메뉴 건너뛰기




Volumn 3, Issue 9, 2014, Pages 940-947

One-pot sequential catalytic hydration of alkynes and α-alkylation with alcohols for the synthesis of α-alkylated ketones

Author keywords

Alcohols; Alkynes; Hydration; Ketones; alkylation

Indexed keywords


EID: 84909947334     PISSN: 21935807     EISSN: None     Source Type: Journal    
DOI: 10.1002/ajoc.201402055     Document Type: Article
Times cited : (16)

References (68)
  • 7
    • 34250893845 scopus 로고    scopus 로고
    • For selected reviews about "hydrogen autotransfer" (or "hydrogenborrowing") processes, see, Angew. Chem. 2007, 119, 2410-2416
    • For selected reviews about "hydrogen autotransfer" (or "hydrogenborrowing") processes, see: a) G. Guillena, D. J. Ramon, M. Yus Angew. Chem. Int. Ed. 2007, 46, 2358-2364; Angew. Chem. 2007, 119, 2410-2416;
    • (2007) Angew. Chem. Int. Ed. , vol.46 , pp. 2358-2364
    • Guillena, G.1    Ramon, D.J.2    Yus, M.3
  • 12
    • 79952634872 scopus 로고    scopus 로고
    • T. Suzuki, Chem. Rev. 2011, 111, 1825-1845;
    • (2011) Chem. Rev. , vol.111 , pp. 1825-1845
    • Suzuki, T.1
  • 45
    • 0041345498 scopus 로고    scopus 로고
    • For selected examples, see, Angew. Chem. 2002, 114, 4745-4747
    • For selected examples, see: a) E. Mizushima, K. Sato, T. Hayashi, M. Tanaka, Angew. Chem. Int. Ed. 2002, 41, 4563-4565; Angew. Chem. 2002, 114, 4745-4747;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 4563-4565
    • Mizushima, E.1    Sato, K.2    Hayashi, T.3    Tanaka, M.4
  • 54
    • 84867783056 scopus 로고    scopus 로고
    • Li and Herzon demonstrated direct synthesis of branched alcohols involving gold-catalyzed regioselective hydration of alkynes, see
    • Li and Herzon demonstrated direct synthesis of branched alcohols involving gold-catalyzed regioselective hydration of alkynes, see: L. Li, S. B. Herzon, J. Am. Chem. Soc. 2012, 134, 17376-17379;
    • (2012) J. Am. Chem. Soc. , vol.134 , pp. 17376-17379
    • Li, L.1    Herzon, S.B.2
  • 55
    • 84872109382 scopus 로고    scopus 로고
    • Naka and co-workers also reported the hydration of terminal alkynes to give methyl ketones catalyzed by a cobalt porphyrin complex, see
    • Naka and co-workers also reported the hydration of terminal alkynes to give methyl ketones catalyzed by a cobalt porphyrin complex, see: T. Tachinami, T. Nishimura, R. Ushimaru, R. Noyori, H. Naka, J. Am. Chem. Soc. 2013, 135, 50-53.
    • (2013) J. Am. Chem. Soc. , vol.135 , pp. 50-53
    • Tachinami, T.1    Nishimura, T.2    Ushimaru, R.3    Noyori, R.4    Naka, H.5
  • 56
    • 84909964028 scopus 로고    scopus 로고
    • The reaction of 1m with 2a was carried out under magnetic stirring because the boiling point of 1m is only 37-38°C
    • The reaction of 1m with 2a was carried out under magnetic stirring because the boiling point of 1m is only 37-38°C.
  • 57
    • 84909964027 scopus 로고    scopus 로고
    • It was speculated that the acidic nature of the catalytic system resulted in the desilylation of trimethyl(2-phenylethynyl)silane, see:Ref 12a
    • It was speculated that the acidic nature of the catalytic system resulted in the desilylation of trimethyl(2-phenylethynyl)silane, see:Ref 12a.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.