Gold-catalyzed regioselective hydration of propargyl acetates assisted by a neighboring carbonyl group: Access to α-acyloxy methyl ketones and synthesis of (±)-actinopolymorphol B

Journal of Organic Chemistry

Volumn 76, Issue 2, 2011, Pages 500-511

  Ghosh, Nayan ^a   Nayak, Sanatan ^a   Sahoo, Akhila K ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACID-LABILE; AMBIENT TEMPERATURES; AMINO ALCOHOLS; CARBONYL GROUPS; CATALYTIC CONDITIONS; FUNCTIONAL MOIETIES; GRAM SCALE; METHYL KETONES; PROLONGED REACTION; PROPARGYL; PROTECTING GROUP; QUANTITATIVE YIELDS; REGIO-SELECTIVE; TERMINAL ALKYNE;

ACETONE; ACETYLENE; ALCOHOLS; CARBONYLATION; ETHERS; HYDRATION; ORGANIC POLYMERS; SYNTHESIS (CHEMICAL);

REGIOSELECTIVITY;

ACETIC ACID DERIVATIVE; ACTINOPOLYMORPHOL B; ALPHA ACYLOXY METHYLKETONE DERIVATIVE; CARBONYL DERIVATIVE; GOLD; KETONE DERIVATIVE; NATURAL PRODUCT; PROPARGYLACETATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CROSS COUPLING REACTION; DRUG STRUCTURE; DRUG SYNTHESIS; ENVIRONMENTAL TEMPERATURE; HYDRATION; STEREOCHEMISTRY; SUBSTITUTION REACTION;

EID: 78651520760     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101995g     Document Type: Article

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