A new class of non-C2-symmetric ligands for oxidative and redox-neutral palladium-catalyzed asymmetric allylic alkylations of 1,3-diketones

Journal of the American Chemical Society

Volumn 137, Issue 7, 2015, Pages 2776-2784

  Trost, Barry M ^a   Donckele, Etienne J ^a   Thaisrivongs, David A ^a   Osipov, Maksim ^a   Masters, James T ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; CATALYSIS; CHELATION; PALLADIUM;

1 ,3-DIKETONES; ASYMMETRIC ALLYLIC ALKYLATIONS; CHIRAL PRODUCT; HIGH YIELD; PALLADIUM-CATALYZED; PHOSPHORAMIDITE LIGANDS; PYROGLUTAMIC ACIDS;

LIGANDS;

1,3 DIKETONE; KETONE DERIVATIVE; LIGAND; PALLADIUM; PHOSPHORAMIDOUS ACID DERIVATIVE; PYROGLUTAMIC ACID; ALLYL COMPOUND; KETONE; ORGANOPHOSPHORUS COMPOUND; PHOSPHORAMIDOUS ACID;

ALKYLATION; ARTICLE; CATALYSIS; CATALYST; DECOMPOSITION; DERIVATIZATION; ENANTIOSELECTIVITY; NUCLEOPHILICITY; OXIDATION; RACEMIZATION; REACTION TIME; STEREOCHEMISTRY; STOICHIOMETRY; SYNTHESIS; TEMPERATURE; CHEMISTRY; OXIDATION REDUCTION REACTION; STEREOISOMERISM;

ALKYLATION; ALLYL COMPOUNDS; CATALYSIS; KETONES; LIGANDS; ORGANOPHOSPHORUS COMPOUNDS; OXIDATION-REDUCTION; PALLADIUM; STEREOISOMERISM;

EID: 84923609240     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b00786     Document Type: Article

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