메뉴 건너뛰기




Volumn 3, Issue 2, 2011, Pages 120-125

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; HYDRAZINE; HYDRAZINE DERIVATIVE; LIGAND; MOLYBDENUM; NITROGEN; PYRIDINE DERIVATIVE;

EID: 79251613415     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.906     Document Type: Article
Times cited : (619)

References (40)
  • 1
    • 0003594324 scopus 로고
    • (ed. Jennings, J. R.) (Plenum Press) and therein
    • Ertl, G. In Catalytic Ammonia Synthesis (ed. Jennings, J. R.) (Plenum Press, 1991) and therein.
    • (1991) Catalytic Ammonia Synthesis
    • Ertl, G.1
  • 2
    • 0010399699 scopus 로고    scopus 로고
    • (Wiley-VCH) and therein
    • Appl, M. Ammonia (Wiley-VCH, 1999) and therein.
    • (1999) Ammonia
    • Appl, M.1
  • 3
    • 0037031703 scopus 로고    scopus 로고
    • Nitrogenase MoFe-protein at 1.16 Å resolution: A central ligand in the FeMo-cofactor
    • Einsle, O. et al. Nitrogenase MoFe-protein at 1.16 Å resolution: a central ligand in the FeMo-cofactor. Science 297, 1696-1700 (2002).
    • (2002) Science , vol.297 , pp. 1696-1700
    • Einsle, O.1
  • 4
    • 15244343409 scopus 로고    scopus 로고
    • Substrate interactions with the nitrogenase active site
    • Dos Santos, P. C. et al. Substrate interactions with the nitrogenase active site. Acc. Chem. Res. 38, 208-214 (2005).
    • (2005) Acc. Chem. Res. , vol.38 , pp. 208-214
    • Dos Santos, P.C.1
  • 5
    • 34547764966 scopus 로고    scopus 로고
    • Elucidating the coordination chemistry and mechanism of biological nitrogen fixation
    • Dance, I. Elucidating the coordination chemistry and mechanism of biological nitrogen fixation. Chem. Asian J. 2, 936-946 (2007).
    • (2007) Chem. Asian J. , vol.2 , pp. 936-946
    • Dance, I.1
  • 6
    • 33947205969 scopus 로고    scopus 로고
    • Ammonia production at the FeMo cofactor of nitrogenase: Results from density functional theory
    • Kästner, J. & Blöchl, P. E. Ammonia production at the FeMo cofactor of nitrogenase: results from density functional theory. J. Am. Chem. Soc. 129, 2998-3006 (2007).
    • (2007) J. Am. Chem. Soc. , vol.129 , pp. 2998-3006
    • Kästner, J.1    Blöchl, P.E.2
  • 7
    • 1542318898 scopus 로고    scopus 로고
    • Dinitrogen coordination chemistry: On the biomimetic borderland
    • MacKay, B. A. & Fryzuk, M. D. Dinitrogen coordination chemistry: on the biomimetic borderland. Chem. Rev. 104, 385-401 (2004).
    • (2004) Chem. Rev. , vol.104 , pp. 385-401
    • MacKay, B.A.1    Fryzuk, M.D.2
  • 8
    • 7244234296 scopus 로고    scopus 로고
    • Multimetallic cooperative activation of N2
    • Gambarotta, S. & Scott, J. Multimetallic cooperative activation of N2. Angew. Chem. Int. Ed. 43, 5298-5308 (2004).
    • (2004) Angew. Chem. Int. Ed. , vol.43 , pp. 5298-5308
    • Gambarotta, S.1    Scott, J.2
  • 9
    • 21944455278 scopus 로고    scopus 로고
    • Research inspired by the chemistry of nitrogenase- novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes
    • Hidai, M. & Mizobe, Y. Research inspired by the chemistry of nitrogenase- novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes. Can. J. Chem. 83, 358-374 (2005).
    • (2005) Can. J. Chem. , vol.83 , pp. 358-374
    • Hidai, M.1    Mizobe, Y.2
  • 10
    • 33749330145 scopus 로고    scopus 로고
    • Intrinsic dinitrogen activation at bare metal atoms
    • Himmel, H.-J. & Reiher, M. Intrinsic dinitrogen activation at bare metal atoms. Angew. Chem. Int. Ed. 45, 6264-6288 (2006).
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 6264-6288
    • Himmel, H.-J.1    Reiher, M.2
  • 11
    • 33845466261 scopus 로고    scopus 로고
    • Dinitrogen functionalization with bis(cyclopentadienyl) complexes of zirconium and hafnium
    • Chirik, P. J. Dinitrogen functionalization with bis(cyclopentadienyl) complexes of zirconium and hafnium. Dalton Trans. 16-25 (2007).
