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Collins, T.J.1
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39
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34147110112
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sadabs, Bruker Nonius area detector scaling and absorption correction - V2.10, Bruker AXS Inc., Madison, Wisconsin, USA, 2003.
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40
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0242560405
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SIR97:
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SIR97:. Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., Guagliardi A., Moliterni A.G.G., Polidori G., and Spagna R. J. Appl. Cryst. 32 (1999) 115
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Altomare, A.1
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Moliterni, A.G.G.7
Polidori, G.8
Spagna, R.9
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41
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34147102073
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note
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2.
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42
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34147166392
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shelxtl Version 5.1, Bruker AXS Inc., Madison, Wisconsin, USA, 1997.
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43
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34147104240
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G.M. Sheldrick, shelxl-93, Program for crystal structure determination, University of Göttingen, Germany, 1993.
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45
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34147188334
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note
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o, and R-factors based on all data will be even larger.
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47
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11844265889
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Campos K.R., Journet M., Lee S., Grabowski E.J., and Tillyer R.D. J. Org. Chem. 70 (2005) 268
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Campos, K.R.1
Journet, M.2
Lee, S.3
Grabowski, E.J.4
Tillyer, R.D.5
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48
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34147184616
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note
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The individual phenyl group proton ABC-spin systems were identified but their assignment to a specific auxiliary phenyl group was arbitrary. The absolute identity cannot be assigned as the spatial relation of the phenyl groups to the backbone protons are too similar to be distinguished.
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-
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49
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34147147342
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note
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The Campos structure did not undergo an absorption correction in its refinement, which could improve its R-factor. However, we are inclined to have more confidence in the final model we obtained, although the differences between the two models are subtle.
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50
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34147147826
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note
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2 has been reported as -1.18 V (vs. SCE) in DMF.
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51
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34147167958
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note
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2 also shows an irreversible oxidation peak on the reverse scan (-2.2 V to +1.0 V) at +0.124 V which characterized the complex generated by the reduction at -1.25 V. Similar results have been observed with carbene-palladium(II) and mixed carbene/phosphane-palladium(II) complexes. See J. Pytkowicz, S. Roland, P. Mangeney, G. Meyer, A. Jutand, J. Organomet. Chem. 678 (2003) 166.
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