Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

Science

Volumn 301, Issue 5629, 2003, Pages 76-78

  Yandulov, Dmitry V ^a   Schrock, Richard R ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; CATALYSIS; PROTONS; X RAY ANALYSIS;

LIGANDS;

REDUCTION;

AMMONIA; DINITROGEN; HEPTANE; LIGAND; MOLYBDENUM; NITROGEN; TRIAMIDOAMINE; UNCLASSIFIED DRUG; CHROMIUM; NITROGENASE; ORGANOMETALLIC COMPOUND; PROTON;

AMMONIA; CATALYSIS; MOLYBDENUM;

ADDITION REACTION; ARTICLE; ATMOSPHERE; CATALYSIS; CATALYST; COMPLEX FORMATION; PRESSURE; PRIORITY JOURNAL; PROTON TRANSPORT; REDUCTION; ROOM TEMPERATURE; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE; X RAY ANALYSIS; ATMOSPHERIC PRESSURE; CHEMISTRY; ELECTRON; METABOLISM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; TEMPERATURE;

AMMONIA; ATMOSPHERIC PRESSURE; CATALYSIS; CHROMIUM; ELECTRONS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MOLYBDENUM; NITROGEN; NITROGENASE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PROTONS; TEMPERATURE;

EID: 0038054274     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1085326     Document Type: Article

References (42)

1. B. K. Burgess. Chem. Rev. 90, 1377 (1990).
2. B. K. Burgess. D. J. Lowe. Chem. Rev. 96, 2983 (1996).
3. D. C. Rees, J. B. Howard. Curr. Opinion Chem. Biol. 4, 559 (2000).
4. D. C. Rees, M. K. Chan, J. Kim, Adv. Inorg. Chem. 40, 89 (1996).
5. R. R. Eady. Chem. Rev. 96, 3013 (1996).
6. R. R. Eady, J. Inorg. Biochem. 86, 42 (2001).
7. J. B. Howard, D. C. Rees, Chem. Rev. 96, 2965 (1996).
8. J. Kim, D. C. Rees., Nature 360, 553 (1992).
9. J. Kim, D. Woo, D. C. Rees. Biochemistry 32, 7104 (1993).
10. J. T. Bolin, A. E. Ronco, T. V. Morgan, L. E. Mortenson, L. E. Xuong, Proc. Natl. Acad. Sci. U.S.A. 90, 1078 (1993).
11. J. Chen et al., Angew. Chem. Int. Ed. Engl. 32, 1592 (1993).
12. O. Einsle et al., Science 297, 1696 (2002).
13. A. D. Allen, C. V. Senoff. J. Chem. Soc. Chem. Commun. 1965, 621 (1965).
14. J. Chatt, J. R. Dilworth, R. L Richards, Chem. Rev. 78, 589 (1978).
15. M. Hidai, Y. Mizobe, Chem. Rev. 95, 1115 (1995).
16. M. Hidai, Coord. Chem. Rev. 185-186, 99 (1999).
17. M. D. Fryzuk, S. A. Johnson. Coord. Chem. Rev. 200-202, 379 (2000).
18. T. A. Bazhenova, A. E. Shilov, Coord. Chem. Rev. 144, 69 (1995).
19. C. J. Pickett, J. Biol. Inorg. Chem. 1, 601 (1996).
20. F. Barriere, Coord. Chem. Rev. 236, 71 (2003).
21. R. L. Richards. Coord. Chem. Rev. 154, 83 (1996).
22. R. A. Henderson, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983).
23. C. R. Dickson, A. J. Nozik, J. Am. Chem. Soc. 100, 8007 (1978).
24. A. E. Shilov. J. Mol. Catal. 41, 221 (1987).
25. K. Komori, H. Oshita, Y. Mizobe, M. Hidal, J. Am. Chem. Soc. 111, 1939 (1989).
26. K. Tanaka, Y. Hozumi, T. Tanaka. Chem. Lett. 1982, 1203 (1982).
27. J. O. Dziegielewski, R. Grzybek. Polyhedron 9, 645 (1990).
28. 3.
29. R. R. Schrock, Pure Appl. Chem. 69, 2197 (1997).
30. G. E Greco, R. R. Schrod, Inorg. Chem. 40, 3850 (2001).
31. G. E. Greco, R. R. Schrock, Inorg. Chem. 40, 3860 (2001).
32. D. V. Yandulov, R. R. Schrock, J. Am. Chem. Soc. 124, 6252 (2002).
33. D. V. Yandulov, R. R. Schrock, A. L Rheingold, C. Ceccarelli, W. M. Davis, Inorg. Chem. 42, 796 (2003).
34. D. V. Yandulov, unpublished data.
35. N. G. Connelly, W. E. Geiger, Chem. Rev. 96, 877 (1996).
36. R. I. Cukier, D. G. Nocera, Annu. Rev. Phys. Chem. 49, 337 (1998).
37. J. L. Robbins, N. Edelstein, B. Spencer, J. C. Smart, J. Am. Chem. Soc. 104, 1882 (1982).
38. Materials and methods are available as supporting material on Science Online.
39. A. L. Chaney, E. P. Marbach, Clinical Chem. 8, 130 (1962).
40. M. W. Weatherbum. Anal. Chem. 39, 971 (1967).
41. C. J. Pickett, J. Talarmin, Nature 317, 652 (1985).
42. Supported by NIH grant no. GM 31978 (R.R.S).