    • (2007) Dalton Trans. , pp. 16-25
    • Chirik, P.J.1
  • 12
    • 61849146962 scopus 로고    scopus 로고
    • Side-on end-on bound dinitrogen: An activated bonding mode that facilitates functionalizing molecular nitrogen
    • Fryzuk, M. D. Side-on end-on bound dinitrogen: an activated bonding mode that facilitates functionalizing molecular nitrogen. Acc. Chem. Res. 42, 127-133 (2009).
    • (2009) Acc. Chem. Res. , vol.42 , pp. 127-133
    • Fryzuk, M.D.1
  • 13
    • 76249134433 scopus 로고    scopus 로고
    • The hydride route to the preparation of dinitrogen complexes
    • Ballmann, J., Munhá, R. F. & Fryzuk, M. D. The hydride route to the preparation of dinitrogen complexes. Chem. Commun. 46, 1013-1025 (2010).
    • (2010) Chem. Commun. , vol.46 , pp. 1013-1025
    • Ballmann, J.1    Munhá, R.F.2    Fryzuk, M.D.3
  • 15
    • 3543120669 scopus 로고    scopus 로고
    • Catalytic reduction of molecular nitrogen in solutions
    • Shilov, A. E. Catalytic reduction of molecular nitrogen in solutions. Russ. Chem. Bull. 52, 2555-2562 (2003).
    • (2003) Russ. Chem. Bull. , vol.52 , pp. 2555-2562
    • Shilov, A.E.1
  • 16
    • 0001190164 scopus 로고
    • Reductive silylation of molecular nitrogen via fixation to tris(trialkylsilyl)amine
    • Shiina, K. Reductive silylation of molecular nitrogen via fixation to tris(trialkylsilyl)amine. J. Am. Chem. Soc. 94, 9266-9267 (1972).
    • (1972) J. Am. Chem. Soc. , vol.94 , pp. 9266-9267
    • Shiina, K.1
  • 17
    • 0001617804 scopus 로고
    • Catalytic conversion of molecular nitrogen into silylamines using molybdenum and tungsten dinitrogen complexes
    • Komori, K., Oshita, H., Mizobe, Y. & Hidai, M. Catalytic conversion of molecular nitrogen into silylamines using molybdenum and tungsten dinitrogen complexes. J. Am. Chem. Soc. 111, 1939-1940 (1989).
    • (1989) J. Am. Chem. Soc. , vol.111 , pp. 1939-1940
    • Komori, K.1    Oshita, H.2    Mizobe, Y.3    Hidai, M.4
  • 18
    • 0024841249 scopus 로고
    • Syntheses and some reactions of trimethylsilylated dinitrogen complexes of tungsten and molybdenum
    • Komori, K., Sugiura, S., Mizobe, Y., Yamada, M. & Hidai, M. Syntheses and some reactions of trimethylsilylated dinitrogen complexes of tungsten and molybdenum. Bull. Chem. Soc. Jpn 62, 2953-2959 (1989).
    • (1989) Bull. Chem. Soc. Jpn , vol.62 , pp. 2953-2959
    • Komori, K.1    Sugiura, S.2    Mizobe, Y.3    Yamada, M.4    Hidai, M.5
  • 20
    • 9944238209 scopus 로고    scopus 로고
    • Activation of nitrogen for organic synthesis
    • and therein
    • Mori, M. Activation of nitrogen for organic synthesis. J. Organomet. Chem. 689, 4210-4227 (2004) and therein.
    • (2004) J. Organomet. Chem. , vol.689 , pp. 4210-4227
    • Mori, M.1
  • 21
    • 0038054274 scopus 로고    scopus 로고
    • Catalytic reduction of dinitrogen to ammonia at a single molybdenum center
    • Yandulov, D. V. & Schrock, R. R. Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Science 301, 76-78 (2003).
    • (2003) Science , vol.301 , pp. 76-78
    • Yandulov, D.V.1    Schrock, R.R.2
  • 22
    • 2442701728 scopus 로고    scopus 로고
    • Molybdenum triamidoamine complexes that contain hexa-tertbutylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen
    • Ritleng, V. et al. Molybdenum triamidoamine complexes that contain hexa-tertbutylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen. J. Am. Chem. Soc. 126, 6150-6163 (2004).
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 6150-6163
    • Ritleng, V.1
  • 23
    • 29544451340 scopus 로고    scopus 로고
    • The Yandulov/Schrock cycle and the nitrogenase reaction: Pathways of nitrogen fixation studied by density functional theory
    • Neese, F. The Yandulov/Schrock cycle and the nitrogenase reaction: pathways of nitrogen fixation studied by density functional theory. Angew. Chem. Int. Ed. 45, 196-199 (2006).
