N-N bond cleavage of 1,2-diarylhydrazines and N-H bond formation via H-atom transfer in vanadium complexes supported by a redox-active ligand

Journal of the American Chemical Society

Volumn 136, Issue 34, 2014, Pages 12099-12107

  Milsmann, Carsten ^a   Semproni, Scott P ^a   Chirik, Paul J ^a  

^a PRINCETON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; ANILINE; ATOMS; ELECTRONIC PROPERTIES; FREE ENERGY; FREE RADICAL REACTIONS; LIGANDS; PRASEODYMIUM COMPOUNDS; PYRIDINE; REDOX REACTIONS; VANADIUM METALLOGRAPHY;

COMPUTATIONAL STUDIES; CROSSOVER EXPERIMENTS; DINITROGEN COMPLEXES; DISPROPORTIONATIONS; HYDROGEN-ATOM TRANSFER; INTERCONVERSIONS; REDOX-ACTIVE LIGAND; VANADIUM COMPLEXES; BOND CLEAVAGES; BOND FORMATION; H-ATOM TRANSFER;

VANADIUM COMPOUNDS;

AMIDE; ANILIDE; AZOBENZENE; HYDRAZINE; HYDRAZINE DERIVATIVE; HYDROGEN; IRON COMPLEX; LIGAND; METHYL GROUP; NITROGEN; TOLUENE; TRANSITION ELEMENT; VANADIUM; XANTHENE; (2,2,6,6 TETRAMETHYLPIPERIDIN 1 YL)OXIDANYL; 1,2 DIPHENYLHYDRAZINE; ANILINE; UNCLASSIFIED DRUG; VANADIUM DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL BOND; CONTROLLED STUDY; CRYSTALLOGRAPHY; DISSOCIATION; ELECTRON SPIN RESONANCE; HYDROGENOLYSIS; INFRARED SPECTROSCOPY; MAGNETISM; OXIDATION REDUCTION REACTION; OXIDATION REDUCTION STATE; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; STOICHIOMETRY; X RAY DIFFRACTION; CHEMICAL STRUCTURE; COVALENT BOND; DENSITY FUNCTIONAL THEORY; RADICAL REACTION; SPECTROSCOPY; SYNTHESIS;

EID: 84906748623     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5062196     Document Type: Article

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