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Volumn 360, Issue 7, 2007, Pages 2455-2463

Tetracoordinate diamidato-bis(phosphanyl) metal systems: Synthesis, characterization, and electrochemical analysis of palladium(II) complexes

Author keywords

Amidato metal bonding; Palladium complexes; Protection from reduction; Trost ligand; X ray crystal structures

Indexed keywords

CHLORINE COMPOUNDS; CYCLIC VOLTAMMETRY; LIGANDS; NITROGEN; REDUCTION; SYNTHESIS (CHEMICAL); X RAYS;

EID: 34147117846     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2006.12.011     Document Type: Article
Times cited : (17)

References (51)
  • 35
    • 0001405073 scopus 로고
    • and references therein
    • Collins T.J. Acc. Chem. Res. 27 (1994) 279 and references therein
    • (1994) Acc. Chem. Res. , vol.27 , pp. 279
    • Collins, T.J.1
  • 39
    • 34147110112 scopus 로고    scopus 로고
    • sadabs, Bruker Nonius area detector scaling and absorption correction - V2.10, Bruker AXS Inc., Madison, Wisconsin, USA, 2003.
  • 41
    • 34147102073 scopus 로고    scopus 로고
    • note
    • 2.
  • 42
    • 34147166392 scopus 로고    scopus 로고
    • shelxtl Version 5.1, Bruker AXS Inc., Madison, Wisconsin, USA, 1997.
  • 43
    • 34147104240 scopus 로고    scopus 로고
    • G.M. Sheldrick, shelxl-93, Program for crystal structure determination, University of Göttingen, Germany, 1993.
  • 45
    • 34147188334 scopus 로고    scopus 로고
    • note
    • o, and R-factors based on all data will be even larger.
  • 48
    • 34147184616 scopus 로고    scopus 로고
    • note
    • The individual phenyl group proton ABC-spin systems were identified but their assignment to a specific auxiliary phenyl group was arbitrary. The absolute identity cannot be assigned as the spatial relation of the phenyl groups to the backbone protons are too similar to be distinguished.
  • 49
    • 34147147342 scopus 로고    scopus 로고
    • note
    • The Campos structure did not undergo an absorption correction in its refinement, which could improve its R-factor. However, we are inclined to have more confidence in the final model we obtained, although the differences between the two models are subtle.
  • 50
    • 34147147826 scopus 로고    scopus 로고
    • note
    • 2 has been reported as -1.18 V (vs. SCE) in DMF.
  • 51
    • 34147167958 scopus 로고    scopus 로고
    • note
    • 2 also shows an irreversible oxidation peak on the reverse scan (-2.2 V to +1.0 V) at +0.124 V which characterized the complex generated by the reduction at -1.25 V. Similar results have been observed with carbene-palladium(II) and mixed carbene/phosphane-palladium(II) complexes. See J. Pytkowicz, S. Roland, P. Mangeney, G. Meyer, A. Jutand, J. Organomet. Chem. 678 (2003) 166.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.