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 196-199
    • Neese, F.1
  • 24
    • 30944442835 scopus 로고    scopus 로고
    • Catalytic reduction of dinitrogen to ammonia at a single molybdenum center
    • Schrock, R. R. Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Acc. Chem. Res. 38, 955-962 (2005).
    • (2005) Acc. Chem. Res. , vol.38 , pp. 955-962
    • Schrock, R.R.1
  • 25
    • 49649098190 scopus 로고    scopus 로고
    • Catalytic reduction of dinitrogen to ammonia by molybdenum: Theory versus experiment
    • Schrock, R. R. Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment. Angew. Chem. Int. Ed. 47, 5512-5522 (2008).
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 5512-5522
    • Schrock, R.R.1
  • 26
    • 0032559215 scopus 로고    scopus 로고
    • Bimetallic system for nitrogen fixation: Ruthenium-assisted protonation of coordinated N2 on tungsten with H2
    • Nishibayashi, Y., Iwai, S. & Hidai, M. Bimetallic system for nitrogen fixation: ruthenium-assisted protonation of coordinated N2 on tungsten with H2. Science 279, 540-542 (1998).
    • (1998) Science , vol.279 , pp. 540-542
    • Nishibayashi, Y.1    Iwai, S.2    Hidai, M.3
  • 27
    • 0034716138 scopus 로고    scopus 로고
    • Formation of ammonia in the reactions of a tungsten dinitrogen with ruthenium dihydrogen complexes under mild reaction conditions
    • Nishibayashi, Y., Takemoto, S., Iwai, S. & Hidai, M. Formation of ammonia in the reactions of a tungsten dinitrogen with ruthenium dihydrogen complexes under mild reaction conditions. Inorg. Chem. 39, 5946-5957 (2000).
    • (2000) Inorg. Chem. , vol.39 , pp. 5946-5957
    • Nishibayashi, Y.1    Takemoto, S.2    Iwai, S.3    Hidai, M.4
  • 28
    • 0032517375 scopus 로고    scopus 로고
    • A model for protonation of dinitrogen by nitrogenase: Protonation of coordinated dinitrogen on tungsten with hydrosulfido-bridged dinuclear complexes
    • Nishibayashi, Y., Iwai, S. & Hidai, M. A model for protonation of dinitrogen by nitrogenase: protonation of coordinated dinitrogen on tungsten with hydrosulfido-bridged dinuclear complexes. J. Am. Chem. Soc. 120, 10559-10560 (1998).
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 10559-10560
    • Nishibayashi, Y.1    Iwai, S.2    Hidai, M.3
  • 29
    • 0035966682 scopus 로고    scopus 로고
    • Protonation of coordinated N2 on tungsten with H2 mediated by sulfido-bridged dinuclear molybdenum complexes
    • Nishibayashi, Y.,Wakiji, I., Hirata, K., DuBois, M. R. & Hidai, M. Protonation of coordinated N2 on tungsten with H2 mediated by sulfido-bridged dinuclear molybdenum complexes. Inorg. Chem. 40, 578-580 (2001).
    • (2001) Inorg. Chem. , vol.40 , pp. 578-580
    • Nishibayashi, Y.1    Wakiji, I.2    Hirata, K.3    Dubois, M.R.4    Hidai, M.5
  • 30
    • 1642633093 scopus 로고    scopus 로고
    • Buckminsterfullerenes: A non-metal system for nitrogen fixation
    • Nishibayashi, Y. et al. Buckminsterfullerenes: a non-metal system for nitrogen fixation. Nature 428, 279-280 (2004).
    • (2004) Nature , vol.428 , pp. 279-280
    • Nishibayashi, Y.1
  • 31
    • 50549083732 scopus 로고    scopus 로고
    • Synthesis and reactivity of tungsten- and molybdenum-dinitrogen complexes bearing ferrocenyldiphosphines toward protonolysis
    • Yuki, M., Miyake, Y., Nishibayashi, Y., Wakiji, I. & Hidai, M. Synthesis and reactivity of tungsten- and molybdenum-dinitrogen complexes bearing ferrocenyldiphosphines toward protonolysis. Organometallics 27, 3947-3953 (2008).
