe, B.; Yide, X., Eds.; Elsevier: Amsterdam, 2004; Vol. 147.
254. Olah, G. A. Carbocations and Electrophilic Reactions Angew. Chem., Int. Ed. 1973, 12, 173-212
255. Heinerman, J. J. L.; Gaaf, J. The Isomerization Activity and Stability of Immobilized SbF5 J. Mol. Catal. 1981, 11, 215-224
256. Kayo, A.; Yamaguchi, T.; Tanabe, K. The Effect of Preparation Method on the Acidic and Catalytic Properties of Iron Oxide J. Catal. 1983, 83, 99-106
257. Yamaguchi, T.; Jin, T.; Tanabe, K. Structure of Acid Sites on Sulfur-Promoted Iron Oxide J. Phys. Chem. 1986, 90, 3148-3152
258. Ono, Y.; Tanabe, T.; Kitajima, N. The Synergism of AlCl3-CuCl2Mixtures in the Low-Temperature Conversion of Pentane J. Catal. 1979, 56, 47-51
259. Ono, Y.; Yamaguchi, K.; Kitajima, N. Isomerization of Pentane with AlCl3-CuSO4Mixtures J. Catal. 1980, 64, 13-17
260. Maxwell, I. E. Zeolite Catalysis in Hydroprocessing Technology Catal. Today 1987, 1, 385-413
261. 2 Structures in an Oxyhydrogen Atmosphere ACS Appl. Mater. Interfaces 2013, 5, 12375-12379
262. Contreras, A. M.; Grunes, J.; Yan, X. M.; Liddle, A.; Somorjai, G. A. Fabrication of Platinum Nanoparticles and Nanowires by Electron Beam Lithography and Nanoimprint Lithography: Comparison of Ethylene Hydrogenation Kinetics Catal. Lett. 2005, 100, 115-124
263. Contreras, A. M.; Grunes, J.; Yan, X. M.; Liddle, A.; Somorjai, G. A. Fabrication of 2-Dimensional Platinum Nanocatalyst Arrays by Electron Beam Lithography: Ethylene Hydrogenation and CO-Poisoning Reaction Studies Top. Catal. 2006, 39, 123-129
264. 2 Layers with Silanization and Self-Assembled Nanopatterning Langmuir 2013, 29, 3054-3060