Redox reaction of the Pd0 complex bearing the Trost ligand with meso-cycloalkene-1,4-biscarbonates leading to a diamidato PdII complex and 1,3-cycloalkadienes: Enantioselective desymmetrization versus catalyst deactivation

Chemistry - A European Journal

Volumn 16, Issue 9, 2010, Pages 2904-2915

  Tsarev, Vasily N ^a   Wolters, Dennis ^a   Gais, Hans Joachim ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Alkylation; Oxidation; Palladium; Redox chemistry; Trost ligand

Indexed keywords

ALLYLIC ALKYLATION; CATALYST LOADINGS; CATALYTIC AMOUNTS; COMPLEX 1; DESYM-METRIZATION; DIHYDROGEN; DIOXYGENS; ENANTIOSELECTIVE; ENANTIOSELECTIVE SYNTHESIS; HIGH YIELD; HYDROGEN CARBONATES; INTERMEDIATE FORMATION; INTRAMOLECULAR SUBSTITUTIONS; REACTION MIXTURE; REDOX CHEMISTRY; ROOM TEMPERATURE; TROST LIGAND;

ALKYLATION; CARBONATION; CATALYSIS; CATALYST DEACTIVATION; CATALYST POISONING; HYDROCARBONS; LIGANDS; OXIDATION; PALLADIUM; REDOX REACTIONS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

PALLADIUM COMPOUNDS;

EID: 77349114495     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902739     Document Type: Article

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