On the origin of dinitrogen hydrogenation promoted by [(η5- C5Me4H)2Zr]2(μ2, η2,η2-N2)

Journal of the American Chemical Society

Volumn 126, Issue 44, 2004, Pages 14326-14327

  Pool, Jaime A ^a   Bernskoetter, Wesley H ^a   Chirik, Paul J ^a  

^a Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; HYDROGEN; METAL COMPLEX; NITROGEN DERIVATIVE; ZIRCONIUM DERIVATIVE;

ADDITION REACTION; ARTICLE; CALCULATION; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ELIMINATION REACTION; ENERGY; HYDROGEN BOND; HYDROGENATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; REPRODUCIBILITY; STEREOSPECIFICITY; STRUCTURE ANALYSIS; SYNTHESIS; TECHNIQUE; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

EID: 7744230336     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja045566s     Document Type: Article

References (18)

1. Smil, V. Enriching the Earth; MIT Press: Cambridge, MA, 2001.
2. For N-H bond formation by hydrogen atom abstraction, see: Korobov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2003, 42, 4958.
3. Fryzuk, M. D.; Love, J. B.; Rettig, S. J. Science 1997, 275, 1445.
4. Basch, H.; Musaev, D. G.; Morokuma, K. Organometallics 2000, 19, 3393.
5. Pool, J. A.; Lobkovsky, E.; Chirik, P. J. Nature 2004, 427, 527.
6. Manriquez, J. M.; Bercaw, J. E. J. Am. Chem. Soc. 1974, 96, 6229.
7. Shaver, M. P.; Fryzuk, M. D. Adv. Synth. Catal. 2003, 345, 1061.
8. Chirik, P. J.; Day, M. W.; Bercaw, J. E. Organometallics 1999, 18, 1873.
9. See Supporting Information.
10. Chirik, P. J.; Henling, L. M.; Bercaw, J. E. Organometallics 2001, 20, 534.
11. Lauher, J.; Hoffmann, R. J. Am. Chem. Soc. 1976, 98, 1729.
12. Hanna, T. E.; Keresztes, I.; Lobkovsky, E.; Bernskoetter, W. H.; Chirik, P. J. Organometallics 2004, 23, 3448.
13. Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. J. Am. Chem. Soc. 1988, 110, 8731.
14. Duncan, A. P.; Bergman, R. G. Chem. Rec. 2002, 2, 431.
15. 2 complex, see: Morello, L.; Love, J. B.; Patrick, B. O.; Fryzuk, M. D. J. Am. Chem. Soc. 2004, 126, 9480.
16. Slaughter, L. M.; Wolczanski, P. T.; Klinckman, T. R.; Cundari, T. R. J. Am. Chem. Soc. 2000, 122, 7953.
17. Churchill, D. G.; Janak, K. E.; Wittenberg, J. S.; Parkin, G. J. Am. Chem. Soc. 2003, 125, 1403.
18. Jones, W. D. Acc. Chem. Res. 2003, 36, 140.