    • (2008) Organometallics , vol.27 , pp. 3947-3953
    • Yuki, M.1    Miyake, Y.2    Nishibayashi, Y.3    Wakiji, I.4    Hidai, M.5
  • 32
    • 68949191224 scopus 로고    scopus 로고
    • Synthesis and protonolysis of tungsten- and molybdenum-dinitrogen complexes bearing ruthenocenyldiphosphines
    • Yuki, M., Midorikawa, T., Miyake, Y. & Nishibayashi, Y. Synthesis and protonolysis of tungsten- and molybdenum-dinitrogen complexes bearing ruthenocenyldiphosphines. Organometallics 28, 4741-4746 (2009).
    • (2009) Organometallics , vol.28 , pp. 4741-4746
    • Yuki, M.1    Midorikawa, T.2    Miyake, Y.3    Nishibayashi, Y.4
  • 33
    • 70349780737 scopus 로고    scopus 로고
    • Preparation and protonation of tungsten- and molybdenum-dinitrogen complexes bearing bis(dialkylphosphinobenzene)chromiums as auxiliary ligands
    • Yuki, M., Miyake, Y. & Nishibayashi, Y. Preparation and protonation of tungsten- and molybdenum-dinitrogen complexes bearing bis(dialkylphosphinobenzene)chromiums as auxiliary ligands. Organometallics 28, 5821-5827 (2009).
    • (2009) Organometallics , vol.28 , pp. 5821-5827
    • Yuki, M.1    Miyake, Y.2    Nishibayashi, Y.3
  • 34
    • 70449117736 scopus 로고    scopus 로고
    • Neutral tridentate PNP ligands and their hybrid analogues: Versatile non-innocent scaffolds for homogeneous catalysis
    • van der Vlugt, J. I. & Reek, J. N. H. Neutral tridentate PNP ligands and their hybrid analogues: versatile non-innocent scaffolds for homogeneous catalysis. Angew. Chem. Int. Ed. 48, 8832-8846 (2009).
    • (2009) Angew. Chem. Int. Ed. , vol.48 , pp. 8832-8846
    • Van Der Vlugt, J.I.1    Reek, J.N.H.2
  • 35
    • 37049115025 scopus 로고
    • Diazene-N-(di-imide) and hydrazido-(2-) N-(aminoimido) complexes: The addition of acids to dinitrogen complexes
    • Chatt, J., Heath, G. A. & Richards, R. L. Diazene-N-(di-imide) and hydrazido-(2-) N-(aminoimido) complexes: the addition of acids to dinitrogen complexes. J. Chem. Soc. Dalton Trans. 2074-2082 (1974).
    • (1974) J. Chem. Soc. Dalton Trans. , pp. 2074-2082
    • Chatt, J.1    Heath, G.A.2    Richards, R.L.3
  • 36
    • 0001300506 scopus 로고
    • Preparation and properties of dinitrogen- molybdenum complexes
    • Hidai, M., Tominari, K. & Uchida, Y. Preparation and properties of dinitrogen- molybdenum complexes. J. Am. Chem. Soc. 94, 110-114 (1972).
    • (1972) J. Am. Chem. Soc. , vol.94 , pp. 110-114
    • Hidai, M.1    Tominari, K.2    Uchida, Y.3
  • 37
    • 0001071810 scopus 로고
    • Syntheses, reactivities, molecular structures, and physical properties of paramagnetic bis(tetraphenylcyclopentadienyl) complexes of vanadium, chromium, cobalt, and nickel
    • Castellani, M. P., Geib, S. J., Rheingold, A. L. & Trogler, W. C. Syntheses, reactivities, molecular structures, and physical properties of paramagnetic bis(tetraphenylcyclopentadienyl) complexes of vanadium, chromium, cobalt, and nickel. Organometallics 6, 1703-1712 (1987).
    • (1987) Organometallics , vol.6 , pp. 1703-1712
    • Castellani, M.P.1    Geib, S.J.2    Rheingold, A.L.3    Trogler, W.C.4
  • 38
    • 0344718437 scopus 로고    scopus 로고
    • A potentiometric study of acid-base equilibria of substituted pyridines in acetonitrile
    • DOI 10.1016/S0003-2670(98)00771-5, PII S0003267098007715
    • Augustin-Nowacka, D. & Chmurzyñski, L. A potentiometric study of acid-base equilibria of substituted pyridines in acetonitrile. Anal. Chim. Acta 381, 215-220 (1999). (Pubitemid 29073298)
    • (1999) Analytica Chimica Acta , vol.381 , Issue.2-3 , pp. 215-220
    • Augustin-Nowacka, D.1    Chmurzynski, L.2
  • 40
    • 0037016413 scopus 로고    scopus 로고
    • Halide effects in transition metal catalysis
    • Fagnou, K. & Lautens, M. Halide effects in transition metal catalysis, Angew. Chem. Int. Ed. 41, 26-47 (2002).
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 26-47
    • Fagnou, K.1    Lautens, M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.