Kinetics and mechanism of N2 hydrogenation in bis(cyclopentadienyl) zirconium complexes and dinitrogen functionalization by 1,2-addition of a saturated C-H bond

Journal of the American Chemical Society

Volumn 127, Issue 40, 2005, Pages 14051-14061

  Bernskoetter, Wesley H ^a   Lobkovsky, Emil ^a   Chirik, Paul J ^a  

^a Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; DERIVATIVES; HYDROGENATION; ISOTOPES; MOLECULAR STRUCTURE; NITROGEN; REACTION KINETICS; SPECTROSCOPIC ANALYSIS;

KINETIC ISOTOPES; N LIGANDS; RATE LAWS; SECOND-ORDER REACTIONS;

ZIRCONIUM COMPOUNDS;

CYCLOPENTADIENE DERIVATIVE; ISOTOPE; NITROGEN; NITROGEN DERIVATIVE; ZIRCONIUM DERIVATIVE; ZIRCONOCENE; BIS(CYCLOPENTADIENYL) ZIRCONIUM; CYCLOPENTANE DERIVATIVE; HYDROGEN; LIGAND; ORGANOMETALLIC COMPOUND; ZIRCONIUM;

ADDITION REACTION; ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENTROPY; HYDROGENATION; SPECTROSCOPY; TEMPERATURE; CHEMICAL MODEL; CHEMISTRY; CONFORMATION; ELECTRON SPIN RESONANCE; KINETICS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; CYCLOPENTANES; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROGEN; HYDROGENATION; KINETICS; LIGANDS; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NITROGEN; ORGANOMETALLIC COMPOUNDS; ZIRCONIUM;

EID: 26444451029     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0538841     Document Type: Article

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